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All alkaline earth elements have an oxidation number of +2, making them very reactive. Because of their reactivity, the alkaline metals are not found free in nature.

所有的碱土金属元素的化合价都是+2,这使他们非常活泼,因为他们非常活泼,也不在自然界中直接出现。

The heaviest noble gas, it is colourless, odourless, tasteless, radioactive, and almost completely unreactive (forming compounds only with fluorine).

氡是最重的稀有气体,无色,无臭,无味,有放射性,相对不活泼

Chapter 2 presents our studies on aromatic amide-derived phosphine applied to room temperature Suzuki cross-coupling of unactivated aryl chlorides with aryl boronic acids.

第二章主要研究了芳基酰胺衍生的膦配体在不活泼的氯代芳烃同芳基硼酸在室温下的Suzuki偶联反应中的应用。

The condensation of aromatic aldehydes with active methylene compounds like malononitrile, cyanoacetamide and ethyl cyanoacetate has been found to proceed very efficiently at room temperature giving excellent yields, but the condensation of heteroaromatic,α,β-unsaturated and aliphatic aldehydes with active methylene compounds proceeded smoothly in 50~65℃ with good yields and the reactions of aromatic, aliphatic ketones as well as p-phthalaldehyde with malononitrile also proceeded in 75~85℃ with moderate yields.

芳香醛与活泼亚甲基化合物如丙二腈、氰基乙酸乙酯、氰基乙酰胺的缩合在室温下即能顺利进行,获得了很高的收率;而对于杂环芳醛、α,β-不饱和的醛以及脂肪醛与活泼亚甲基化合物的缩合,需在50~65℃下进行,也取得了很高的收率;对于脂肪酮、芳香酮以及二元醛与丙二腈的缩合在75~85℃下也能顺利地进行,获得中等以上的收率。

To explore new synthetic methods, we set out a careful investigation of the reaction of benzimidazolium salt with many nucleophilic agents, including the active aromatic compounds and heteratom nucleophilic agents, and found that the quaternary C=N is not so active; when benzimidazolium salt is reacted with big nitrogen nucleophilic agent? phthalimide, it does not give the expected addition product, instead, produces N-alkyl phthalimide through alkyl-transfermation from benzimidazolium salt to phthalimide.

为了开发新的合成方法,研究了苯并咪唑盐与各种亲核试剂(活泼芳环与杂原子亲核试剂)的反应,发现苯并咪唑盐不与活泼芳环及杂原子亲核试剂发生2位加成反应;在与体积较大的位阻型N亲核试剂邻苯二甲酚亚胺反应时,未得到亲核试剂与极化的C=N的加成产物,而是得到N烷基化的邻苯二甲酰亚胺,进一步研究表明,苯并咪唑盐将1(3)位N上的烷基转移给了邻苯二甲酰亚胺,并讨论了其反应机理和取代基,溶剂效应。

By following the "self-assisted molecular editing" protocol first established in our labs,a number of Aphos ligands were efficiently prepared from a single starting material and they were screened for catalytic efficacy, leading to the discovery of the best-performing Aphos appended with a 3-nitrophenyl group at the C4 position.Combination of this Aphos with Pd_2 offers a precatalyst for successful cross-coupling of unactivated aryl chlorides with aryl boronic acids at room temperature.The reactions took place under mild basic conditions to produce the products in high yields.

通过我们首次提出的&自助分子剪裁&的概念从单一起始物快速合成和筛选了一系列膦配体,并发现C4位含3-硝基苯基的的膦配体和醋酸钯联用可以在室温下顺利地催化不活泼氯代芳烃和芳基硼酸的偶联反应,反应条件温和且产物收率很高。

Under these conditions several aryl iodides bearing a wide range of functional groups were converted into the corresponding aryl azides in good yields.

在重新优化后的条件下,大部分不活泼芳基溴化物可以与叠氮化钠发生交叉偶联反应得到良好收率的芳基叠氮化合物,但是有拉电子基团取代的芳基溴化物与叠氮化钠的偶联反应则难以进行。

Under these conditions several aryl iodides bearing awide range of functional groups were converted into the corresponding aryl azides in good yields.

在重新优化后的条件下,大部分不活泼芳基溴化物可以与叠氮化钠发生交叉偶联反应得到良好收率的芳基叠氮化储蓄型投资银条合物,但是有拉电子基团取代的芳基溴化物与叠氮化钠的偶联反应则难以进行。

Tungsten is relatively inert , but compounds (in which it has various valences) are known.

钨的化学性质相对不活泼,但已经知道它有化合物。

A reduced model coneentrates all external excitations into expressions representing the motion of the pendulum suspension point.this approach assumes that the payload motions are influenced by,but do not have a significant influence on,the platform motion;that is,the inertial coordinates of the suspension point are known functions of time T.

被减少的样板 coneentrates 进入表现钟摆中止点的运动的表达之内的所有外部的刺激。这方法承担负载量提议被影响被,但是没有重要的影响力在,之上月台提议;也就是说,中止点的不活泼坐标是时间 T 的已知功能。

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这一模式非常关注商人的网络信用基础。

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