丙炔

The reactions of propargyl bromide/sodium iodide and aldehydes and ketones promoted by metallic dysprosium could obtain homopropargyl alcohols in high yield.

炔丙基溴/碘化钠与醛、酮在金属镝促进下可较高产率地得到高炔丙醇化合物。

Reduction of 2-bromodifluoromethyl substituted propargyl vinyl ether afforded the difluorovinyl propargyl ether, which rearranged to the corresponding allene bearing a gem-difluoromethene in the mid-aliphatic chain.

第三部分，在碱性条件下，α-氟烷基乙酸乙酯与炔丙醇反应制备了一系列的氟烷基取代的炔丙基烯基醚，并研究了它的Claisen重排反应，得到了2，4-不饱和的氟烷基酮。

Chiral centers of C5 and C8 are directly constructed in the key step of the diastereoselective propargylation from D--tartrate. The methylation and subsequent methoxycarbonylation result in desymmetrization of the terminal dialkynes. The α,β-unsaturated δ-lactone is synthesized after partial hydrogenation and lactonization.

由非天然酒石酸出发，利用双向非对映选择性的炔丙基化反应，在一步反应中同时构建C5和C8手性中心；然后通过末端炔基的甲基化、甲酯基化，延长碳链并对分子去对称化；内酯化得到关键中间体α，β-不饱和六元内酯，再经多步反应转化得到8-epi--Boronolide。

In the presence of SnCl2- C6H5Me3NBr and microwave irradiation, the mixture of tin-indium and propargyl bromide reacted quickly with aldehydes in aqueous media to produce the homopropargyl alcohols exclusively in high yields.

在SnCl2 和C6H5Me3NBr存在及微波照射下，锡-铟和炔丙基溴的混合物在水介质中与醛快速反应，生成高产率的单一的高炔丙醇。

Promoted by metal dysprosium, aldehydes and ketones could react smoothly with propargyl bromide to afford the corresponding homopropargylic alcohol s in good to excellent yields, and no allenic alcohols were found.

在金属镝的促进下，醛、酮可与炔丙基溴反应，高选择性高产率地得到相应的高炔丙醇，没有发现连二烯醇的存在。

The substituents on 2 and 4 position of furan ring were derived from the propargylic part of homopropargylic alcohol, and the substituent on 5 position of furan ring was derived from the

其呋喃环上2号及4号位置的取代基乃源自於高炔丙基醇之炔丙基，5号位置的取代基乃源自於醇之偕位，故藉此方法合成之碘化呋喃化合物具有高度的位向选择性。

In previous results, Alkyl substituted propargylic dithioacetals treating with butyl lithium then were allowed to react with carbonyl compounds to form homopropargylic alcohol with high yields and highly regioselective.

在本实验室先前的研究中发现，烷基取代炔丙基硫缩酮与正丁基锂进行开环反应后，若是与羰基化合物反应，能够以高产率、具位向选择性的生成高炔丙基醇。

In the presence of palladium catalyst and triphenylphosphine, alkynyl Grignards or alkynyllithiums could successfully couple with alkyl bromides and iodides. Aryl-substituted propargylic dithioacetals could also be obtained by this strategy.

在钯触媒和三苯基磷的存在下，我们可利用炔基格林那试剂或炔基锂和简单的卤烷进行偶合，而这样的反应条件也能应用在苯基取代炔丙基硫缩酮衍生物的合成上。

In the last part we first synthesized the propargylic amines though several methods and then developed a new methodology for the synthesis of -α-chloroalkylidene-β-lactams via the catalysis of PdCl〓 with CuCl〓 and BQ with moderate to good yields and good generality.

论文的第三部分工作是我们首先通过几种方法合成了炔丙基胺化合物，接着对PdCl〓催化的炔丙基胺的羰基插入环化反应进行了研究，以中等收率得到-α-氯代亚烷基-β-内酰胺化合物，反应的普适性良好。

First, when operating the DABCO-catalyzed Ireland-Claisen rearrangement of propargylic acrylates 18b-d, we added dienophiles 40a-f in the reaction system to capture the rearranged allenes products respectively. The Diels-Alder adducts 41a-i were obtained with complete regioselectivity. Thus a novel tandem Ireland-Claisen rearrangement /Diels-Alder reaction process with propargylic acrylates has been developed.

首先在进行DABCO-催化的丙烯酸炔丙酯类化合物18b-d的Ireland-Claisen重排反应的同时，于反应体系中分别加入亲二烯体40a-f捕获重排得到的连二烯中间体，一步反应获得了单一区域选择性的Diels-Alder环加成产物41a-i，从而创建了一条新颖的丙烯酸炔丙酯类化合物的Ireland-Claisen重排与Diels-Alder环加成的串联反应路线。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。