丙二烯

2-Substituted-3,4-dihydro-1(2H)-isoquinolinones were synthesized from methyl 3-hydroxy-ben- zoates via allyl etherification, Claisen rearrangement, oxidation, reductive amination and aminolysis for the first time.

以3-羟基-4-甲氧基苯甲酸甲酯等为原料，通过烯丙基醚化、Claisen重排、氧化、与伯胺反应、还原、分子内酯的胺解六步反应合成了一系列2-取代-3，4-二氢-1-异喹啉酮类化合物。

In the final step of the synthetic pathway leading to cabergoline, an allylic acid intermediate of Formula is reacted with N-(3-dimethylaminopropyl)-N-ethyl carbodiimide to produce cabergoline, i.e.

在卡麦角林合成路径的最后一步，分子式中的一个烯丙酸基中间体同碳二亚胺耦联剂反应生成卡麦角林，如

Then bis chloroformate was reacted with aromatic amines under the appropriate solvent and appropriate catalyst, after removed the solvent to obtain one kind of new amine-terminated polyether.

以聚氧化丙烯为基础原料，与光气在合适的溶剂下经过传统的低温、高温两段法光气化反应合成氯甲酸二酯，然后再与芳香多胺在合适的溶剂和催化剂下反应，脱除溶剂后得到一种新型的端胺基聚醚。

As a foundation raw material, propylene oxide was reacted with phosgene use the process tradition method that mean low temperature and high temperature two phosgenation sections to synthesis bis chloroformate .

以聚氧化丙烯为基础原料，与光气在合适的溶剂下经过传统的低温、高温两段法光气化反应合成氯甲酸二酯，然后再与芳香多胺在合适的溶剂和催化剂下反应，脱除溶剂后得到一种新型的端胺基聚醚。

To study the bioactive components from water soluble extract of the Chinese eaglewood, various column chromatography of Chinese eaglewood led to the isolation of ten compounds. Their structures were elucidated as 2,3-bis(3-hydroxyphenyl)- propan-1-ol (1), [(2R,3R)-3-(4-amino-3,5-dimethoxyphenyl)oxiran-2-yl]methanol (2), 8-chloro-4'- methoxy-5,6,7,3'-tetrahydroxy-2-(2-phenethyl)-5,6,7,8-tetrahydrochromone (3), 4'-methoxy-5,6,7,3'-tetrahydroxy-2--5,6,7,8-tetrahydrochromone (4), the isomer of 4 (5), 4'-methoxy-5,6,7,8-tetrahydroxy-2-(3'-hydroxyphenethyl)-5,6,7,8- tetrahydrochromenone (6), 4'-methoxyisoagarotetrol (7), 6-hydroxy-2-(2-hydroxy-2- phenethyl)-chromone (8), 6-hydroxy-2-(2-phenethyl)-chromone (9), 6-hydroxy-2-(4'- hydroxy-2-phenethyl)-chromone (10), and Guaiacylacetone (11) by means of spectral analysis and comparison with references.

为了进一步发现沉香中具有生理活性的化学成分，本文对国产沉香的水溶性成分进行了研究，从中分离得到11个化合物，通过红外、紫外、质谱、核磁共振(1H-NMR， 13C-NMR， COSY， HSQC， HMBC， ROESY)波谱解析，分别鉴定为：2，3-二(3-羟基苯基)-丙-1-醇(1)，[(2R，3R)-3-(4-氨基-3，5-二甲氧苯基)-2-氧化烯基]甲醇(2)，8-氯-4'-甲氧基-5，6，7，3'-四羟基-2-(2-苯乙基)-5，6，7，8-四氢色原酮(3)，4'-甲氧基-5，6，7，3'-四羟基-2-(2-苯乙基)-5，6，7，8-四氢色原酮(4)，化合物3的差向异构体(5)，4'-甲氧基-5，6，7，8-四羟基-2-(3'-羟基-2-苯乙基)-5，6，7，8-四氢色原酮(6)，4'-甲氧基异沉香四醇(7)，6-羟基-2-(2-羟基-2-苯乙基)色原酮(8)，6-羟基-2-(2-苯乙基)色原酮(9)，6-羟基-2-(4'-羟基-2-苯乙基)色原酮(10)和Guaiacylacetone (11)。

The results showed in the seven food preservative s,that calcium propionate had no effect on the growth of Peronophythoral litchii,while cinnamyl glyceroyl fumarate was the best.

结果表明：在所用的7种食品防腐剂中，丙酸钙对荔枝霜疫霉菌的生长无抑制作用，反丁烯二酸桂醇甘醇酯的抑菌效果最好

The trifluoroethylester silane was synthesized by modifying a PEG diacid to form the corresponding bistrifluoroethylester, followed by a reaction with 3-aminopropyltriethoxysilane.

通过用PEG二酸修饰合成三氟乙基乙烯醚硅烷，由此形成相应的双丙烯酰胺三氟乙基乙烯醚，再将其与3-APS相互作用。

Polyelectrolyte hydrogels based on n -alkyl methacrylate esters,acrylic acid and acrylamide cross-linked with 4,4′-diazobenzene were prepared.

合成了不同疏水链长的甲基丙烯酸酯、甲基丙烯酰胺及丙烯酸与 4 ，4′-二偶氮苯交联共聚的聚电解质凝胶。

Hydrogels based on n -alkyl methacrylate esters,acrylic acid and acrylamide cross-linked with 4,4′-diazobenzene were preparared.

合成了带不同疏水侧基的甲基丙烯酸酯、甲基丙烯酰胺及丙烯酸与 4，4′二偶氮苯交联共聚的凝胶。

A white-threadlike solid copolymer has been prepared from maleic anhydride, acrylamide and methyl acrylate initiated by dibenzoyl peroxide in an aqueous solution. The scale inhibiting efficiency of the copolymer to simulated water containing CaCO3 is studied.

以马来酸酐、丙烯酰胺、丙烯酸甲酯为单体，水为溶剂，过氧化二苯甲酰为引发剂合成一种白色丝状固体共聚物阻垢剂。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。