不反应的

In the asymmetric hydrogenation of ethyl pyruvate catalyzed by 0 5% Rh/PVP TiO 2, the chiral modifier cinchonidine not only induces the enantioselectivity, but also accelerates the reaction rate greatly.

研究了辛可尼定作手性修饰剂修饰的负载型纳米铑簇合物催化剂(0 5 %Rh/PVP TiO2 )催化丙酮酸乙酯不对称氢化反应，在该反应中手性修饰剂辛可尼定不仅具有对产物生成的手性诱导作用，而且对反应具有明显加速作用；在优化反应条件后，反应的TOF和对映选择性分别可以达到 5 8 0min-1和

By use of the Fischer-Tropsch reaction in a C-H-O system, we discussed the relationships between inorganic CO〓 and some physical chemistry conditions, such as Oxygen flee degree , temperature, pressure, other objects consistency and catalyzer. a when T=200K～2000K, if f〓＞0, the reaction of generating CO〓 will be dominant, CH〓 hardily exists; b when T＞1000K, CH〓 is not propitious to exist, carbon in system almost exists in form of CO〓; c the more pressure, the more CO〓 is propitious to exist; d the more consistency of CO, O〓 and H〓O, the more CO〓 is propitious to exist, the more consistency of H〓, the more CH〓 is propitious to exist.

依据C-H-O体系费托反应的简化模型，讨论了氧逸度、温度、压强、其它物质浓度、催化剂等物理化学条件对无机成因CO〓生成的影响，从理论上讨论了在地质环境中，无机成因CO〓存在的物理化学条件：1在T＝200K～2000K的温度范围内，体系中一旦氧逸度＞0，生成CO〓的反应将占绝对优势，CH〓几乎不可能存在；2T＞1000K时，不利于CH〓形成，使体系中的碳主要以CO〓的形式存在；3体系压强越大，越有利于CO〓的形成；4反应物CO、O〓、H〓O的浓度越高，越有利与CO〓的存在，H〓的浓度高有利于CH〓的形成。5地质成藏作用可以经历很长的地质年代，这足以补偿矿物岩石中的Ni、Mo、Fe、Co、Ru等催化性能的降低及其它动力学条件的不足，使得费托反应可能发生，从而生成无机成因的CO〓和烃类。

Using tapioca starch as raw material to prepare oxidized starch is better if we need the oxidized starch with low viscosity,can be used with high concentration starch slurry, and good transparency, good whiteness, low retrogradation and syneresis. Then, the research of using oxidization technology to improve the properties of tapioca crossed-linked and esterified starch was also researched: under the conditions of

然后，研究了应用氧化技术来改善木薯交联酯化淀粉的性能，在次氯酸钠用量为0.2%， pH8.5恒定反应，室温反应，反应过程不控温的反应条件下对木薯交联酯化淀粉进行氧化，可以在保持其交联酯化淀粉的应用性能不改变的前提下，大幅度提高产品的透明度，改善了产品应用性能。

At present,the rate laws and reaction mechanisms of pyrite oxidation,pyrite and chalcopyrite formation,uraninite and magnetite dissolution in aqueous solutions are mainly studied,and it is discovered that (1)oxidation rate of pyrite controlled by surface reaction assume fractional dependence on Fe3+ and O2 molalities in acid solutions;(2)Pyrite cannot nucleate directly from solutions below 300 ℃,it can only form initially through sulfidation of a FeS precursor. The rate equation of reaction between FeS and H2S to form pyrite is of the second order;(3)Chalcopyrite is formed by reactions of pyrrhotite or pyrite with Cu2+,the former proceeds via a series of mediate metastable phases of Cu-Fe sulfide,whereas the rate equation of the latter is apparently of the first order which is controlled by surface reaction;(4)The nonlinear behavior of magnetite dissolution at acid pH can be represented by a shrinking core model coupling with surface reaction and diffusion transport.

目前主要研究了水溶液中黄铁矿氧化、黄铁矿和黄铜矿形成、晶质铀矿和磁铁矿溶解的速率定律和反应机理，发现：(1)酸性溶液中黄铁矿的氧化速率对Fe3+和O2浓度呈分数依赖并受表面反应的控制；(2)低于300 ℃时黄铁矿不能从溶液中直接成核，而需初始地通过FeS先驱物的硫化生成，FeS与H2S反应形成黄铁矿的速率方程为二级；(3)磁黄铁矿或黄铁矿与Cu2+反应均可形成黄铜矿，前者经历了一系列准稳的Cu-Fe硫化物的中间物，后者的速率方程为表观一级并受表面反应的控制；(4)酸性pH时磁铁矿的非线性溶解行为可采用表面反应扩散输运耦合的收缩核模型来描述。

The key advantages of the Suzuki cross-coupling are the mild reaction conditions and the commercial availability of the diverse boronic acids that are environmentally safer than the other organometallic reagents.

催化剂是suzuki偶联反应当中一个重要的因素，选择合适的催化剂不仅能够使反应条件变得比较温和而且能够提高反应产率，甚至能使原本不能发生的反应变为可能。Suzuki偶联反应的催化剂通常由两部分组成：钯源和配体。

The results showed that the kinetical rule of the ion-exchange reaction was not changed, the ion-exchange process was still controlled by the grain diffusion, and the concentration of Cl~- has little effect on the apparent activation energy of reaction if the total concentration of ion in the solution kept invariableness.

结果表明，在维持溶液中离子总的当量浓度不变的条件下，离子交换反应的动力学规律不会发生改变，反应仍然是受粒扩散控制，氯离子浓度对交换反应表观活化能的影响不大。

In this thesis, the reaction of methanol conversion into hydrocarbons on HZSM-5 and SAPO molecular sieves, which is of great importance to industry, is selected as probe reaction to get deeper insights into the structure of solid catalysts and the interaction of reactants with catalysts during adsorption and catalytic reaction by solid state NMR.

本论文主要以固体NMR为研究手段，以甲醇制烃类作为探针反应，详细研究了催化剂的结构、吸附过程中反应物与催化剂的相互作用、反应过程中反应物与催化剂的相互作用，主要取得了如下结果： 1 原位MAS NMR实验结果表明，甲醇制烃类的过程是通过&碳池&机理来实现，&碳池&的组成随反应的进行而变化，在反应前期，&碳池&由饱和烃类构成，随着反应的进行，饱和烃类和不饱和烃类共同组成&碳池&。

If the content of SiH〓 kept constant, the laser energy value of threshold that decomposed SiH〓 increased linearly at first, but when the gas flux exceeded 100ml/min, the laser energy value of threshold increased slowly because the coaxial Ar could not"suppress"the reaction flame which leaded to radial dilation of reaction gases and increasing the effective absorption to laser energy.

在反应气体中SiH〓含量不变的情况下，随着反应气体流量的逐渐增加，可以引发硅烷分解的激光能量阈值一开始成线性增加，当流量大于100ml/min以后，由于同轴Ar不能有效的&压住&反应焰，导致反应气体的径向扩张，增加了对激光能量的有效吸收面积，因此激光能量阈值的增加减缓。

Novozym 435 was used for the synthesis of vitamin A plamitate. The influences of solvent, the molar ratio of substrates, the reaction temperature and time, and the water concentration were optimized and the best result was obtained by interesterification from 0.200 g vitamin A acetate and 0.468 g palmitic acid, at 30℃, in 10 mL hexane, containing 0% of water, with 10% of lipase(mass ratio, immobilized lipase to vitamin A plamitate). In these conditions, 75% of vitamin A acetate was converted into vitamin A plamitate. The immobilized lipase was reused about 6 batches.

对催化合成维生素A棕榈酸酯反应的脂肪酶和反应介质比较，同时对影响合成维生素A棕榈酸酯反应的因素（温度、初始水含量、底物摩尔比、反应时间和酶量等）进行了探讨，优化了反应条件：在10 mL不含水分的正己烷中，0.200 g 维生素A醋酸酯和0.468 g棕榈酸在酶量为10％（指固定化酶与维生素A醋酸酯的质量比）的固定化脂肪酶催化下，在 30℃、190 r/min下反应6 h，转化率可以达到75%，固定化酶可连续使用6次以上。

Kinetics on the reaction of epoxy resin with acrylic acid has been studied.

本工作研究了以丙烯酸和环氧树脂为原料合成丙烯酸环氧酯的动力学，认为该反应是一级反应，在此基础上提出了反应机理同时研究了不饱和酸离解常数及溶剂对反应速率常数的影响，进一步支持了上述观点；并且求出了在不同温度中的反应速率常数及反应的活化能。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。