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The characteration of 15 will may provide a new pathfor searching new triboluminescent complexes. The triboluminescence maximum of 15is similar to that of its photoluminescence. The disorder of the thienyl rings and 〓groups in 15 may be responsible for its triboluminescent activity.

Eu的距离为4.2137(9)〓。两个桥联O原子与两个Eu构成一平面四边形,∠Eu(1)-O(7)-Eu(1A)和∠O(7)-Eu(1)-O(7A)分别为117.84(14)°和62.18(14)°。15的摩擦发光光谱与其光致发光光谱很类似,表明它们有相同的激发态。15的摩擦发光活性可能与其结构中噻吩环及〓的无序有关。

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