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The reaction has been drawing increased attention in that the reaction permit the use of organoboron compounds that are thermally stable and inert to water and oxygen.In this section microwave promoted Suzuki reaction of Sodium tetraphenylborate (NaBPh4) with carboxylic anhydrides catalyzed by Pd(PPh3)2Cl2 in THF was first reported.

第二章:微波辐射下Pd配合物催化NaBPh_4与羧酸酐的偶联反应研究本章中我们在微波辐射条件下,研究了PdCl_2(PPh_3)_2催化NaBPh_4与羧酸酐偶联反应,合成出了十种不对称芳酮,并分别考察了微波辐射功率、辐射时间、溶剂和原料配比等因素对反应的影响,优选出了较佳的反应条件,并根据文献及实验结果,讨论了可能的反应机理。

However, three isomers are obtained when [3(5)-〓-5(3)-MeS]pyrazole or[3(5)--5(3)-MeS]pyrazole reacts with 〓 in the same conditionpossibly owing to the influence of both the steric and electronic factors.

通过配体与〓的光化学反应,首次分离得到了不对称取代的双吡唑烷VIB金属配合物,但3位取代基的立体位阻减弱了双吡唑烷与〓的反应。

In this thesis, two synthetic routes for the incorporation of sugar moiety into C5(5") or C3(3") of salicylaldehyde part of Salen Mn complex were designed and several corresponding compounds were prepared, as carbohydrate derivatives are widely used in asymmetric catalytic reactions.

鉴于糖类衍生物在不对称催化反应中的广泛应用,设计了两条分别在Salen Mn配合物水杨醛部分C5(5′)、C3(3′)位并入糖基的路线并合成了相应的化合物。

In this paper, a procedure of nonlinear analysis of the cable-stayed bridge was developed based on the nonlinear theory of structures using the finite element method, in which the vehicle-bridge interaction element based on the concept of dynamic condensation is used. The influence of vehicles on the response of the cable-stayed bridge is studied by employing the spung mass model and the bridge model with and without considering cable vibration modes.

本文拟应用非线性力学分析程序与有限元素数值计算法,建立斜张桥的非线性分析程序,应用VBI的车桥互制元素配合动态浓缩的观念,以悬浮移动质量模拟车体对斜张桥的影响,并对考虑与不考虑缆索振动模态两种分析模型,做一对应分析比较。

The chiralMn complexes, especially Jacobsenscatalyst, display high enantioselectivity for asymmetric epoxidation of conjugated cis-di-, tri-and some tetrasubstituted prochiral alkenes in the NaClO biphasic system, but the epoxidationreaction generally requires a long reaction time even in the presence of an axial ligand.

在NaClO两相体系中,手性Mn配合物,尤其是Jacobsen催化剂,对共轭顺式二取代、三取代和部分四取代烯烃的不对称环氧化具有高的对映选择性,然而即使存在轴向配体,环氧化反应也通常需要长的反应时间。

The chiralMn complexes, especially Jacobsen\'scatalyst, display high enantioselectivity for asymmetric epoxidation of conjugated cis-di-, tri-and some tetrasubstituted prochiral alkenes in the NaClO biphasic system, but the epoxidationreaction generally requires a long reaction time even in the presence of an axial ligand.

在NaClO两相体系中,手性Mn配合物,尤其是Jacobsen催化剂,对共轭顺式二取代、三取代和部分四取代烯烃的不对称环氧化具有高的对映选择性,然而即使存在轴向配体,环氧化反应也通常需要长的反应时间。

Otherwise, if you choose to use the unpatched ROM, you'll need the official memory expansion pak.

A:破解版的可以用,但是需要配合相应的SLOT-2卡(G6,M3,SC),原版的还是不能用

In the paper, the factors of the pressure of gas-gathering pipes and high-pressured ammonia water was controlled unstably in the period of Linhuan Coking Limited Liability Company began to product were analyzed, then effective methods about how the coke workshop and chemicals workshop coordinate to control the pressure of gas-gathering pipes and high-pressured ammonia water well in production were made.

文章对临涣焦化股份有限公司投产初期集气管压力与高压氨水压力控制中的不稳定因素进行了分析,并对炼焦车间与化产车间在生产中怎样配合来做好集气管压力与高压氨水压力的控制提出了行之有效的方法。

Under the fire crew, the Red Cross, the news media positively coordinate, the exercise scene simulation and the real situation are extremely similar, the staff in 4 minutes time, rapidly, orderly evacuates the scene and completes the following activity to cause this fire drill to obtain the complete success.

在消防支队、红十字会、新闻媒体的积极配合下,演习情景的模拟与真实情况十分相似,员工在不到4分钟的时间内,迅速地、有秩序地撤离现场及完成后续活动使得本次消防演习取得圆满成功。

Eliminate the scar-free surgery: a variety of traumatic scars left by old or new scar bump, body parts, size, a maximum of 20 days treatment effect could be seen clearly, with a total has more than 90% efficiency; all of the scars resulting from burns, scar tissue lesion prominent extravasated blood swelling, joint adhesion traction, twin reduction, pigmentation, stasis purple, white spot, no surgery and skin grafting, simply tie in with the scrubbing liquid, the effect of scar will be a miracle.

免手术祛除疤痕:各种创伤留下的凹凸疤不分新旧疤痕、身体部位、面积大小、最多治疗20天都能见到明显效果,总有效率达90%以上;所有烧烫伤后造成的疤痕、患处组织增生性疤痕突出、红肿淤血、关节粘连牵拉、孪缩、色素沉着、淤血紫红、白斑,不用手术及植皮,只需配合擦洗液,疤痕的效果会出现奇迹。

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With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务,乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐,因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。

Closes the eye, the deep breathing, all no longer are the dreams as if......

关闭眼睛,深呼吸,一切不再是梦想,犹如。。。。。。