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Poly (N-isopropylacrylamide) macromonomer with a styrol end group was prepared by free radical polymerization of NIPAAm.

用链转移自由基聚合和端基置换反应,合成了聚N-异丙基丙烯酰胺热敏性大分子单体。

By the experimental study we can get the ways of this polymerization craft which is that we can construct water-solution foam polymeric system with the help of the foaming agent, using AM and DMDAAC as monomers, and that we choice the oxide-reductive agent and ultraviolet light as compound initiation system, and that we proceed vacuate pretreating for Pharmaceuticals, and superinduce additive to prevent cross link in drying process which also can improve product water-solubility.

实验研究得出这种聚合工艺的具体方法为:以丙烯酰胺、二甲基二烯丙基氯化铵为单体,在起泡剂的帮助下,构建出水溶液泡沫聚合体系,引发体系则选用氧化—还原剂和紫外灯组成的复合引发体系引发反应,药品进行抽真空预处理,同时添加一定量的助剂防止产品在干燥过程中发生交联,改善产品水溶性。

Taking acryl amide, dimethyldiallyl ammonium chloride, acrylic acid as the monomer, amphoteric polyacrylamide was prepared by solution copolymetization. The effect of reaction conditions on the molecular weight and flocculation performance of AMPAM was studied.

以丙烯酰胺、二甲基二烯丙基氯化铵、丙烯酸为单体,用溶液共聚法制备两性聚丙烯酰胺,研究了反应条件对两性聚丙烯酰胺分子量及絮凝性能的影响。

Further more, to make the hybrid microspheres with good dispersibility in aqueous media, 3-propyl triethoxysilane was added to copolymerize with St and DVB, and after hydrolization the microspheres with silanol groups on the surface were obtained, which can be well dispersed in water and used for cell imaging.

进而将3-甲基丙烯酰氧基丙基三甲氧基硅烷作为共聚单体,得到了表面硅羟基功能化的聚苯乙烯荧光微球,改善了微球在水相中的分散性,并将此类荧光功能微球成功用于细胞成像。

The polymerization reacts from the inverse emulsion . Selecting white oil as continuous medium , Span60 and TX-10 as the complex emulsifier , AM-01﹑(NH4)2S2O4 and NaHSO3 as new-type complex initiator , the copolymerization of dimethylamino ethyl acrylate methyl chloride/acrylamide was developed . The effects of the concentration of monomer﹑emulsifier and initiator﹑ temperature﹑reaction time and pH on the molecular weight﹑intrinsic viscostity﹑conversion ratio and cation degree of copolymer were studied .

以反相乳液为初始聚合体系,油酸失水山梨醇酯Span60和辛基酚聚氧乙烯醚TX-10构成复配乳化剂,白油为连续介质,AM-01、过硫酸铵和亚硫酸氢钠组成新型复合引发体系,进行丙烯酰胺/(2-甲基丙烯酰氧乙基)三甲基氯化铵的反相准微乳液共聚合,研究了单体浓度、乳化剂、反应温度、反应时间、pH等因素对聚合产品分子量、特性粘数、转化率及阳离子度的影响。

Employing acetyl chloride as the electrophile afforded the β-acetoxyvinyl-γ-butyrolactone 3 as the product, which provided an experimental evidence to the mechanism involving the palladium enolate intermediate.

使用乙酰氮作为亲电试剂得到了β-乙酰氧基烯基-γ-丁丙酯3,这一结果为烯醇钯中间体的机理提供了一个实验证据。

The silica/Polystyrene monocore-shell nanocomposite particles(95nm in diameter) were synthesized through miniemulsion polymerization by using sodium dodecyl sulfate surfactant,hexadecane costabilizer in the presence of silica particles(50nm in diameter) coated with methacryloxytrimethoxysilane.

采用细乳液聚合法,以3-甲基丙烯酰氧基丙基三甲氧基硅烷(KH570)表面改性的直径50nm的氧化硅粒子为核,在乳化剂、助乳化剂、引发剂存在的情况下制备了小粒径、单核核壳结构氧化硅/聚苯乙烯纳米复合微球。

Comb-shaped copolymer of polycarboxylate containing carboxyl,sulfonic groups(-SO3M),polyethylene glycol(-OC2H4-) was synthesized by monomers of sodium 2-acrylamido-2-methylpropane sulphonate,acrylic acid,polyethylene glycol monoester acrylate under certain conditions.

本文通过2-丙烯酰胺-2甲基丙基磺酸钠与丙烯酸、聚乙二醇单丙烯酸酯在一定条件下发生聚合反应合成含有羧基、磺酸基(—SO3M)、聚氧乙烯链(—OC2H4—)等侧链的高性能减水剂PC。

The catalytic performance of PhTMG was evaluated in the reaction for synthesis of diethylene glycol bis via carbon dioxide route and the highest yield of ADC was 95.3%.

考察了PhTMG对以二甘醇、氯丙烯和CO2为原料合成二甘醇双烯丙基碳酸酯反应的催化性能,ADC的最高收率为95.3%。

The results suggested that the reaction temperature, the ratio of oil to water, the amount of ethyl cellulose as dispersant, initial monomers composition, the drop manner and the amount of initiator, the stirring speed, the pH of the buffer and the elution process have great influence on the morphology such as diameter of the hydrogel beads.

研究结果表明,采用反相悬浮聚合法,以丙烯酰胺和N-乙烯基吡咯烷酮为共聚单体,N,N'-亚甲基双丙烯酰胺为交联剂,牛血清白蛋白为模板,可以制备BSA印迹共聚物微球;反应温度、水油比、乙基纤维素分散剂用量、初始共聚单体配比、引发剂用量和加入方式、搅拌速度、水相pH值以及后续洗脱条件等均对粒径等微球结构和形态产生明显影响。

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