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In all cases, only the biboronic products with one boryl group adding to the middle carbon and the other to the nonsubstituted terminal carbon of the allene moiety were observed.

两个硼酯基都接於丙二烯基没有取代的末端双键上。立体选择性很高,主要的产物都是Z form的形式。

Reduction of 2-bromodifluoromethyl substituted propargyl vinyl ether afforded the difluorovinyl propargyl ether, which rearranged to the corresponding allene bearing a gem-difluoromethene in the mid-aliphatic chain.

第三部分,在碱性条件下,α-氟烷基乙酸乙酯与炔丙醇反应制备了一系列的氟烷基取代的炔丙基烯基醚,并研究了它的Claisen重排反应,得到了2,4-不饱和的氟烷基酮。

Otherwise, an intermediary allylamine deposition was covalently linked to the oxide layer by glow discharge, the covalent binding of bioactive protein to the free terminal NH2 groups using glutaraldehyde as a coupling agent was followed.

并利用丙烯胺的电浆处理在钛金属表面键结上胺基(-NH2)的官能基,之后再以交链剂戊二醛来固定生物活性胶原蛋白於低温电浆处理后的钛金属表面。

The detailed mechanisms of the electron transfer reactions of common coenzyme NADH model compounds were systematically investigated using o-allyloxy benzenediazonium salt as the probe.

应用邻位烯丙氧基取代的芳基重氮盐作为探针,对辅酶NADH几种最常用的模型化合物电子转移反应的过程和机理进行了比较系统的考察。

The coating composition comprises, in a specific proportion, a vehicle ingredient comprising in a specific proportion an oligomer having at least twoacrylate groups and an ethylenic monomer copolymerizable with the oligomer, aacrylic-modified chlorinated polyolefin having a specific chlorine content, an organic peroxide polymerization initiator, and a polyisocyanate compound.

该涂料组合物含有特定比例的由至少具有两个丙烯酸酯基的低聚物和可与该低聚物共聚的乙烯性不饱和单体形成的媒介物成分、特定氯含率的丙烯酰基改性氯化聚烯烃、有机过氧化物聚合引发剂、和聚异氰酸酯化合物。

This process makes the agglomerate soot more compact, and is possibly caused by the peroxy radicals and hydroxyl radicals generated from propene oxidation.

研究表明这种重构是由丙烯氧化产生的过氧自由基和羟基自由基引起的。

We screened a set of Lewis base organocatalysts derived from chiral pipecolinic acid and tert-butanesulfinamide for the reduction of-N-Cbz-1- phenylpropenamine, including newly designed ones and some of those previously developed in our lab. However, only moderate stereoselectivities, albeit high yields were obtained.

在本课题组前期研究的基础上,我们筛选并设计了一系列以手性哌啶酸和叔丁基亚磺酰胺为母体的有机小分子路易斯碱催化剂,它们能催化三氯氢硅对-N-苄氧羰基-1-苯基丙烯胺的不对称还原,获得很高的收率和中等的对映选择性,并且具有很好的底物普适性。

The PMMA macromer was obtained by radical polymerization in the presence of 2-mercaptoethanol as a chain transfer agent, followed by termination with acryloyl chloride.

甲基丙烯酸甲酯进行自由基溶液聚合,巯基乙醇为链转移剂,然后用丙烯酰氯封端制备了聚甲基丙烯酸甲酯大分子单体。

Aiming at the shortcomings of high formaldehyde content and low soaping and crocking fastnesses of currently used pigment printing binder,by60Co-γ radiation polymerization process,the waterborne polyacrylate emulsion containing active keto groups was synthesized from acrylate monomers and diacetone acrylamide.

针对目前所用涂料印花黏合剂存在的色牢度低和甲醛含量高的缺陷,采用钴60-γ辐射法聚合工艺,利用丙烯酸酯单体、双丙酮丙烯酰胺合成出含活性酮羰基的丙烯酸酯乳液;然后同含端酰肼基聚氨酯乳液按一定的比例混合,制备出酮肼交联型丙烯酸酯聚氨酯复合乳液。

In this thesis, a novel polymerizable cation amphiphilic compound, 4-2-(acryloyloxy ethoxy benzyl tri-ethyl ammonium bromide, was synthesized.

本论文合成了一种新型可聚合两亲化合物4-2-(丙烯酰氧基乙氧基苯亚甲基三乙基溴化铵。

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推荐网络例句

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候,里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色,卵在发育96h后卵基本全部孵化。

There was a conflict between plebs and patricians in ancient Rome in 494BC.

在公元前494年,罗马发生了一次平民反对贵族的斗争。