不配合

The reaction has been drawing increased attention in that the reaction permit the use of organoboron compounds that are thermally stable and inert to water and oxygen.In this section microwave promoted Suzuki reaction of Sodium tetraphenylborate (NaBPh4) with carboxylic anhydrides catalyzed by Pd(PPh3)2Cl2 in THF was first reported.

第二章：微波辐射下Pd配合物催化NaBPh_4与羧酸酐的偶联反应研究本章中我们在微波辐射条件下，研究了PdCl_2(PPh_3)_2催化NaBPh_4与羧酸酐偶联反应，合成出了十种不对称芳酮，并分别考察了微波辐射功率、辐射时间、溶剂和原料配比等因素对反应的影响，优选出了较佳的反应条件，并根据文献及实验结果，讨论了可能的反应机理。

S-Naproxen was obtained by asymmetric cross-coupling reaction of 2-bromo- 6-methoxynaphthalene with organozinc reagent of ethyl α- bromopropionate, catalyzed by chiral β-aminoalkylphosphine-nickel complexes.

用β -氨基烷基膦的NiCl2 配合物为手性催化剂，以 6 -甲氧基- 2 -溴萘和α-溴代丙酸酯的有机锌试剂为原料，通过不对称交叉偶联反应合成S --萘普生。

Through condensing o-aminobenzoic acid, ethyl oxalyl chloride and ethylenediamine(or 1,2-propylenediamine), two new ligands N-benzoato-N′-(2- aminoethyl)oxamido(H3oxbe) and N-benzoato-N-(2-amino-2-methylethyl)oxamido(H3oxbt) have been synthesized. Their mononuclear complexes Na·1.5H2O and Na·1.5H2O have also been obtained.

2以邻氨基苯甲酸、草酸乙酯酰氯和乙二胺(或1，2-丙二胺)缩合制得了两种具有不对称草酰胺结构配体N-(2-苯甲酰基)-N&-(2-氨乙基)草酰胺(H3oxbe)和N-(2-苯甲酰基)-N&-(2-氨丙基)草酰胺(H3oxbt)，并得到了它们的单核配合物：Na·1.5H2O和Na·1.5H2O。

Equilibrium constants for reactions of ZnTPP (parasubstituted zinc tetraphenylporphyrins) with ligands of Schiff base complex in CH2Cl2 and several other solvents have been measured by visible spectral techniques, and determined by the method of Rose-Drago.

用紫外-可见光谱和Rose-Drago数据处理方法对多种新型空间不对称含咪唑基团金属Schiff碱配合物与取代四苯基卟啉锌轴向配位反应平衡常数进行了测量。

At present, consensus about rural industrialization and rural population migrants has not been achieved in the economic literatures, controversies still exist about strategic status of rural modernization and choices of rural industrialization and choices of rural population migrants ;in pr-actice , although usually emphasize the importance of problem of the farmer and rural and agriculture , but always did not put a premium on the rural reformation, only from the perspective of provisionment security and social stablity and expanding demand . Various policies does not coordi 梟ated.

目前，理论界对农村工业化和农村人口城镇化的认识还不一致，对农村经济现代化的战略地位、农村工业化道路选择、农村人口城镇化道路选择等问题存在一定的分歧；在实践中，虽然经常强调农业和农民问题的重要性，但始终没有将进一步推进以农村为重心的改革提高到战略高度，只从保障粮食供给和稳定社会秩序、扩大内需的角度来强调&三农&工作的重要性，各项政策措施缺少协调配合。

However, three isomers are obtained when [3(5)-〓-5(3)-MeS]pyrazole or[3(5)--5(3)-MeS]pyrazole reacts with 〓 in the same conditionpossibly owing to the influence of both the steric and electronic factors.

通过配体与〓的光化学反应，首次分离得到了不对称取代的双吡唑烷VIB金属配合物，但3位取代基的立体位阻减弱了双吡唑烷与〓的反应。

Our main research work has been focused on the synthesis, characterization of substituted salicylaldehyde Schiff bases and their complexes, which are not reported in articles now. There are twenty-one new compounds in total.

本论文研究了目前未见国内外文献报道的、水杨醛中苯环上含有取代基的水杨醛缩脱氢枞胺Schiff碱及其金属配合物的合成与表征，共计获得了21个新的化合物，从而为后期生物活性的测定及不对称催化提供研究基础和实验样品。

In this thesis, two synthetic routes for the incorporation of sugar moiety into C5(5") or C3(3") of salicylaldehyde part of Salen Mn complex were designed and several corresponding compounds were prepared, as carbohydrate derivatives are widely used in asymmetric catalytic reactions.

鉴于糖类衍生物在不对称催化反应中的广泛应用，设计了两条分别在Salen Mn配合物水杨醛部分C5(5′)、C3(3′)位并入糖基的路线并合成了相应的化合物。

Except this, cooperate with eras requirement supply quiet soundlessness not incur disturb de work environment, much more we chief tell beg.

除此以外，配合时代需求提供安静无声不受干扰的工作环境，更是我们主要的诉求。

In this paper, a procedure of nonlinear analysis of the cable-stayed bridge was developed based on the nonlinear theory of structures using the finite element method, in which the vehicle-bridge interaction element based on the concept of dynamic condensation is used. The influence of vehicles on the response of the cable-stayed bridge is studied by employing the spung mass model and the bridge model with and without considering cable vibration modes.

本文拟应用非线性力学分析程序与有限元素数值计算法，建立斜张桥的非线性分析程序，应用VBI的车桥互制元素配合动态浓缩的观念，以悬浮移动质量模拟车体对斜张桥的影响，并对考虑与不考虑缆索振动模态两种分析模型，做一对应分析比较。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。