不反应的

In this dissertation, eight novel bisoxazoline ligands L1-L8 containing 2,2-dimethyl cyclopropane units have been synthesized and evaluated in the asymmetric cyclopropanation and Diels-Alder reaction, moreover the influence of many factors on the enantioselectivity of the new ligands was studied in detail.

在本论文中，我们设计并合成了8个新型双噁唑啉手性配体L1～L8，并研究它们在环丙烷化反应与Diels-Alder反应中的对映选择性，以及影响配体不对称诱导性能的各种因素。

An experiment of water-rock interaction in the packed bed reactor between granodiorite and pure water under the condition of stable pressure of 22 MPa and continuous current has been performed to study the formation process of the Hucun skarn copper deposit in Tongling,Anhui.

以铜陵胡村矽卡岩型铜矿为研究对象，选择与成矿关系密切的花岗闪长岩，在22MPa恒压、不间断流动条件下，与纯水在叠层反应器中进行水-岩反应动力学实验研究。结果表明，水-岩反应速率与流体流速成反相关，与流体在体系内的停顿时间成正相关。

You respond to every challenge according to your conditioning and your conditioning being inadequate will always react inadequately.

你根据你的限制来对每个挑战反应，而不当的限制总是产生不当地反应。

The soil urease and invertase activity effected by Hg was investigated in different fertility soils. The results show that soil urease activity、maximum reaction velocity (Vmax、Vmax/Km) and reaction velocity constant k have remarkably negative correlation with Hg concentration so that these can be used as ecological indexes of soil polluted by Hg, Km changes a little indicating that the reaction mechanism of Hg and urease is nonreversible competitive restraint. Urease of low soil fertility is more damaged by Hg than that of high soil fertility, with severe pollution at Hg concentration of 6.00 and 14.79mg/kg respectively; while invertase is less sensitive to Hg than urease. Cultural time has less influence on the relationship of soil enzyme and Hg concentration.

对不同肥力土壤脲酶和转化酶活性受汞影响进行了研究，结果显示，土壤脲酶活性、最大反应速度Vmax 、Vmax/Km和反应速度常数k与汞浓度呈现显著或极显著负相关关系，表明其可作为土壤汞污染的生态指标；米氏常数Km则变化较小，表明汞与脲酶作用机理为不可逆竞争抑制；低肥力土壤脲酶比高肥力土壤脲酶受汞毒害作用更强，当汞浓度分别为6.00和14.79mg/kg时即达到严重污染；而转化酶对汞的敏感性较差；培养时间对土壤酶与汞浓度间关系影响较小。

Therelationship of the amount of catalyst and the ee% of product was seen to be negative nonlin-ear. Catalyst 3 was used in the enantioselective addition of diethylzinc to aromatic aldehydesand gave good results. The configuration of products was determined by the configuration ofthe catalysts' chiral carbon linked with hydroxy group. Using β- amino alcohols bearing only one chiral center as catalysts for the enantiose-lective addition were studied. D-N, N-dialkyl-2-amino butanol gave poor catalytic effect be-cause of their structure. The configuration of the product is the same as the catalyst. Anotherkind of β- amino alcohols - phenylglycine derivatives and valine derivatives have chiralcenter on the carbon linked with amino group. Catalyzed by-phenylglycine derivatives 6,7, 9, 10, the reactions gave satisfied results. The optical yields exceeded 80%.

在探讨了含有两个手性中心的β-氨基醇之后，选择了只有一个手性中心的β-氨基醇，一是手性中心为连羟基的手性碳原子：D-N，N-二烷基-2-氨基丁醇；二是手性中心为连氨基的手性碳原子：D-苯基甘氨酸衍生物和L-缬氨酸衍生物。D-2-氨基丁醇的催化效果不太好，这与其结构的空间位阻较小有关系，反应产物与连羟基手性碳构型一致；由苯基甘氨酸和缬氨酸出发合成五种β-氨基醇6-10，研究了不同ee％的-6作用下的二乙基锌-苯甲醛加成反应，发现该催化剂具有不对称放大效应；-7，9，lO的催化效果也比较令人满意，光学产率80％以上，所得产物构型与催化剂构型一致。

Protease treatment of the plasma membranes could abolish the binding but NaIO_4 and glycosidase could not, indicating that nsLTP144 bound to plasma membranes protein without carbohydrate moiety. Using the homobifunctional cross-linking regent bissuberate (BS~3) and rice plasma membranes incubated with ~(125)I-Trx-nsLTP144, we identified, after SDS-polyacrylamide gel electrophoresis and autoradiography, a putative protein receptor on the rice plasma membranes with the molecular mass around 60 kDa. NsLTP144 can not trigger extracelluar alkalization in arabidopsis, but can abolish the extracellular alkalization effect of phytopathogen elicitor cryptogein, suggesting that cryptogein and nsLTP144 may bind to the same membrane protein. In vitro pull-down assay showed that nsLTP144 interacted with OsCaM1, a possible extracellular calmodulin, implying that nsLTP144 and OsCaM1 could function in the same signal transduction pathway. These results shed light on revealing the roles of nsLTP in vivo and make it promising to finally characterize the plasma membranes receptor of nsLTP.

发现~(125)I-Trx-nsLTP144、~(125)I-Trx-nsLTP110与水稻细胞质膜均具有特异性结合，而且结合是饱和性的、可被竞争的，符合配体-受体结合的典型特征，同时用于对照实验的蛋白质~(125)I-Thioredoxin没有此特性，表明水稻细胞质膜上存在nsLTP的受体；利用可氧化糖基的NaIO_4和水解糖基的N\'-糖苷酶F处理水稻细胞质膜，再进行结合实验，结合活性几乎不受影响；而利用胰蛋白酶处理细胞膜则使得结合能力几乎完全丧失，表明其受体为没有经过糖基化修饰的蛋白质；利用交联剂BS~3交联配体一受体后，再进行SDS-PAGE分离和放射自显影，结果显示水稻细胞质膜上的nsLTP受体中有一个60kDa的蛋白质可以与nsLTP144发生特异性的结合，可能是其受体；细胞外碱化实验表明，nsLTP144不能促使拟南芥原生质体细胞培养液的细胞外碱化反应，却能猝灭来自植物病原菌的激发子Cryptogein刺激拟南芥原生质体产生的细胞外碱化反应，表明nsLTP和Cryptogein结合细胞膜上相同的位点，保护了植物细胞免受Cryptogein导致的细胞程序性死亡，并诱导系统获得性抗性的产生；体外Pull-down实验表明，nsLTP144和水稻的OsCaM1具有相互作用，暗示了nsLTP144和OsCaM1可能同在一个信号通路上起作用。

Antagonists of GABAA receptor/Cl一channel, picrotoxin and bicuculline,have no effect on the progesterone-induced AR,but they can significantly inhibit the GABA-induced AR in Cl--containing medium.

在含CI一培养液中，GABA*受体拮抗剂picrotoxin和bicuculline不抑制孕酮诱发的顶体反应，而抑制GABA诱发的顶体反应。

We used the reported chiral ligand QD-4 derived from quinidine to catalyze the reaction of aldehydes and methyl vinyl ketone in the presence of various additives and found that the highest e.

用喹尼叮衍生物QD-4分别催化醛和丁烯酮以及醛和丙烯酸-萘酚酯的不对称Baylis-Hillman反应，通过改变添加剂和优化反应条件，最终分别取得了最高为49％和70％的e.e值。

Theoretical analysis and experimental results indicate that reaction of zinc with selenide as fully as possible under H2-O2 flame at about 1500℃ is the key step in the synthesis process and prolonging holding time at high temperature, which makes the diffuse reaction adequately take place, is favourable to obtain stoichiometry ZnSe polycrystalline.

理论分析和实验研究均表明：前期H2-O2焰下高温灼烧(~1500℃)使Zn和Se充分反应，是合成工艺的关键；延长后期恒温时间（不少于2周），使扩散反应进行完全，有利于获得更接近化学计量比的ZnSe多晶料。

In DMSO, the polymerization of methyl methacrylate could be carried out efficiently. However the photopolymerization was inhibited in acetonitrile. It was ascribed to the complex formed between coumarin 1 and HTIB photolyzed to unreactive species after irradiation in acetonitrile.

在一般极性溶剂中如DMSO中能有效地引发甲基丙烯酸甲酯光聚合，而在电子受体性质的极性溶剂如乙腈中，光聚合反应受阻，这归结于香豆素1与羟基苯基碘鎓盐形成络合物，使得光反应后生成不具活性的产物。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。