不配合

These dendritic NOBIN derived Schiff base ligands have been applied to titanium catalyzed hetero-Diels-Alder reaction of Danishefshy's diene and aldehydes, affording the corresponding 2-substituted 2, 3-dihydro-4H-pyran-4-one in quantitative yields and excellent enantioselectivities (up to 97. 2%ee). Comparing the reactivities and enantioselectivities of reaction catalyzed by the titanium complexes of these Schiff base ligands, it was found that a series of ligands L〓 were superior to the other three series of ligands L〓, L〓 and L〓, a significant positive NLE and a dendrimer effect existed in the L〓 dendritic catalyst system. The disposition of the dendritic wedges and the dendron size in the ligands were observed to have a significant impact on the enantioselectivity of the reaction.

NOBIN衍生的树枝状大分子希夫碱手性配体与钛形成的配合物在催化不对称杂Diels-Alder反应中的应用将得到的四个系列NOBIN衍生的树枝状希夫碱三齿手性配体与四异丙氧基钛形成的配合物用于催化Danishefsky's diene与醛的不对称杂Diels-Alder反应，通过反应条件的优化，获得了定量的收率和最高达97.2％ee值的对映选择性；考察了这四个系列NOBIN衍生的树枝状希夫碱钛配合物的催化活性和对映选择性，结果发现它们的活性次序依次为L〓≈L〓＞L〓＞L〓，对映选择性次序依次为L〓＞L〓＞L〓＞L〓。

Defect noticed by most customers(greater than 75%) Low or a portion (less than 100%) of the product may have to be scrapped with no sorting, or vehicle/item repaired in repair department with a repair time less than a halfhour or 100% of product may have to be reworked, or vehicle/item repaired off-line but does not go to repair department or the product may have to be sorted, with no scrap, and a portion (less than 100%) reworked 6 5 Very low 4 or a portion (less than 100%) of the product may have Fit and finish/squeak and rattle item does not conform.

多数 (75%以上)顾客能发觉缺陷或一部分产品(小于100%)可能需要报废，不需分检或车辆/项目在翻修部门翻修少于0.5小时或100%的产品可能需要返工或者车辆/项目在线下翻修，不需送往翻修部门处理或产品可能需要分检，无需报废，但部分产品(小于100%)需返工 7 6 5 4 3 2 1 配合和外观/尖响和咔嗒响项目不舒服。50%顾或部分产品(小于100%)可能需要返工，无需报客能发觉缺陷废，在生产线上其他工位返工配合和外观/尖响和咔嗒响项目不舒服。

There are two independent molecules of ZnL or Co(IIL and two water molecules in one asymmetric unit of complex 1(or 2), the crystal structure of CuClL1·2H2O consists of one molecule of CuClL1 and two water solvate molecules in the asymmetric unit, while the ZnL·CH3OH (4) comprises of one molecule of ZnL and a methanol molecule in per unit.

在这四个金属配合物中，配合物(1)和配合物(2)的每个不对称单元中有两个独立的ML 分子和两个水分子，配合物(3)的每个不对称单元中有一个CuClL1分子和两个水分子，而配合物(4)的每个不对称单元中只有一个ZnL 分子和一个甲醇分子。

There are two independent molecules of ZnL or Co(IIL and two water moleculesin one asymmetric unit of complex 1(or 2), the crystal structure of CuClL_1·2H_2O consistsof one molecule of CuClL_1 and two water solvate molecules in the asymmetric unit,while the ZnL·CH3OH (4) comprises of one molecule of ZnL and a methanolmolecule in per unit.

在这四个金属配合物中，配合物(1)和配合物(2)的每个不对称单元中有两个独立的MLZn(IIL、CoL分子和两个水分子，配合物(3)的每个不对称单元中有一个CuClL_1分子和两个水分子，而配合物(4)的每个不对称单元中只有一个ZnL分子和一个甲醇分子。

The synthesis and characterization of asymmetric dinuclear and mononuclear vanadium complexes show that the pH value is very important for the products\' formation and isolation. In some pH range, theα-alkoxy bridge was easy to break and form asymmetric dinuclear and mononuclear vanadium structure.

三、不对称的双核钒和单核钒配合物的合成和表征显示，pH值对产物的形成和分离具有至关重要的作用。pH值在一定范围内，柠檬酸的烷氧基氧作为桥氧的化学键才容易断开，从而形成不对称的双核钒和单核钒结构。pH值不仅影响不对称双核V_2O_3钒配合物和单核钒配合物的形成，还关系到钒还原的速度。

Our purpose is simulating the catalytical action of enzyme in biologic system, so we can directly investigate the factors relating to the functions of enzyme by studying the catalyzing behavior of model molecules imitating enzyme\'s functions. And it is a base of synthesizing high performance model enzyme.

从得到的实验数据我们可以看出：锌是酯水解反应的活性中心；并且金属中心相同时，配位数相同的配合物，结构越简单，其催化酯水解效果越好；含有配位不饱和金属中心的锌配合物表现出更好的催化效果；配合物中咪唑基团的存在可有效的增强这个配合物催化酯水解的效果。

All the ligands and complexes have been characterized with ~1H-NMR, MS and EA.X-Ray single crystal diffraction reveals that zirconium complex containing the tert-butyl substituted N_2O_2 ligand is an oxo- and hydroxyl-bridged dinuclear structure, which is possibly formed by partial hydrolysis of chlorides at one of the zirconium centers. A tetranuclear zirconium complex has been obtained and chacaterized, which is formed by complete hydrolysis of the chlorides at the zirconium centers.

通过研究配合物的单晶结构，我们发现叔丁基取代的不对称N_2O_2配体与ZrCl_4反应生成的锆配合物为氧桥和羟基桥连接的双核锆配合物，中间过程涉及单核锆配合物中氯原子部分水解，并得到氯原子部分水解的双核锆配合物和全部水(来源：8e6eAB67C论文网www.abclunwen.com)解的四核锆配合物的晶体结构，在晶体培养过程中发现双核锆配合物能够以手性自发拆分结晶析出。

The United States hoped the Soviet Union being trouble in Afghanistan, so it increased the assistance to the Resistance and was passive to the Geneva Negotiations.

美国则希望苏联继续背着阿富汗这个&包袱&，因此，加强了对圣战者的政治支持和军事援助，同时对日内瓦谈判持消极、不配合的态度。

Despite all these advantages, the casing of the esi battery is not very well-moulded.

然而，esi 这枚电池的密合度实在有待改善，外壳颜色与机身不配合、贴纸和防滑胶容易脱落等情况更是一大败笔。

With these specific properties, the problem of how to make the beacon light on a uncooperative target become a light spot used for an adaptive optical system may be dealt with tentatively.

依此特性，初步探索不配合目标的信标光成为点光源用于自适应光学系统的问题。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。