丙二醇

The common chemical constituents were juniper camphor,1,3,3-trimethylcyclohex-1-ene-4-carboxaldehyde,borneol,α-curcumene,α-bisabolol,cis-caryophyllene,benzyl benzoate,methyl β,β-dimethylbenzenepropanoic acid ester,2,4-decadienal and heneicosane in the essential oil of the five cultivars' Hangjuhua.Among them,juniper camphor is most which were composed of 11.96%,10.51%,10.95%,13.28% and 10.77% of the total essential oil,and methyl β,β-dimethylbenzenepropanoic acid ester is second,which were composed of 1.51%,1.86%,2.52%,4.89% and 2.51% of the total essential oil,respectively.

5种栽培类型杭菊花挥发油中共有成分为1，3，3-三甲基环己-1-烯-4-甲醛、冰片、α-姜黄烯、α-甜没药萜醇、顺式石竹烯、桧脑、安息香酸苄酯、β，β-二甲基苯丙酸甲酯、2，4-癸二烯醛和二十一烷；其中桧脑含量最高，分别占挥发油总量的11.96%，10.51%，10.95%，13.28%和10.77%，为5种栽培类型杭菊花挥发油中最具特征的成分；其次是β，β-二甲基苯丙酸甲酯，分别占挥发油总量的1.51%，1.86%，2.52%，4.89%和2.51%。

Their structures were characterized as dihydroconiferyl dihydro-p-coumarate, vanillin, apocynin, p-hydroxybenzaldehyde, syringaldehyde, syringic acid, syringylethanone,α-hydroxypropiosyringone, coniferyl aldehyde, dihydroconiferyl alcohol, 2-hydroxyphenylpropanol, and 3-hydroxy-4-methoxy-phenylethanol, respectively.

结果 从该植物中分离得到12个酚性化合物，其结构分别为二氢松柏醇二氢对羟基桂皮酸酯，香草醛，罗布麻宁，对羟基苯甲醛，丁香醛，丁香酸，丁香乙酮，α-羟基丁香丙酮，松柏醛，二氢松柏醇，2-羟基苯丙醇和3-羟基－4-甲氧基苯乙醇。

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene PolymerizationFacile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that:1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下：(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2，3-双(2，6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2，6-二[1-(2，4，6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上，研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响，研究表明：1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理，可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体；2、BET，XRD，IR，SEM，GPC和DSC研究表明，脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene Polymerization Facile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that: 1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下：(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2，3-双(2，6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2，6-二[1-(2，4，6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上，研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响，研究表明： 1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理，可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体； 2、BET，XRD，IR，SEM，GPC和DSC研究表明，脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

The method is characterized in that: mixture of macromolecular dihydric alcohol and a dihydroxybutyl-terminated polydimethylsiloxane is dehydrated, added with diisocyanate for reaction, then added with a bis propionic acid, a dihydric alcohol chain extender and a catalyst - dibutyl tin laurate, and is diluted by acrylic ester; temperature reduction and emulsion are performed on the mixture after reaction; chain extension reaction is performed in water by a multi-amine chain extender, and siloxane modified polyurethane dispersoid which contains acrylic ester monomer is prepared; and an initiator - potassium persulphate is added into the siloxane modified polyurethane dispersoid for emulsion polymerization.

特征是先将大分子二元醇与二端羟丁基聚二甲基硅氧烷的混合液脱水后加入二异氰酸酯，反应后加入二羟甲基丙酸、二元醇扩链剂和催化剂二月桂酸二丁基锡，并用丙烯酸酯进行稀释，反应后降温乳化，用多元胺扩链剂在水中进行扩链反应，得到含有丙烯酸酯单体的硅氧烷改性聚氨酯分散体，然后再通过加入引发剂过硫酸钾进行乳液聚合。

The constituents were extracted by some solvents. 18 constituents were isolated from Chloroform fraction by different chromatography. 15 constituents were identified by IR ,MS and NMR as follows: 3-sitosterol, P-sitosterylpalm itate,succinate acids, 1, 4-benzenediol, 1, 2-benzenediol, p-hydroxybenzaldehyde, syringaresinol, oleanolic acid, usolic acid, ethyl caffeate , Rosmarinic acid ethylster and etc. In such constituents ,nine compounds were isolated for first time from Origanum vulgare L..

牛至药材经水煮醇沉法所得浸膏，利用溶剂法和色谱法从中分离得到18个单体成分，通过IR、MS、NMR等波谱技术鉴定了其中的15个化合物，分别为β-谷甾醇(1)、β-胡萝卜苷(2)、琥珀酸(3)、对-二苯酚(4)、邻-二苯酚(5)、对羟基苯甲醛(6)、1.2-二羟基-4-异丙基-5-甲基苯(7)、新木脂素(8)、丁香脂素(9)、齐墩果酸(10)、乌苏酸(11)、4-二十六烯(12)、正二十六醇(13)、咖啡酸乙酯(14)、迷迭香酸乙酯(15)等，其中化合物3、4、5、6、7、8、9、14、15等9种化合物均为首次从该属植物中分离得到。

Polydimethyl siloxane, polydimethyl siloxane, sodium acrylate/sodium acryloyldimethyl taurate copolymer, isocetane, sorbitan ester-80, PCA sodium, ethanol, menthyl lactate, spicery, Contain Bulgaria wild rose pistil extract with tendering formula, moisturize and nourish skin, strengthen the firmness and toughness of eye skin, and recover eye skin to moist, firm, tender and bright state.

环聚二甲基硅氧烷、聚二甲基硅氧烷、丙烯酸钠/丙烯酰二甲基牛磺酸钠共聚物、异十六烷，聚山梨醇酯-80、PCA 钠、乙醇、薄荷醇乳酸酯、香精、蕴含自保加利亚野生玫瑰精华成份调和而成的嫩肤配方，保湿滋养，增强眼部弹性及韧性，回复眼部肌肤柔润、富有弹性，令眼部肌肤幼滑紧致、水嫩柔润、神采明亮。

The enzymolytic products identified were:diisopro-pylaminoethanethiol through the breakdown of P-S bond, and its oxidized product, N, N'-dithiodiethylene-bis ; and diisopropyla-minochloroethane through the breakdown of S-C bond.

VS与电鳐乙酰胆碱酯酶作用的主要产物是： P—S键断裂产物二异丙氨基乙硫醇，该化合物在水溶液中不稳定，可进一步氧化为N，N＇-双二异丙氨基乙基二硫醚；S—C键断裂产物二异丙氨基氯乙烷。

The main components were myristic acid (19.37%), palmitic acid methyl ester(7.56%), lascorbic acid 2,6dihexadecanoate(6.27%), 8,11octadecadienoicacid methyl ester(5.22%), heptadecane(4.82%), lauryl ethoxylate(2.98%), 2isopropyl5methyl1heptanol (2.62%), tetracosanoic acid methyl ester(2.12%),2ethyl2methyltridecanol (2.08%), et al.

其化学成分主要为肉豆蔻酸(19.37%)，棕榈酸甲酯(7.56%)，2，6十六烷基1抗坏血酸酯(6.27%)，8，11十八碳二烯酸甲酯（5.22%），十七烷（4.82%），十二烷基乙氧基醚（2.98%），2异丙基5甲基1庚醇(2.62%)，二十四烷酸甲酯（2.12%），2乙基2甲基十三醇（2.08%）等。

The catalytic performance of PhTMG was evaluated in the reaction for synthesis of diethylene glycol bis via carbon dioxide route and the highest yield of ADC was 95.3%.

考察了PhTMG对以二甘醇、氯丙烯和CO2为原料合成二甘醇双烯丙基碳酸酯反应的催化性能，ADC的最高收率为95.3%。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。