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Group in the periodic table there are silver-white metallic luster of the solid metal transition element, atomic number Z = 26, atomic weight of 55847, chemical symbol Fe, there is a stable F isotope 5626Fe and a radioisotope 5526Fe, content of 5% of the earth's crust, accounting for elements of in the fourth place, the metal in the second melting point 1535 ℃, boiling point 2750 ℃, the relative density of 786, the external electronic structure 3d64s2, chemical reactions 2-6 tram F-volatile son, oxidation number of 0, 2, 3, 4 , 5 and 6, the chemical nature of the metal element is very lively, in the humid air combined with oxidation, but also directly with the sulfur, phosphorus, silicon, carbon together.

周期表中Ⅷ族有银白色金属光泽的固体金属过渡元素,原子序数Z=26,原子量55847,化学符号Fe,有一种稳定F同位素5626Fe和一种放射性同位素5526Fe,地壳中含量5%,占元素中第四位、金属中第二位熔点1535℃,沸点2750℃,相对密度786,外围电子结构3d64s2,化学反应时易丢失2—6个电F子,氧化数为0、+2、+3、+4、+5和+6、化学性质很活泼的金属元素,在潮湿空气中能与氧化合,也能直接与硫、磷、硅、碳化合。

Monododecylphosphate was prepared by esterification of lauryl alcohol with phosphoric acid(mass fraction 85%) on cesium phosphotungstate catalyst.

以磷钨酸铯盐为催化剂,由月桂醇和85%的磷酸直接酯化合成单十二烷基磷酸酯,考察了带水剂种类、反应时间、磷钨酸铯盐催化剂中的铯取代数、催化剂用量和月桂醇与磷酸摩尔比等条件对磷酸转化率及单十二烷基磷酸酯选择性的影响。

Melting point 3410 ℃, boiling point 560 ℃, relative density of 1935, F the external electronic structure of 5d46s2, in the chemical reaction time is very easy to lose 1-6 electronic, but also can get 1-2 electronic, so oxidation number of 0,± 1,± 2, 3, 4 , 5 and 6, with 6 price of the most stable compounds, such as WO3 does not dissolve in water, the air will form in the tungsten trioxide thin protective layer of tungsten, tungsten with fluorine at room temperature, chemical combination, red hot when there is no moisture and Bromine iodide together, red hot when you can and water reaction WO3, at room temperature reaction of tungsten with aqua regia, but the hot concentrated hydrochloric acid and sulfuric acid can only be played with its weak response, but molten nitrate, nitrite, too Hydrogen peroxide, sulfur steam, steam and other phosphorus can play intense reaction, high temperature can not be carbon, boron and silicon reaction of binary compounds, widely used in industrial tungsten steel and tungsten carbide, pure tungsten filament is used to the system, and X-ray tube Tube heating components, semiconductor components can be prepared tungsten silicide, tungsten industrial production is white or black tungsten ore tungsten ore refining.

熔点3410℃,沸点560℃,相对密度1935,F外围电子结构为5d46s2,在化学反应时很容易丢掉1—6个电子,也能得到1—2个电子,所以氧化数为0、±1、±2、+3、+4、+5和+6,以+6价化合物最稳定,如WO3不溶于水,空气中的钨会形成薄层三氧化钨保护层,钨能与氟在室温下化合,红热并无潮气时能与溴、碘化合,红热时还能和水反应生成WO3,室温下钨可与王水反应,但热的浓盐酸和硫酸只能与其起微弱反应,但对熔融的硝酸盐、亚硝酸盐、过氧化氢、硫蒸汽、磷蒸汽等能起激烈反应,高温下不能与碳、硼和硅反应生成二元化合物,工业上广泛使用钨钢和碳化钨,纯钨用来制灯丝、电子管和X射线管的发热元件,硅化钨可制半导体元件,钨工业生产是将白钨矿石或黑钨矿石精炼。

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