不反应的

In some cases, its epimer 4 was also obtained. 22 compounds were synthesized, among them 18 were new.3. Using the intramolecular Pictet-Spengler reaction to form the pentacyclic skeleton of Et-743, the byproducts 25 were obtained under various conditions. The structures of them were determined to be 1, 2-dihydro-isoquinoline compounds, and the mechanism of the reaction was proposed.B. The synthesis of the analogs of Et-743Because of the failure of removing the protective groups in compounds 14, the synthetic strategy was adjusted.

对于苄基保护的羟基化合物13a，顺利得到化合物30，然后与不同的羧酸反应得到18个酯化合物33-50；对于苄氧羰基保护的氨基化合物13b，由于脱除保护基的化合物31在空气中不稳定，所以我们采取不经分离纯化，直接与羧酸反应得到酰胺化合物53-62，然后再分别对其C-21位的羰基进行还原氰基化，得到10个酰胺目标化合物63-72，另外，我们还对羟基转化为氨基的反应进行了探索。3。

The region between the circular brown band generated by cell lipid exosmosis and the band of the wound in the non-transgenic cotton Z35's leaves, is wider than that of the transgenic cotton T-34's leaves, and no micro-HR was found in Z35, the intensity of leaves wilting is much serious, by contrast, micro BR was found around the wound region within the transgenic cotton leaves inoculated with the pathogen, but the micro-HR was not found in the transgenic cotton treated with water and around wound region of non-transgenic cotton Z35 leaves which showed that there was micro-HR defence in transgenic hpa1xoo cotton.

棉花黄萎病菌侵染叶片后，非转基因棉花叶部伤口周围细胞无微过敏性反应，受病原菌侵染的叶片萎蔫程度较重；转hpa1xoo基因棉花叶部伤口周围细胞有微过敏反应，叶部刺伤处仅有较小的坏死斑，且不相连，发病较轻，而清水处理的转基因棉花与非转基因棉花叶片中伤口周围均无微过敏反应，说明病原菌侵染诱导转hpa1xoo基因棉花产生微过敏防御反应，转hpa1xoo基因棉花较非转基因棉花有较强的抗病性。

Solid acid catalysts have been found to be useful catalyst in a variety of organic reactions. They have many advantages, such as non-toxic, inodorous, non-volatile; non-corrosive, non-pollution, mild reaction conditions, high yields and reactivity, excellent stability and simple work-up procedure, and these are what liquid catalysts cant replace.

固体酸催化剂在有机合成反应中应用广泛，这类催化剂无毒无味，不挥发，不污染环境，不腐蚀设备，容易回收，可重复使用，所催化的反应条件温和，产率和选择性高，后处理简便，且具有独特的催化性能，这些是液体催化剂所不能代替的。

The results showed that the population administered with free adjuvant cholera vaccines,both low dose group and common dose group,occurred the weak adverse reaction with 10￣25% rate.The reaction rates between two dose groups of the same vaccine have not significant difference;The reaction rate of the first inoculation(19￣25%) is higher than those of the second inoculation(10￣15%)(P 05);The inoculating local reaction is very light ,only the very few subject occurred the scleroma with 15 mm of diameter.The reaction of aluminum absorbed cholera vaccine is slightly stronger than those of other groups.

结果表明，不加铝佐剂的O139型霍乱菌苗及O1群霍乱菌苗，不论是低剂量组（两剂全程接种45亿菌体）抑或常剂量组（全程接种90亿）接种人群均可产生10～25％的体温呈轻度升高的弱反应，并且同种菌苗的两剂量组的反应率无显著差异；第一剂接种的反应率（19～25％）较第二剂接种的（10～15％）高，P＜0.05；接种局部反应轻微，只有个别受试者出现直径小于15mm的硬结；加佐剂的O1群吸附霍乱菌苗的反应较其它组强。

Esterification process of a reversible step wereresolved as two irreversible steps,then chemical decomposition of wood components weredecreased in liquid acid catalyst.Experiments showed that crosslinking catalysts took catalysisrole on two process in the esterification,(1)five cyclic anhydrides formed by dehydration ofpolycarboxylic acids,(2)esters occurred by substitution between five cyclic anhydrides andwood.

实验中的反应过程使一般的酯化一步可逆反应，分解为两步不可逆反应，减少了液相酸催化过程的木材组分化学降解；交联反应催化剂对于多元羧酸类化合物与木材组分的酯化反应具有两个过程的催化作用：(1)多元羧酸脱水形成五元环酸酐中间体；(2)木材与五元酸酐中间体亲核取代反应形成酯。

The first asymmetric synthesis of trans-β-hydroxy-γ-butyrolactones:-(3R, 4R, 5S)-4-(1-acetoxy-isopropyl)-3-hydroxy-butyrolactone 65a was achieved starting from isobutylaldehyde through nine steps. The key steps involve the construction of three chiral carbon centers by the Sharpless's asymmetric epoxidation and Substrate directable chemical reaction.

以异丁醛为起始原料，经过九步反应首次设计合成了具有三个手性中心的trans-β-羟基-γ-丁内酯：-（3R，4〓，5S）-4-（1-乙酰氧基-异丙基）-3-羟基-丁内酯65a，关键步骤是Sharpless不对称环氧化和底物定向不对称合成反应。

Expanding pinacol reductive coupling reaction into asymmetric one with both diastereoselectivity and enantioselectivity may lead to its application in synthesising medicaments and biologic active compounds with structure of vicinal diol. Asymmetric pinacol coupling reaction is also the most compact and effecient method in synthesizing chiral ligands or chiral auxiliary with C〓 symmetry.

将这一反应发展成为既有高度的非对映选择性，又有高度对映选择性的不对称偶联反应在合成许多含有手性邻二醇结构的药物或生物活性物质将有更重要的应用，同时不对称Piancol偶联反应也是合成C〓对称性的邻二醇多用途手性配体或手性助剂的最为简捷有效的方法。

Results indicated that introducing some ring-structure into UF molecule during the synthesis could efficiently improve the water resistance of UF resin. The Uron ring would form if reaction temperature was more than 75 degrees C, and the higher Uron content was obtained at pH 8 and 85 degrees C in the absence of catalyst when the reaction time was long enough.

结果表明：通过在脲醛树脂合成中引入Uron环等环状结构物质能够有效提高脲醛树脂胶黏剂的耐水性；当反应温度高于75℃时，反应产物都生成了一定量的Uron环物质；在pH值为8左右、温度控制在85℃、不使用催化剂、尽可能延长反应时间的条件下，尿素与甲醛成环化反应生成的Uron相对值最多。

In order to provide theoretical basis for applications of plasma method in degradation of pollutants,the degradation mechanism of halons(CF 2ClBr,CF 3Br)with cold plasma technology was studied.In oxygen free systems,the amounts of some products change dramatically with the discharge time.When enough oxygen is present,the dominant product is CF 2O.

利用低温等离子体技术对哈隆类物质 CF2 Cl Br和 CF3Br进行了降解反应研究，发现无氧条件下某些降解产物的量随放电时间不同而出现波动，表明降解过程中存在竞争反应；而氧气过量条件下不存在竞争反应，其主要产物为 CF2 O等。

Chiral amine-protonic acids are highly efficient and excellent enantioselective organocatalysts developed in recent years. They have been successfully applied to a number of enantioselective organic reactions, such as asymmetric aldol condenstion, Michael addition, Diels-Alder cycloaddition, Strecker reaction and so on.

手性胺-质子酸是近年来发展起来的新型高效、高对映选择性的有机催化体系，已成功应用于催化不对称Aldol反应、Michael加成反应、Diels-Alder反应和Strecker反应等许多重要的有机合成反应。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。