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Three chiral phosphorus ligands were prepared using anisole as the startingat material.Their applications in the asymmetric hydroformylation and asymmetric conjug ed addition of diethylzinc to enones were investigated.

以苯甲醚为原料,合成了三种新的手性含磷配体,考察了三种配体在不对称氢甲酰化反应和ZnEt2对环己烯酮的不对称共轭加成反应中的应用。

It is inextricably linked with existing substance, which is asymmetric; it also asymmetric with rich system of science itself and infinity expansibility.

这和存在的事物,具有千丝万缕的联系,不对称;也和科学本身丰富的体系、无限的可发展性,不对称。

Overcoming the inability of Forcing Decoupling method, this paper presents a new method-To-Step-Additional-Stiffness method to calculate the translation-torsion coupling seismic response of tile symmetric structures with asymmetrically viscous dampers.

摘要克服强行解耦法不能求解对称结构由于不对称安装粘滞消能器而产生平扭耦合地震作用的不足,提出了一种求解该种情况下的平扭耦合地震反应的新方法-两步附加刚度法。

In chapter 1, as a preparative knowledge, the main results about symmetry theoryand Wus method are introduced, in addition some fundamental definitions, such as trans-formation group, infinitesimal operator, prolongation, first integral, infinitesimal criterionfbr invariance of an ODE, characteristic set are recalled.

第一章中作为预备知识简单介绍了对称理论和吴方法,并给出了一些基本概念和理论,如变换群、无穷小算子、算子延拓、首次积分、微分方程在对称下不变的判别准则和微分特征列集算法。

This book is about a theory of markedness and its application in describing and explaining various asymmetrical phenomena in Chinese grammar.

本书将"标记理论"运用于语法研究,对汉语语法中各种对称和不对称现象作出统一的描写和解释。

For certain reactions, they function as chemoenzymes and produce both good chemical and optical yields. Over the last decade a wide range of C〓-symmetric chiral bisoxazoline ligands have been synthesized from readily available diacid derivatives and amino alcohols.

但是,手性双噁唑啉催化的某些不对称反应的机理以及影响双噁唑啉分子催化性能的结构要素目前仍不是很清楚,诱导某些反应的不对称选择性仍有待于进一步提高,因此需设计和合成新的双噁唑啉类配体。

Considerable attention has really been focused on ionic liquids as "green" alternatives to classical environmentally damaging organic solvents in many fields such as in organosynthesis, material, catalysis, electrochemistry, biochemistry, physicochemistry, separation and so on. However, there have been only a few examples of chiral ILs have been reported so far, and ILs possessing chirality are having been synthesized aimed at application in asymmetric catalytic reaction.

离子液体在许多领域如电化学、有机合成、催化、生物化学、物理化学、材料及分离等的绿色替代溶剂技术引起了人们的重视,然而,有关手性离子液体的合成与应用的报道比较少,含有手性片段的离子液体不断被合成出来并期望在不对称催化反应中得到应用,但是成功的例子不多,使用手性离子液体在不对称催化反应中还在初始的探索阶段。

The applications of various organocatalysts in asymmetric Diels-Alder reaction and the asymmetric induction mechanism are reviewed in this paper. Contents

本文对各类有机催化剂在有机催化不对称Diels-Alder反应中的应用研究进展,以及不对称诱导反应的机理进行了评述。

According to the result of asymmetric Diels-Alder reaction of phenyl-sulfonyl a , P-unsaturated ketones and cyclopentadiene catalyzed by chiral Titanium catalysts and the structure of crystal, we discussed the mechanism of asymmetric Diels-Alder reaction.

根据苯磺酞基取代的a,p一不饱和酮与环戊二烯在钦手性金属催化剂存在下的不对称Diels一Alder反应的结果以及我们测得的单晶结构,初步探讨了不对称催化Die1S一Alder反应的机理。

The Research about the Synthesis of Phenylsulfonyl α,β-unsaturated Ketones and Their Applications in Asymmetric Diels-Alder Reaction Catalyzed by Lewis Acid and Chiral Titanium Reagents.

苯磺酰基取代的α,β-不饱和酮的合成及其在不对称催化Diels-Alder反应中的研究中文名称:苯磺酰基取代的α,β-不饱和酮的合成及其在不对称催化Diels-Alder反应中的研究

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And discuss some key point of integrated management system design, include hazard identification and risk assessment and risk control in the occupational health and safety management, the measure of satisfaction target of customer, the flawlessness of law system, the integration of the integrated management system and enterprise standardization system, unify lead institution and work orgnization, integreted internal audit and integrated management review.

同时,论述了一体化管理体系构建中的几个主要问题,包括职业健康安全管理中的危险源辨识、风险评价和风险控制、顾客满意度的科学监测、法律、法规体系的完善、一体化管理体系与企业标准化体系的有机结合、统一的领导机构和工作机构、一体化的内部审核和管理评审。

Deepwater Taranaki is investigated for its petroleum potential, using all available seismic data tied to shallow-water wells.

运用与浅水井相关的现有全部震波探测数据考察了深海区塔拉纳基盆地的油藏前景。

If you're huffing and puffing at any point during the run, slow down and make sure you can take deep breathes.

如果你任何时候在跑步过程中气喘如牛,降低速度并且确保你能够深呼吸。