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丙二烯

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The presence of a gem-diphenylmethylene moiety at the vinylidene ligand with the appropriate terminal vinyl or alkynyl group along with the proper steric environment implements such a novel reactivity in the ruthenium vinylidene complexes.

因此推测丙二烯基与末端的不饱和键确实可以进行一些分子内的反应,但是gem-diphenylmethylene 官能基需位於适当的立体位置方可进行。

Allene oxide synthase is a key enzyme for JA biosynthesis.

丙二烯氧化物合成酶是茉莉酸生物合成的关键酶。

Allene is an isomer of methyl acetylene.

丙二烯是甲基乙炔的一种异构体。

In all cases, only the biboronic products with one boryl group adding to the middle carbon and the other to the nonsubstituted terminal carbon of the allene moiety were observed.

两个硼酯基都接於丙二烯基没有取代的末端双键上。立体选择性很高,主要的产物都是Z form的形式。

According to somephysiological characteristic in Camptotheca acuminata and several specific functionsof CPT, allene oxide cyclase, a key enzyme of jasmonites pathway, was isolated fromCamptotheca acuminata; mealwhile, it was investigated whether themRNA expression of CaAOC was related to the content of CPT in Camptothecaacuminata.

根据喜树自身的一些生理现象和喜树碱在其中可能参与的一些特殊作用,我们主要从喜树中克隆了茉莉酸合成途径的关键酶丙二烯氧化物环化酶(allene oxide cyclase,AOC)基因并考察了其对喜树碱含量的影响,同时还进行了其他方面的相关研究。

Similar to S-adenosylmethionine decarboxylase(B26),S-adenosylmethionine methyl-transferase(B70), allene oxide synthase(B38),ethylene receptor(B96),cytochrome P450(B58) and methionine synthase (B77) were found in ovaries of Pingyi Tiancha at 1d before the blossom day,which related to plant hormone and could participate in metabolic pathways of ethylene,polyamine,jasmonate acid and gibberellin,et al.,as well as had close relationship with maturity and senescence of plants.

在平邑甜茶开花前1d的子房中发现的S-腺苷甲硫氨酸脱羧酶(B26)、S-腺苷甲硫氨酸甲基转移酶(B70)、丙二烯氧化合酶(B38)、乙烯受体(B96)、细胞色素P450酶(B58)、甲硫氨酸合酶(B77)等相似基因片段与植物体内的生长素有关,将会参与乙烯、多胺、茉莉酸、赤霉素等的代谢途径,与植物的成熟和衰老具有密切的关系。

For example,the addition reaction with small molecular,the metathetical reaction with alkynes and Wittig reaction to prepare high-valent transtion-metal allenylidene complexes.

对于化合物11,详细研究了其与小分子加成反应、炔烃复分解反应以及通过Wittig反应制备高价态过渡金属丙二烯基卡宾化合物。

Examples of highly unsaturated hydrocarbons include without limitation acetylene, methylacetylene and propadiene.

高度不饱和烃的实例包括但不限于乙炔、甲基乙炔和丙二烯

In an embodiment, the selective hydrogenation catalysts of this disclosure are used in the hydrogenation of highly unsaturated hydrocarbons such as for example and without limitation acetylene, methylacetylene, propadiene or combinations thereof.

在实施方案中,本公开的选择性加氢催化剂被用于高度不饱和烃的加氢中,其中所述高度不饱和烃例如但不限于乙炔、甲基乙炔、丙二烯或它们的组合。

The unsaturated hydrocarbon stream 10 primarily comprises one or more unsaturated hydrocarbons, but it also contains one or more highly unsaturated hydrocarbons such as for example and without limitation acetylene, methylacetylene and propadiene.

所述不饱和烃料流10主要包含一种或多种不饱和烃,但它也含有一种或多种高度不饱和烃例如但不限于乙炔、甲基乙炔和丙二烯

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