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The copolymers of 2-acrylamide-2-methyl propanesulfonic acid and itaconic acid were synthesized by free radical aqueous solution copolymerization, and its structure was characterized by IR.

用自由基水溶液聚合法,合成了2-丙烯酰胺基-2-甲基丙磺酸和衣康酸的二元共聚物缓凝剂,并用红外光谱表征了其结构。

The results showed that the thermo-sensitivity of hairy PNIPA changed obviously in the presence of hairy PAA as polyelectrolyte.4-cyanopentanoic acid dithiobenzoate as soluble reversible addition-fragmentation chain transfer agent was directly added into the above PS particles with photo-initiator on the surface and NVP or NIPA as monomer.

其次,将水溶性RAFT试剂直接引入上述光引发聚合体系,探讨连续相中RAFT试剂的存在对微球表面N-乙烯基吡咯烷酮或N-异丙基丙烯酰胺聚合的影响,考察了RAFT试剂对聚合过程中微球壳层高分子毛发厚度和单体转化率变化趋势。

Methacryloyloxydecyl-2-thiouracil-5-carboxylate was synthesized from the reaction of thiouracil with diethyl ethoxymethylene malonate and ω-hydroxy-decyl-methacrylate.

以硫脲、乙氧基次甲基丙二酸二乙酯和甲基丙烯酸ω-羟癸酯为主要原料合成了一种新的粘接性单体10-甲基丙烯酰氧癸基-2-硫脲嘧啶-5-羧酸酯。

Thiazolidiane-4-carboxylic acid was prepared and used as the aid catalyst that has strengthened the catalytic effect of chloroplatinic acid, greatly improved the yield of the hydrosilylation of methyldichlorosilane with allychloride, and made the yield get to 64.9%.

通过比较,选用自制的含硫化合物4-羧基-1,3-噻唑烷作助催化剂,大大增强了氯铂酸的催化活性,使甲基二氯硅烷与氯丙烯的加成反应以较高产率得到γ-氯丙基甲基二氯硅烷,产率可达64.9%。

In this study, Polyurethane/hydrogel composites were fabricated for wound repair applications. The hydrogel was copolymer of thermosensitive N-isopropyl acrylamide and acrylic acid.γ-ray irradiation was employed to copolymerize NIPAAm with AAc and to graft hydrogel onto porous PU simultaneously.

本研究以聚胺基甲酸酯为基材,将感温性异丙基丙烯醯胺(N-isopropyl acrylamide, NIPAAm)和丙烯酸(Acrylic acid, AAc)以γ-ray照射聚合法进行聚合,并同时将水胶接枝在多孔PU上,制备出PU/水胶复材之人工敷料,应用於伤口修复。

In the presence of alkalinity and tetraethyl ammonium bromide, 2,4-dihydroxy benzophenone reacts with allyl glycidyl ether to form an ethylenic derivative of benzophenone, 2-hydroxy-4-(β-hydroxy-γ-allyloxy) propyloxy benzophenone, which can further undergo hydrosilylation with polyhydromethylsiloxane.

在相转移催化剂四乙基溴化按作用下,利用2,4-二羟基二苯甲酮与烯丙基缩水甘油醚在碱性水溶液中的开环加成反应,合成了中间体4-丙氧基-2-羟基二苯甲酮,将其进一步与聚甲基氢硅氧烷进行硅氢化加成反应。

The results indicated isoprene was soon consumed under the condition of excess ozone. During the reaction, the major carbonyl products formed were methyl vinyl ketone, methacrolein, methylglyoxal, and formaldehyde. Formic acid, CO and CO2 were also among the products.

在反应温度(294±2)K,压力为1.01×10^5Pa空气,O3过量的条件下,异戊二烯很快反应完全,反应中生成的羰基产物主要包括甲基丙烯醛、甲基乙烯基酮、丙酮醛和甲醛;产物中还包括甲酸、一氧化碳和二氧化碳。

N-propyl-4-(N-methylacryloxy-ethyl)amino-1,8-naphthalimide was synthesized and used for determination of picric acid.

合成了N-丙基-4-(N-甲基丙烯酰基氧乙基)氨基-1,8-萘酰亚胺,研制出了苦味酸荧光光纤传感器,可间接测定药片中磷酸氯喹和水样中苦味酸的含量。

Poly silica hybrids were prepared through polymerization, condensation and sol gel processes of the mixture of methyl methacrylate, poly and a small amount of coupling agent methacryloxylpropyl trimethoxy siliane in tetrahydrofuran.

采用溶胶-凝胶技术,以硅酸钠为原料制备聚硅酸/四氢呋喃溶胶,再与甲基丙烯酸甲酯及少许偶联剂甲基丙烯酰氧丙基三甲氧基硅烷(MPTMS 混合,经聚合、缩合和溶胶-凝胶过程制备了有机/无机两相间有— C—Si—O—键的杂化材料——聚甲基丙烯酸甲酯/二氧化硅(PMMA/Si O2 )。

Using tetrabutyl titanate and methyl methacrylateor 2-Hydroxyethylmethacrylate (HEMA as materials, methacryloxylpropyl trimethoxy siliane as coupling agent, HCl as catalyst, Poly-titania(PMMA-TiO2) nanocomposites and Poly-titania(PMMA-TiO2) nanocomposites were synthesized by sol-gel process.

以盐酸作为催化剂,将钛酸四丁酯水解制备二氧化钛(TiO2)溶胶;随后将所制备溶胶与甲基丙烯酸甲酯、硅烷偶联剂(γ-甲基丙烯酰氧丙基三甲氧基硅烷)相混合,以过氧化苯甲酰作为引发剂,经过聚合、缩合和溶胶-凝胶过程,制备了均匀透明的PMMA-TiO2纳米复合材料和PHEMA-TiO2纳米复合材料。

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