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丙氨酸

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" Phenylalanine: One of the essential amino acids, present in many common protein s, especially hemoglobin."

丙氨酸:见于普通蛋白质、尤其是血红蛋白中的一种基本氨基酸。

Can cause brain damage and progressive mental retardation as a result of the accumulation of phenylalanine and its breakdown products.

如果不治疗,这种异常会导致脑损伤和精神抑制,这是苯基丙氨酸沉积和其分解物的产物

In order to diagnose phenylketonuria early and rapidly for newborns,the fluorescence method for detecting phenylalanine is proposed.

苯丙酮尿症是一种由于人体正常染色体缺陷,造成的新生儿体内苯丙氨酸代谢紊乱性疾病。

Click here to read more about phenylalanine.

点击这里有关苯丙氨酸

However, it is still a vacancy for the metabolizability of resveratrol in the phenylalanine metabolism pathway.

但是由于白藜芦醇代谢在苯丙氨酸代谢途径中至今还是一个空白,因而与其衍生物和类似物的关系至今仍不够清晰。

The effects of feeding alanine-enriched mulberry leaves on the larval weight, silk gland weight and cocoon characters of the silkworm Bombyx mori L. were studied.

本研究以添加丙氨酸的桑餵食桑蚕Bombyx mori L。,解其对桑蚕幼虫重、丝腺重、蚕茧特性所造成的影响。

With L-DOPA as the starting chiral phenylalanine derivatives, construction of the skeleton of Phthalascidin was studied. Firstly, starting from L-DOPA and 3,4-dimethoxyphenylalanine, an amide 〓 was obtained, and a modeling cyclization reaction was carried out but failed to give the anticipated product.

二、对由苯丙氨酸甲酯衍生物通过Bischler-Napieralski反应合成四氢异喹啉—3—甲酯进行了研究,通过研究首次发现,生成苄基噁唑的反应是正常的B-N反应的竞争性反应,并从机理上给予了解释,所得出的结论具有一定的规律性,在杂环的合成方面具有一定的应用价值。

The synthesis of the pentacyclic skeleton of Et-743 and the construction of the five chiral centers thereof.1. The core pentacyclic skeleton of phthalascidin was constructed with L-dopa as the starting material via thirteen steps. First, two basic synthons, the C-1 functionalized tetrahydroisoquinoline compounds 8 and N-protected Z-dopa derivative 9, were prepared from L-dopa. They were coupled via amide bond to form the dipeptide compounds 10, which were the first key intermediates. Then the primary hydroxyl groups were transformed into the corresponding amino aldehydes 11 via Swern oxidation. Followed by the intramolecular Pictet-Spengler cyclization, the pentacyclic compounds 12 were synthesized.

五环骨架的构建及五个正确手性中心的确立:1.1我们以L-多巴为起始原料,经过多步官能团保护和转化合成了基本结构单元8然后和苯丙氨酸衍生物9,通过缩合反应生成酰胺中间体10,经Swern氧化得到醛化合物11,然后再次利用分子内改良的Pictet-Spengler反应一步构建c,d两环,得到五环骨架化合物12,最后,实现了21-位羰基向氰基的转化,得到了C-1位官能化的化合物14,化合物14不但具有和Et-743一致的五环骨架,而且分子中五个手性中心立体构型也与其完全相同:其中,3,位和13,位的手性中心由原料L-多巴带入,而1,位,11,位和21,位手性中心则通过不对称诱导而确立。

Effect of stoichiometric ratioof organic fuel to oxidizer on structures and catalytic activities of the catalysts were studied.

以D,L-丙氨酸为有机燃料,采用溶液燃烧法制备了钙钛矿型复合氧化物La0.8Sr0.2CoO3催化剂,研究了有机燃料与氧化剂的化学计量比对催化剂结构和性能的影响,考察了催化剂的甲烷燃烧活性,并对催化剂进行了表征。

Four new chiral sulfonamide alcohol s were synthesized from camphor and L-phenylalanine and their application to the enantioselective addition of diethylzinc to benzaldehyde was described.

由天然樟脑和-苯丙氨酸合成了4个新的手性磺酰胺醇,并对其在二乙基锌对苯甲醛的不对称加成中的催化性能进行了研究。

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