丙二醇

In this study, we carried out the allylation of anilines with allylic acetates in PEG-H2O system in the presence of palladium as catalyst. N-allylation of anilines was achieved.

在本研究中，我们完成利用钯催化剂，在水及聚乙二醇系统中，使苯胺类和乙酸烯丙酯类进行烯丙基化反应，并探讨各苯胺类反应物之结果。

The diol ester compound was used as a new-type internal electron donor forZiegler-Natta catalyst system recently.

二醇酯类化合物是近年提出的用于丙烯聚合催化剂的新型内给电子体，以它为内给电子体的Ziegler-Natta催化体系催化丙烯聚合得到的聚合物具有等规度高，易于加工等优良性能。

The affections on the yield of DLLA caused by catalyst, temperature and time etc. were studied. By using ethylene glycol as diluent, the distillate temperature of DLLA was lowed and the carbonization phenomenon could be avoided, which caused the yield of DLLA increasing from 36.8% to 51.3%. The molecular weight of PDLLA prepared by this method could reach 184,000. DLLA and PDLLA was characterized and analyzed by DSC, XRD and IR.The key of direct method to synthesize PDLLA is the exclusion of H2O from reaction system.

丙交酯开环聚合制备PDLLA的关键在于中间体D，L-丙交酯的制备，研究了催化剂、反应温度、反应时间等因素对DLLA产率的影响，通过在反应体系中加入稀释剂乙二醇，DLLA的馏出温度明显降低，避免了DLLA在蒸馏过程中产生碳化现象，并使DLLA的平均产率由36.8％提高至51.3％，制备的PDLLA分子量最大值达18.4万。

Objective To study the pH and temperature sensitive properties of sulfamerazine oligomers-polyε-caprolactone-co- DL -lactide-b-ethyleneglycol- b -ε-caprolactone-co-DL-lactide-sulfamerazine oligomers（OSM1-PCLA-PEG-PCLA-OSM1）block copolymer and evaluate sustained release effect of 5-fluorouracil release from the loaded hydrogel in vitro.

摘要目的为嵌段共聚物磺胺甲嘧啶低聚物-聚-ε-己内酯-丙交酯-聚乙二醇-聚-ε-己内酯-丙交酯-磺胺甲嘧啶低聚物（sulfamerazine oligomers-poly(ε-caprolactone-co- DL -lactide-b-ethyleneglycol- b-ε-caprolactone-co-DL-lactide)-sulfamerazine oligomers，OSM1-PCLA-PEG-PCLA-OSM1作为缓控释给药系统的载体提供依据。

The acetalization and ketalization of various aldehydes and ketones with glycerol by using KHSO4 as catalyst were studied. Effect of reaction time, mole ratio of reactants and amount of catalyst on yield of acetals were investigated.

研究了在KHSO4催化下，丙三醇与环己酮、丁酮、丙酮、丙醛、丁醛、异丁醛、戊醛、异戊醛、正辛醛、二苯甲酮、苯甲醛等十余种醛的缩合反应。

A set of laser monitoring observation system to be used for measure the solubility with a high speed, which is programmed heating apparatus , have designed. The solubility of 1,2-cyclohexanediol were measured in water, methyl acetate, acetic ester, propyl acetate, butyl acetate, methyl acrylate, ethyl acrylate, acetoacetic ester at different temperature.

另外，还建立了一套带激光监视系统，可以控制升温速率的溶解度测定实验装置，测定了反式-1，2-环己二醇在水、乙酸甲酯、乙酸乙酯、乙酸丙酯、乙酸丁酯、乙酰乙酸乙酯、丙烯酸甲酯、丙烯酸乙酯和甲基丙基酮等9个二元体系中的溶解度。

Aqua、Butylene Glycol、Dimethicone、Cyclomethicone、Glycerin And Glyceryl Acrylate/Acrylic Acid Copolymer And Propylene Glycol And PVM/MA Copolymer、Hydrolyzed Adansonia Digitata Extract、Commiphora Myrrha Extract、Hydrolyzed Callogen、Carbomer、Triethanolamine、Allantoin、Elastin 、Diazolidinyl Urea、Fragrance .

水、丁二醇、聚二甲基硅氧烷、环聚二甲基硅氧烷、甘油和甘油丙烯酸酯/丙烯酸共聚物和丙二醇和PVM /MA共聚物、水解猴面包树提取物、没药提取物、水解胶原、卡波姆、三乙醇胺、尿囊素、弹性蛋白、双咪唑烷基脲、香精。

Cycloalkylation of diethyl malonate and ethyl cyanoacetate with alkyl halide was investigated in the presence of toluene.

以甲苯为溶剂及带水剂，用粉末K2CO3代替常规使用的乙醇钠，在季铵盐和聚乙二醇混合相转移催化剂的存在下，含有活泼氢的丙二酸二乙酯和氰乙酸乙酯与二卤代物进行缩合反应，得到相应的环化物。

Three fullerene derivatives including a bisadduct of tetraethyl methano[60] fullerenediphosphona- te、a dimalonic acid[60]fullerene (DMA C60and fullerol were used to study the relationship between their photo-induced GSH depletion and structures.

采用二加成亚甲基富勒烯[60]二膦酸四乙酯、二加成富勒烯[60]丙二酸(DMA C60)和富勒醇 3种富勒烯衍生物研究富勒烯衍生物的结构与光诱导细胞内GSH耗竭的关系。

Mascagni were held into a solution containing calcium, ethylene glycol bis-amino tetmacetate and water, respectively. The effects of calcium were studied by measuring the ornamental quality of cut flowers and the physiological characteristics such as calmodulin, abscisic acid, gibberellins, zeatin, endogenous calcium, malondialdehyde and soluble sugar in florets.

以唐菖蒲红色品种'马加烈'切花为材料，瓶插在含有乙酸钙或钙离子专一性螯合剂乙二醇二乙醚二胺四乙酸的溶液中，分析乙酸钙对切花观赏品质的影响以及第1和第3朵小花内钙调素、脱落酸、赤霉素、玉米素、Ca(上标 2+)、丙二醛和可溶性糖含量的变化。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。