丙二烯

This invention applies mild condition uses substituent group triphenylamine aldehyde or triphenylamine dialdehyde as raw material to react by heating with 2-(5,5-dimethyl-3-vinylcyclohexenyl-2-enylidene)propanedinitrile group to produce the intermolecular charge transfer chromogen with high decomposition temperature, non-coplanar structure, and triphenylamine group.

本发明采用温和的手段，将取代基三苯胺单醛或取代基三苯胺双醛为原料与2-(3，5，5-三甲基环己烯-2-烯亚基)丙二腈共热生成具有高的热分解温度、非共平面空间结构的含三苯胺基团的分子内电荷转移生色团。

The photochemical graft copolymerization of isoprene on the surface of tetrafluoroethylene-propylene copolymer was effected by external magnetic field.

我们已经报道了异戊二烯在四氟乙烯一丙烯共聚物的光化学接枝反应，并且证实了该反应是按三重态机理进行的〔l。

A series of novel chiral aminophosphine ligands with binaphthyl backbone and partially reduced binaphthyl backbone were synthesized from optically pure NOBIN and H〓-NOBIN respectively. The effects of binaphthyl backbone and substitutes at the phosphorous atom on Pd (0)-catalyzed allylation of racemic 1, 3-dipheylprop-2-en-1-yl acetate with dimethyl malonate were systematically investigated.

从NOBIN出发合成了一系列膦上含有不同取代基的氮膦配体MAPs以及含有被部分还原的联萘骨架的氮膦配体H〓-MAPs，将此两类配体运用于钯催化的乙酸1，3-二苯基烯丙基酯与丙二酸二甲酯的反应中，考查了膦上取代基和配体骨架对反应的影响。

In addition to cyclopropanation, the typical Diels-Alder reaction between cyclopentadiene and N-acryloyl-l,3-oxazolidinine-2-one with Ll-L8/metal complexes have also been studied.

对于新配体在Diels-Alder反应中的对映选择性的研究，我们采用环戊二烯与3-丙烯酰基-2-噁唑啉酮的反应。

The polyester in these compositions is a 50% solution of a maleic acid-prophlene glycol condensate in diallyl phthalate.

在这些配方中的聚酯是马来酸--丙二醇缩合物在酞酸二烯丙酯中的50％溶液。

Ee were achieved in the Pd (0)-catalyzed asymmetric reaction of racemic 1, 3-dipheylprop-2-en-1-yl acetate with dimethyl malonate under the optimized reaction conditions.

在钯催化的乙酸1，3-二苯基烯丙基酯与丙二酸二甲酯的不对称反应中，取得了接近定量的收率和较好的对映选择性（71.2％ee）。

The free-radical addition reaction of malonic ester with a series of alkenes under the uniform conditions has been studied.

在相同反应条件下，进行一系列烯烃与丙二酸二乙酯的加成反应，求得产率与烯烃结构间的定量关系，即反S型曲线。

The results indicated isoprene was soon consumed under the condition of excess ozone. During the reaction, the major carbonyl products formed were methyl vinyl ketone, methacrolein, methylglyoxal, and formaldehyde. Formic acid, CO and CO2 were also among the products.

在反应温度(294±2)K，压力为1.01×10^5Pa空气，O3过量的条件下，异戊二烯很快反应完全，反应中生成的羰基产物主要包括甲基丙烯醛、甲基乙烯基酮、丙酮醛和甲醛；产物中还包括甲酸、一氧化碳和二氧化碳。

The result of potassium malonyloxyborohydride as a new hydroboration reagent reacts with terminal alkenes and alkynes is described.

介绍新的硼氢化试剂丙二酰氧基硼氢化钾与链端烯炔烃的作用，烯烃的硼氢化物在PTC条件下，插入∶CCl2 ，可得饱和羧酸；炔烃则难以与之硼氢化。

The premixing self-assembly solution of horseradish peroxide with poly(sodium 4-styrenesulfonate) is made by blending HRP and polyelectrolyte PSS,and the active.enzyme muhilayer biofilm is fabricated by altemate deposition of and PDDA on the surface of negative ionized PET.

以阳离子化的辣根过氧化物酶和阴离子聚苯乙烯磺酸钠的预混合溶液，与阳离子聚电解质聚二甲基二烯丙基氯化铵通过逐层组装，在阴离子化聚对苯二酸乙二酯表面构建了多层生物活性膜。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。