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Anethole accounted for 82.65% of the whole oil. Selective isolation of anethole form the volatile oil was carried out using an inclusion crystalline method with 1,1,6,6- tetraphenylhexa- 2,4-diyne-1,6-diol inclusion complex with anethole . The crystal structure of the inclusion complex was determined by IR, 1^H NMR and single crystal XRD techniques.

采用包结结晶方法对小茴香挥发油中的对-丙烯基茴醚进行了选择性分离,以1,1,6,6-四苯基-2,4-已二炔-1,6-二醇作为主体分子,小茴香挥发油中的对-丙烯基茴香醚作为客体分子,D.D选择性地与之形成超分子包结物晶体。

For developing an immunoassay for multiple residues of pyrethroid pesticides, the hapten N-2- carbanmoyl-(3"-phenoxyphenyl) methyl 3-(2"-Cldoro-3",3",3"-trifluoropropenyl)-2, 2-dimethylcyclopropane- carboxylate was synthesized from cyanohydrin and 3-(2"-Chloro-3",3",3- trifluoropropenyl)-2, 2-dimethylcyclopropanecarboxylic acid via hydrolysis and esterification. The synthesis of the hapten was foundation of preparaing anti- cyhalothrin polyclonal antibodies.

为了制备对单一拟除虫菊酯高特异性的抗体,以菊酸和氰醇为起始原料,通过水解、酯化反应合成了半抗原N-2-氨甲酰-(3-苯氧基苄基)甲基-3-(2-氯-3,3,3-三氟丙烯基)-2,2-二甲基环丙烷羧酸酯,为进一步制备抗三氟氰菊酯的特异性抗体奠定基础。

The main compounds in the natural terpineol oil were eucalyptol, trans4thujanol, pisopropenyl toluene, cis4thujanol, linalool, camphor, borneol, 4terpineol,αterpineol and safrole.

天然松油醇粗油中主要成分是1,8桉叶素、反式4艹守醇、p异丙烯基甲苯、顺式4艹守醇、芳樟醇、樟脑、龙脑、4松油醇、α松油醇和黄樟素。

In chapter four molecular modeling method is employed to comparatively study five S-allyl γ-hydroxy ketene dithioacetals reactions of Thio-Claisen rearrangement with and without zeolite catalysts.

第四章用分子模拟途径研究了在有、无分子筛催化条件下五种丙烯基羟基乙烯酮二硫代乙缩醛Thio-Claisen重排反应。

As a precursive work of polymerization directly from vesicles, a polymerizable surfactant, allyl dodecyl dimethylammonium bromide was synthesized, and spontaneous stable vesicles were formed from aqueous solutions of ADDB and sodium dodecyl sulfonate in equimolar composition.

作为可聚合囊泡制备的前期基础工作,研究了一种可聚合的囊泡体系:1-丙烯基-2,2,二甲基-十二烷基溴化胺和ADDB与十二烷基磺酸钠的等摩尔比混合体系。

It showed that the blend system had much slower Rp than that of hybrid monomer, either of acrylate double bond or propenyl ether double bond, and propenyl ether double bond conversion of hybrid monomer was much higher than that of the blend system at the end.

杂化单体与相同类型的混合体系相比,每种基团的反应动力学性质都得到了促进,丙烯酸酯和丙烯基醚双键的聚合速率都有了很大提高,丙烯基醚双键的转化率较混合体系有很大增加。

The reaction of the compound - 3 - triaiylstannyl -1,1 - diphenyl - 2 - propenyl - 1 -ol with ICl,Br2,I2 formed organotin halides ,which reacted with KOH to form organotin oxide or hydroxide.

首次以非碳环醇-3-三芳基锡基-1,1-二苯基-2-丙烯基-1-醇[Ph_2 CCH=CHSnAr_3]和卤素或拟卤素发生取代反应得到卤化物,并以此合成了氢氧化物、氧化物和配合物。

The title anti-fogging coating was prepared from film-forming substance such as UV curing of n-butyl methacrylate,β-hydroxy ethyl acrylate,acrylamide and sodium propenyl alkyl ether hydroxyl sulfonate,and proper solvents, crosslinker s,photoinitiators and additives.

以光敏丙烯酸酯低聚物、甲基丙烯酸丁酯、丙烯酸-β-羟乙酯、丙烯酰胺及丙烯基烷醚羟磺酸钠为主要成膜物质,再配以适量的溶剂、交联剂、光敏剂及各种助剂制成UV固化防雾涂料。

Methyl-2,3,5,6-tetrafluoro-benzene methanol was synthesized by chlorination, acylation, fluorination, esterifica- tion, reduction, bromization, reduction from terephthalic acid. Tefluthrin was obtained from-(1RS,3RS)-3-(2-chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethyl cycolpropa-necarboxylate acid by reacting with 4-methyl-2,3,5,6-tetrafluoro-benzene methanol.

以对苯二甲酸为原料,经氯化、酰氯化、氟化、酯化、还原、溴化、还原七步反应合成了4-甲基-2,3,5,6-四氟苄醇,甲基苄醇与-(1RS,3RS)-3-(2-氯-3,3,3-三氟丙-1-丙烯基)-2,2-二甲基环丙甲酸一步酯化合成了七氟菊酯。

A multi-element graft copolymer of starch is prepared from starch, allyl compound and water as medium through free radical graft copolymerizing reaction at 80-85 deg.

该共聚物是以淀粉、丙烯基化合物为主要原料以水为介质通过自由基聚合方法得到的产物。

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