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Rare earth organometallic chemistry is closely interrelated with materials science, organic synthesis, life science. Rare earth organometallic complexes containing Ln-C σ bond and involving silylene-bridged fluorenyl are of important significance in macromolecular and asymmetry organic synthesis.

稀土金属有机化学与材料科学、有机合成、生命科学等学科密切相关,含Ln-Co键稀土金属有机配合物和含硅桥配体稀土金属有机配合物在高分子和有机合成不对称催化领域具有重要意义。

The synthesis of designed for an organizing functionalized system by supramolecular interaction is emphasized. We have designed three series of compounds and explored their properties.1 Two asymmetry derivatives from pyridinium and their complexes have been synthesized and characterized.

合成了两种不对称吡啶衍生物,将它们和硫氰酸盐组装成了三种配合物,得到了三个配合物单品,并分别用红外、核磁、电喷雾、单晶解析现代化学手段进行了表征,研究了它们的固体荧光性质。

Blizzard is estimated that not all air blue, but with Chimera shooting barbed Nailing Viperidae, is almost useless, I think at least more than the blue smoke point out, 10 seconds of the ultimate skills CD ah, do not hurt on the HP , how to target the consumption of blue and HP can harm a certain balance, or a change in thinking can also be in line with Chimera shooting barbed Viperidae Nailing the role of time, the goal of releasing any of the magic spell to increase consumption of 200 percent or 300 % consumption, such as the Blue penalty in disguise.

暴雪估计不让大家都空蓝,但是奇美拉射击配合蝰射钉刺,就几乎没用了,我认为至少要多吸点蓝出来,10秒CD的终极技能啊,不用在HP伤害上,怎么也要在消耗目标蓝上能和HP伤害有一定平衡,或换个思路也可以,在奇美拉射击配合蝰射钉刺的作用时间内,目标施放任何法术的魔法消耗增加200%或300%等变相耗蓝惩罚。

The chloroform solution of PMNHA extracts vanadium rapidly from 2.25―4.50mol/L hydrochloric acid solutions as a violet complex. The absorption maxmium of the violet complex is at 540nm. Many diverse ions, especially considerable quantity of Ti ions do not interfere with the determination of V.

该试剂的三氯甲烷溶液能很快从2.25―4.50mol/L HCl中萃取钒的紫色配合物,其配合物最大吸收在540nm,很多外来离子,特别是大量的钛不干扰钒的测定,钒含量在0―28μg?

In the asymmetric epoxidation of cis-β-methylstyrene, the selectivity and enantiometric excess for the epoxides reached 96% and 78%, respectively. The recyclability of the catalyst was also studied.

结果表明,该配合物对顺-β-甲基苯乙烯的不对称环氧化反应具有很好的催化性能,产物选择性达96%,ee值达78%,以顺-β-甲基苯乙烯为底物,m-CPBA为氧化剂,考察了该配合物催化剂的循环使用性能。

Yet by studying the ratio and scope rule of quorum in the Standing Committee of the People's Congress, it is discovered that the quorums of presence and voting are not set up scientifically, as a result, the voting result can not reflect the majority consent of all legislator when absent rate is high, or certain legislative members waive in voting, or these two things happen together.

然而,由于我国人大常委会的出席法定人数和表决法定人数的配合及其范围规则和比例规则的配合存在缺陷,因而在缺席人员较多、投弃权票较多或缺席者加弃权者较多的情况下,现行统计表决结果的规则不能够保障立法表决结果真实反映立法机关全体组成人员的多数意见。

To cooperate with new and old parts: although standard zero, components, but in between interchangeable in assembly parts, and to make the optimal coordination between trim, still needs a lot of work, such as the gear and rack, boring if after removal of gear various performance indicators are used by detecting without the need to change, and to replace worn rack, rack and rack positioning pin hole on installation bolt holes and should be first, reoccupy hand crossed positioning drills and tapered reamer to match the drill and match hinge, and after the installation of new and old super-modulus gear mesh clearance to achieve technical standards, this work takes about one day.

。新,旧零部件重新配合过程:尽管标准零,部件间具有互换性,但在装配中,要使新旧零部件间的配合达到最佳状态,仍需大量的修整工作,如镗床的齿轮与齿条,若拆卸后齿轮的各项性能指标经检测尚能使用不需更换,而齿条磨损严重需更换,那么齿条及齿条安装面上的定位销孔和定位螺钉孔就需先划线定位,再用手电钻及锥形铰刀重新配钻和配铰,且新齿条安装完毕后与旧齿轮的啮合间隙需达到技术要求的标准,此项工作需时约一天。

To cooperate with new and old parts: although standard zero, components, but in between interchangeable in assembly parts, and to make the optimal coordination between trim, still needs a lot of work, such as the gear and rack, boring if after removal of gear various performance indicators are used by detecting without the need to change, and to replace worn rack, rack and rack positioning pin hole on installation bolt holes and should be first, reoccupy hand crossed positioning drills and tapered reamer to match the drill and match hinge, and after the installation of new and old super-modulus gear mesh clearance to achieve technical standards, this work takes about one day.

。新,旧零部件重新配合过程:尽管标准零,部件间具有互换性,但在装配中,要使新旧零部件间旳配合达到最佳状态,仍需大量旳修整工作,如镗床旳齿轮与齿条,若拆卸后齿轮旳各项性能指标经检测尚能使用不需更换,而齿条磨损厉害需更换,那么齿条嘉逸条安装面上旳定位销孔和定位螺钉孔就需先划线定位,再用手电钻及锥形铰刀重新配钻和配铰,且新齿条安装完毕后与旧齿轮旳啮合间隙需达到技术要求旳标准,此项工作需时约─天。

The compositon and structure of two complexes differed from the complex ZnS (en 〓 synthesized in ethylenediamine. The precursors were pyrolysed in nitrogen stream at 400℃.

实验结果表明这种配合物结构、组成都不同于在纯乙二胺溶液中得到的中间体配合物。

And under our experiment condition complexes 1, 4 have shown non-chemical nucleases.

并发现配合物2,3,5,6均具有光化学核酸酶活性,在光照条件下能促使pBR 322 DNA单股断裂,还研究了它们的光核酸酶活性的作用机理;而在我们的实验条件下,配合物1和4均不具备光化学核酸酶活性。

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On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面,更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值,分为几个相等的区间作为横轴,并将各区间内所测定值依所出现的次数累积而成的面积,用柱子排起来的图形,也叫做柱状图。

You rap, you know we are not so good at rapping, huh?

你唱吧,你也知道我们并不那么擅长说唱,对吧?