丙炔

The second part of this paper relates to the synthesis of 3(2)-fluoro-4-propargyl- benzyl alcohol.

本论文的第二部分工作是3-氟(2-氟)-4炔丙基苄醇的合成探讨。

In the thesis, the mechanism of Three-Component coupling ofα-oxyaldehyde, piperidine and phenylacetylene was analyzed.

当使用光学纯的受保护的三碳醣作为反应底物时，得到了高产率和高立体选择性的炔丙基胺。

Via comprehensive computations, the possibilities of vinylidene and allene intermediates were excluded, and the reaction mechanism was found to contain the following three steps:(1) gold-catalyzed cyclization to give the cyclic intermediate,(2) the cyclic intermediate undergoing a 1,3-H migration to give a more stable intermediate, with the assistance of water-cluster,(3) finially, the 1,2-H or 1,2-silyl migration occuring for generation of the observed product.

通过对各种可能的反应路径的进行计算和比较，排除了亚甲基卡宾和连二烯中间体的可能性，并确定该异构化反应机理包含以下三个步骤：（1）炔丙基吡啶反应在金催化条件下发生分子内的成环得到环状中间体；（2）环状中间体在水分子簇的协助下优先发生1，3-氢迁移反应，异构化得到更为稳定的中间体；（3）最后再进行1，2-氢迁移或是1，2-硅烷基团迁移即得到实验中所观察到的环异构化产物。

The details and results are summarized below:(1)An ABC style three component cascade reaction of aromatic aldehydes, aromatic amines and diethyl malonic ester or cyclohexanone has been developed.

论文从苯炔和亚胺出发，设计并系统研究了4种新的多组分串联反应，主要内容和结果如下：(1)发展了一种芳醛、芳胺和丙二酸二乙酯或环己酮的ABC型三组分串联反应。

For example,the addition reaction with small molecular,the metathetical reaction with alkynes and Wittig reaction to prepare high-valent transtion-metal allenylidene complexes.

对于化合物11，详细研究了其与小分子加成反应、炔烃复分解反应以及通过Wittig反应制备高价态过渡金属丙二烯基卡宾化合物。

The reaction with propargyl sulfide gave a mixture of allenic sulfide and furan.The former is the [2,3]-sigmatropic rearrangement product,while the latter is derived from the furt...

同样条件下与炔丙基硫醚的反应则生成[2，3]-σ重排产物联烯和呋喃衍生物，后者是联烯进一步在Ru作用下重排的产物。

Thirdly, The preparation of 3-aryl-5-substituted-ethenyl isoxazoles and l-isoxazolyl-2-isoxazolinyl substituted-ethenes was developed through 1, 3-dipolar cycloaddition of nitrile oxides,α-alkylation reaction and another 1, 3-dipolar cycloaddition of nitrile oxides based on polystyrene-supported propargyl selenide.

三、从聚苯乙烯负载的炔丙基硒醚出发，经过腈氧化物的1，3-偶极环加成反应、α-烷基化反应和腈氧化物的1，3-偶极环加成反应固相分别合成了3-芳基5-取代--乙烯基异噁唑和1—异噁唑—2—异噁唑啉取代的-乙烯。

The new olefination methods of alkyl substituted propargylic dithioacetals are described in this thesis.

中文摘要本篇论文围绕在烷基取代炔丙基硫缩醛的新型态烯化反应，可分为两部分进行探讨。

In chatpter three the mechanism of the gold-catalyzed cycloisomerization of propargylic pyridine was reported.

论文第三章将报道金催化的炔丙基吡啶衍生物的环异构化反应的机理研究结果。

We studied Ireland-Claisen rearrangement of propargylic esters of unsaturated acids.

三、研究了不饱和羧酸炔丙酯类化合物的Ireland-Claisen重排反应。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。