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The reaction rate was mainlyinfluenced by temperature but nearly uninfluenced by concentration of H2S and particle scaleswhen they were small.

温度对预硫化反应速率的影响较为显著;在较低的硫化氢浓度和较小的催化剂粒径范围内,预硫化宏观反应速率几乎不受二者的影响。

The asymmetric ring-opening aminolysis of meso-epoxides represents one of the most important reactions in organic synthesis,giving rise to enantio-enriched aminoalcohol products with two chiral centers.

中文摘要:胺类对内消旋环氧化合物的不对称开环是一类重要的反应,反应生成两个手性中心的氨基醇化合物在有机合成中有着重要的应用。

The isomerization principle of independent double bonds of unsaturated fatty acids from Chinese featural arboroid oils-stillingia oil was first studied in the paper in China. The synthesis principle, properties of products and practical experiment of the derivatives of conjugate acids were also discussed.

本文以中国特产木本油脂—梓油为原料,在国内首次对油脂不饱和脂肪酸孤立双键的异构化反应规律进行了系统的研究,并以异构化反应所得共轭酸为原料,对共轭酸衍生物系统产品的合成规律、产品性能及应用性实验进行了一定程度的探索。

Enzyme as a biological catalyst is very sensitive to the environment , physical, chemical and biological factors.In the other hand it is difficult to purify from the reaction products. What's more it can not make a continuous operation.All those astrict the reaction.Under this condition, enzyme immobilization was put forward and developed.

酶作为一种生物催化剂,对环境十分敏感,易受物理、化学和生物等因素的影响而失活,而且反应后混入产品,纯化困难,不能实现连续操作,这些难以克服的现象大大限制了酶促反应在工业中的应用,在这种条件下,固定化酶的概念和技术得以提出和发展。

Grasp the electron delocolization theory; be capable of judging the relative stability of allylic and benzylic free radicals and carbocations, know the relative stability of dienes and other multiple unsaturated hydrocarbons; grasp the characteristics for the nucleophilic substitution reactions of allyl halides and benzyl halides, and the addition reactions of conjugate dienes.

掌握电子非定域化理论;能够分析判断烯丙基、苄基自由基和正离子的稳定性和二烯及多重不饱和碳氢化合物的稳定性;掌握烯丙基、苄基卤代物的亲核取代反应特性和共轭二烯的加成反应。

The chemical structure of the product was characterized by means of the melting point and IR. The results show that tetraethylammonium bromide which was used as a phase transfer catalyst in this reaction had optimization effect on the interfacial diffusive reaction of BTC and PNP. Higher concentration of sodium hydroxide, lower temperature and a higher dosage of BTC produced a small amount of 4-nitrophenyl chloroformate, while lower concentration of sodium hydroxide and a lower dosage of BTC made reaction incomplete, which affected the yield.

结果表明,在碳酸二(4-硝基苯基)酯合成中使用的相转移催化剂四乙基溴化铵对受界面扩散控制的BTC气与对硝基酚钠反应有良好的相转移催化效果;氢氧化钠质量分数较低时,酚钠盐向溶有BTC的油相扩散速度较小,较高时会产生氯甲酸对硝基苯酯;温度较低、BTC量较高时,会产生少量氯甲酸对硝基苯酯,BTC用量较低会使反应不完全,这些都影响着收率。

The result was compared with oxidations of cyclohexene without irradiation and at irradiation without catalyst.

另外,本文还研究了各种类型的催化剂在中压汞灯下光催化环己烯的氧化反应,结果表明,无论上述的哪种催化剂,在中压汞灯下光催化环己烯氧化反应,都得不到环氧环己烷,生成的产物主要为水和二氧化碳。

According to the structure and property of feather fibre fabric and the sizing ingredients,choosing the biological catalyst-enzyme which has high catalysis efficiency and undivided reactivity,to desize the feather fibre fabric ,the paste would be removed quickly and efficiently.

在羽毛纤维织物结构性能基础上,结合织物上所含浆料的组成,选择催化效率高、反应专一的生物催化剂酶对羽毛纤维织物进行退浆处理,可以快速、高效退除织物上的浆料,同时酶退浆时反应条件温和,不需要高温、高压、强酸、强碱的作用条件;采用超声波对羽毛纤维织物进行退浆可以缩短处理时间、降低处理温度,减少药剂用量,而处理效果优于常规法退浆。

The cracking reaction of Ethylidene diacetate is the key step to manufacture vinyl acetate from C1 compound. The technological development is based on the study of the reaction property and the reactor, and is guided by the process simulation results.

二醋酸亚乙酯裂解反应是C1路线制醋酸乙烯的关键步骤,其工艺的开发离不开反应过程的研究和反应器的确定,而过程数学模拟可以指导过程开发。

Analogous complexes 3a" and 4a"= CpRu(PPh32, Ar = para-C6H4OMe containing methoxy group at the para-position of gem-diphenyl group were similarly obtained from protonation of the corresponding acetylide complexes via formation of vinylidene intermediate. But only complex 3a'= CpRu(PPh32, Ar2 = fluorenyl is stable in solution, and decomposed to unidentified complex when heated to reflux in THF. Deprotonation of complex 4a in the presence of base gives neutral acetylide complex 6a.

在两个相邻位置的苯基对位位置上接有一甲氧基的衍生物3a&和4a&也可利用类似的质子化反应合成,唯有错合物3a'= CpRu(PPh32, Ar2 = fluorenyl 可以稳定於溶液中,不会进行上述反应,如将其溶於四氢呋喃溶液加热至沸腾则会分解产生无法鉴定的化合物。

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