丙烯基

The allylation reactions of aldehydes with allyl bromide were carried out in 76%～93% yields with Nd-SnCl2-H2O under ultrasound irradiation at room temperature for 50～60 min.

在Nd-SnCl2-H2O体系中，用烯丙基溴超声诱发下进行了一系列芳香醛的烯丙基反应，室温反应50～60min得76%～93%烯丙基化产物；而不用超声波时同样体系中搅拌3～4h高烯丙基醇产率为30%～86%。

This work, concentrated on the asymmetric allylation of aldehydes controlled by different chiral auxiliaries prepared from rotational pure tartaric acid, can be divided into three parts.The first part aims to review the developments of chiral drugs and asymmetric synthesis, from which derived the present research topic backgrounds and works.Synthesis and applications of allylation from aldehydes are the second part of the thesis. By optimizing the reaction conditions, such as solvents, temperature, time and chiral auxiliaries like N,N\'-dibenzyl tartamide, N,N\'-p-dimethylphenyl tartamide, N,N\'-o-dimethylphenyl tartamide, N,N\'-o-dichlorophenyl tartamide, N,N\'-a-dinaphyl tartamide, N,N\'-dicyclohexyl tartamide and N,N\'-diphenyl tartamide, ideal experimenttal conditions are obtained according to HPLC monitoring, as well as the auxiliaries\' recoveries experiments. Starting from benzaldehyde and 3-bromopropaldehyde, N,N\'-dibenzyl tartamide is considered the best auxiliary in this reaction.

本文介绍了醛的不对称烯丙基化反应，以光学纯酒石酸为原料，研究了不同构型手性配体在醛的烯丙基化反应中的立体选择性，全文共分三部分十个章节：第一部分对当前手性药物和手性技术进行了概述，并由此展开了本文的研究背景和任务；第二部分为有机合成部分，对醛的不对称烯丙基化反应进行了深入探讨，以苯甲醛为原料对反应条件进行优化，在优化的反应条件下对制备的七种可回收手性酰胺配体(N-苄基酒石酸二酰胺、N-对甲苯基酒石酸二酰胺、N-邻甲苯基酒石酸二酰胺、N-邻氯苯基酒石酸二酰胺、N-a-萘基酒石酸二酰胺、N-环己基酒石酸二酰胺和N-苯基酒石酸二酰胺)进行筛选，优化配体回收实验条件，最终确定出N-苄基酒石酸二酰胺在苯甲醛的不对称烯丙基化反应中具有较大优越性，结晶回收的手性配体光学纯度保持不变。

Compared with the present process for the synthesis of acrylate by esterification of acrylic acid, which comes by oxygenation of propylene, the process by the carbonylation of acetylene to acrylic acid and its esters pays less cost, and so, is worth to be studied.

相对于目前主张的丙烯氧化法生产丙烯酸，再酯化生产丙烯酸酯的主流工艺，乙炔羰基化法合成丙烯酸及酯的工艺具有很好的经济性应用价值。

N-Benzylacryl amide was synthesized using acrylonitrile and benzyl alcohol as raw materials and sulfuric acid as catalyst.

以丙烯腈和苯甲醇为原料，浓硫酸作催化剂，合成了N-苄基丙烯酰胺。

A concentration of 2.5 micrograms per millilitre was effective at reducing the acrylamide-induced ROS production, as well as the preventing the fragmentation of DNA, and effects of cytotoxicity, report Cao and co-workers.

曹及其同僚表示，浓度为2.5微克/毫升的姜黄色素就能有效的减少由丙烯酰胺引起的活性氧自由基的产生，从而可以防止DNA的裂解，同时有效阻止细胞毒素。

The fluorescence of the polymer, P could be quenched by electron-deficient quenchers such as methacrylonitrile, acrylonitrile, fumaronitrile; methyl acrylate and methyl methacrylate.

本文合成了新的功能性单体N一甲基丙烯酞一N，一呛吮基呱嗦，并观察了单体及其聚合物溶液的荧光光谱。

The relationship between the melt index, the tensile strength and the stress-crack resistance, and that between the end-group structure and thermal stability of copo-lymer of tetrafluoroethylene and hexafluoropropylene have been studied.

研究了四氟乙烯和六氟丙烯共聚物的熔融指数，抗张强度和耐应力开裂之间，以及端基和热稳定性之间的关系。

It is important to use the best available water blended with not more than 60 percent ethylene glycol base antifreeze or 50 percent propylene glycol base antifreeze.

最重要的是要利用现有的水混合不超过60%或50%乙烯丙烯乙二醇防冻剂乙二醇基制药基地。

We had finished some items such as propanoic acid and acetic acid series antimildew compound. animal and vegctable hydrolyzed protcin. yeastextracts. starch sodium octenylsuccinate. etc.

自成立10年以来，在食品添加剂中开发了丙酸系列、乙酸系列防霉剂，动植物水解蛋白，酵母抽提物，辛烯基琥珀酸淀粉钠等。

Single component and multi\|component of iron system colloidal catalyst \Ali\|Bu\-3CH\-2CHCH\-2Cl\ were mixed by different ratios in hydrogenated gasoline medium at 25℃.This paper studied the relationship between the nonaqueous systematic electroconductivity and the concentration of catalyst components.In combination with Tyndall effect,polymerization experimental results,Ali\|Bu\-3 existed in associated state and dissociated into ionpair.The reaction between Ali\|Bu\-3 and Fenaph\-2 was the main reaction which formed colloidal core.Ali\|Bu\-3 reacted on CH\-2CHCH\-2Cl and Ali\|Bu\-2Cl was yielded which joined the formation of active center on the surface of colloidal core.The excessive Ali\|Bu\-3 was dissociated into ionpair which formed double electrode layer,and the double electrode layer kept the colloidal particles relatively stable.

研究了在25℃加氢汽油介质中，铁系胶体催化剂［Fenaph2Ali-Bu3―CH2==CHCH2Cl］单组分、多组分按不同配比混合，非水体系电导率与浓度的关系，结合Tyndall效应，聚合实验结果，得出Ali-Bu3以缔合状态存在并解离成离子对它同环烷酸亚铁的作用是形成胶核的主要反应，与氯丙烯反应生成的氯化异丁基铝，在胶核表面参与形成活性中心由过量Ali-Bu3解离的离子对形成的双电层结构，使胶粒保持相对稳定。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。