不偏

The results show: the strongest bond is the Al-Al bond in the segregated cell without containing vacancy, where the Al atomic covalence radius is greater than that of Li atom in the cell; while the strongest bond is the Al-Li bond in the segregated cell containing vacancy, and the Al atomic covalence radius in the cell is less than that of Li atom. Since the difference of electronagativity between the Al and Li atoms is obvious, it is inclined to formed the Al-Li segregated cell of short range order structure in the condition of vacancy present. The short range order structure containing vacancy is probably the embryo or precursor structure of the metastable phase δ′(Al3Li). Because the strongest covalent bond in the Al-Li-vacancy segregated cell in alloy formed in quenching is the main strength reason for supersaturated solid solution of alloy. The bond net of succeeding precipitation of δ′(Al3Li) has the picture of anisotropic Al-Al bonding and the bond intensity enhanced. Since the δ′(Al3Li) is coherence with matrix, the bond net strength is enhanced by the precipitation of δ′(Al3Li) and so strengthen the alloy.

计算结果表明：不包含空位的偏聚晶胞的键络最强键为Al—Al键，其中Al原子的共价半径较Li原子的共价半径要大；而含空位的偏聚晶胞的最强键为Al—Li键， Al原子的共价半径要比Li原子的共价半径要小；在空位存在的情况下，由于Al原子与Li原子的电负性相差明显，促使Al和Li原子结合，倾向形成Al-Li短程序结构偏聚区，这种含空位的短程序结构很可能就是δ′(Al3Li)亚稳相的前兆结构和生长胚胎；由于Al-Li-空位有序偏聚晶胞的Al—Li键络比基体键络要强许多，因此，淬火过程中合金生成的Al-Li-空位偏聚晶胞对合金过饱和固溶体起主要强化作用；后续析出的δ′(Al3Li)亚稳相键络各项异性显著，键络强度明显提高；由于Al3Li与基体共格，其大量均匀弥散析出起到提升基体整体键络强度，同样对合金产生强化作用。

The results show: the strongest bond is the Al-Al bond in the segregated cell without containing vacancy, where the Al atomic covalence radius is greater than that of Li atom in the cell; while the strongest bond is the Al-Li bond in the segregated cell containing vacancy, and the Al atomic covalence radius in the cell is less than that of Li atom. Since the difference of electronagativity between the Al and Li atoms is obvious, it is inclined to formed the Al-Li segregated cell of short range order structure in the condition of vacancy present. The short range order structure containing vacancy is probably the embryo or precursor structure of the metastable phase δ'(Al3Li). Because the strongest covalent bond in the Al-Li-vacancy segregated cell in alloy formed in quenching is the main strength reason for supersaturated solid solution of alloy. The bond net of succeeding precipitation of δ'(Al3Li) has the picture of anisotropic Al-Al bonding and the bond intensity enhanced. Since the δ'(Al3Li) is coherence with matrix, the bond net strength is enhanced by the precipitation of δ'(Al3Li) and so strengthen the alloy.

计算结果表明：不包含空位的偏聚晶胞的键络最强键为Al-Al键，其中Al原子的共价半径较Li原子的共价半径要大；而含空位的偏聚晶胞的最强键为Al-Li键，Al原子的共价半径要比Li原子的共价半径要小；在空位存在的情况下，由於Al原子与Li原子的电负性相差明显，促使Al和Li原子结合，倾向形成Al-Li短程序结构偏聚区，这种含空位的短程序结构很可能就是δ'(Al3Li)亚稳相的前兆结构和生长胚胎；由於Al-Li-空位有序偏聚晶胞的Al-Li键络比基体键络要强许多，因此，淬火过程中合金生成的Al-Li-空位偏聚晶胞对合金过饱和固溶体起主要强化作用；后续析出的δ'(Al3Li)亚稳相键络各项异性显著，键络强度明显提高；由於Al3Li与基体共格，其大量均匀弥散析出起到提升基体整体键络强度，同样对合金产生强化作用。

In this paper, three robust estimators: robust best invariant quadratic unbiased estimator, robust minimum norm quadratic unbiased estimator and robust Helmert estimator have been designed. Finally, this paper states that these three classical estimators are particular cases of the RBIQUE.

导出了稳健最优不变二次无偏估计、稳健最小范数二次无偏估计、稳健Helmert估计，并说明了最优不变二次无偏估计、最小范数二次无偏估计以及Helmert估计等均是稳健最优不变二次无偏估计的特例。

It sums up that the persons of applied abilities in Jilin Province are quantitatively poorly educated in obstructed ways, lack of hi-tech skills, in unbalanced age-sex structure and industrial structure. Our study analyzes the factors that influence the development of rural people, and figures out two main obstacles, which are impercipience and imperfection of resource management.

通过对这些数据的分析，总结归纳出我省农村实用人才目前存在着总量偏少、学历层次偏低、高科技人才缺乏、产业结构不合理、培养渠道不通畅以及年龄偏大、女性比例偏小的问题；同时对制约农村实用人才发展的因素进行了分析，认为主要存在着对农村实用人才的作用认识不到位、对其资源开发的管理不够完善两方面的问题。

The emulation result shows that the error of polarizer rotation angle almost does not influence nonlinearity when elliptic polarization of laser beams exists; when the error of rotation angle of polarizing beam splitter exists, the second-harmonic nonlinearity caused by the error of polarizer rotation angle will not increase, but the first-harmonic nonlinearity will increase greatly.

仿真结果表明，当存在激光束椭圆偏振时，检偏器旋转误差对非线性误差的影响很小；当存在偏振分光镜旋转误差时，检偏器旋转误差引起的非线性误差不增加二次谐波分量，但增大了非线性误差一次谐波分量，严重影响非线性误差的大小，当偏振分光镜旋转误差为3°时，检偏器旋转误差从0°增加到5°，非线性误差从0.14 nm增大到0.97 nm。

In this thesis,the AM1,MNDO,MINDO/3(mainly AM1)and INDO/S-CI semiempirical MO methods were used toinvestigate the excited-state intramolecular protontransfer reactions of salicylic acid derivatives—salicylic acid,methyl salicylate,salicylaldehyde,o-hydroxyaceto-phenone,salicylamide and 3-hydroxy-picolinamide (6 conformers and 2-3 anion species);2-(2'-hydroxy-5' methylphenyl) benzotriazole(4 conformers),2-(2' hydroxyphenyl) benzimidazole (3 conformers and 3anion species),Bis-2,5-(2-benzoxazolyl)hydroquinone(3 conformers),2-(2'-hydroxyphenyl)benzothiazole(2conformers) and 7-azaindole dimer (2 conformers).Theinvestigations were described as follows.Geometry optimization,relative stability andhydrogen bonding energy First,for sylicylic acid derivative molecules,the AM1,MNDO and MINDO/3 methods were used toinvestigate ground-state geometry optimization,energies,relative stabilities and hydrogen-bondingenergies on the five kinds of the molecules(designing 6 conformers and 2-3 anion species).Comparing with experimental data,the optimizedgeometry,the order of stability,the hydrogen-bonding energies and the distances between O-O in O-H..O hydrogen bonds by AM1 method were in agreementwith the experimental data,however,the C-C bondlengths optimized by MNDO and MINDO/3 were longer,C-O and O-H bond lengths were shorter;for C-N bondlengths,the results opitimized by MNDO method werethe same as those by AM1 method,nevertheless the C-Nbond lengths given by MINDO/3 method were muchshorter.For some sylicylic acid derivatives(e.g.methyl salicylate,salicylamide),the order ofstabilities on the conformers given by MNDO andMINDO/3 methods were not in agreement with theexisting conformers deduced by experimental methods,and the hydrogen bonding energies calculated by MNDO.and MINDO/3 methods were smaller.Second,the studyon the other systems found that the optimizedgeometry of the proton-transfered product with INDOmethod could not be obtained,only could theoptimized geometry of reactant be obtained,and thecalculated hydrogen bonding energies were greater.Many results of calculation indicated that the studyon the excited-state intramolecular proton transferreaction system using AM1 method was suitable andreliable.

本论文用AM1、MNDO、MINDO/3（主要是AM1）和INDO/S-CI半经验分子轨道方法对水杨酸衍生物系列——水杨酸、水杨酸甲酯、水杨醛、O-羟基乙酰苯酮、水杨酰胺和3-羟基吡啶酰胺（6种异构体和2-3种阴离子）；2-（2'-羟基-5'-甲基苯基）苯并三〓唑（4种异构体）；2-（2'-羟基苯基）苯并咪唑（3种异构体和3种阴离子）；2，5-二间氮杂氧茚氢醌（3种异构体）；2-（2'-羟基苯基）间〓杂硫茚（2种异构体）和7-〓吲哚二体（2种异构体）的激发态分子内质子转移反应在以下几个方面进行了较系统的理论研究：几何构型优化和相对稳定性及氢键能首先以水杨酸衍生物系列分子为例，用AM1、MNDO和MINDO/3方法考察了5种分子（每种分子设计6种异构体和2-3种阴离子）的基态几何构型优化，能量、相对稳定性和氢键能计算，通过和实验数据进行比较，AM1方法给出的优化几何构型、稳定性次序、氢键能和O—H。。。O氢键的0—0距离与实验数据吻合最好，MNDO和MINDO/3方法优化的C-C键长偏长，C-O键和O-H键长偏短；对于C-N键长，MNDO和AM1优化结果差别不大，而MINDO/3给出了过短的C-N键长，MNDO和MINDO/3方法给出的有些水杨酸衍生物分子（如水杨酸甲酯和水杨酰胺）异构体的稳定性次序和实验上推测的可存在异构体结果不一致，MNDO和MINDO/3方法给出的氢键能偏低，对其他体系的研究发现INDO方法常常不能得到质子转移产物的优化几何构型，只能得到反应物的优化构型，并且估算的氢键能偏高，大量的计算结果表明AM1方法对本论文研究的激发态分子内质子转移反应体系是适宜和可靠的。

According to the energy conservation theory, BOM and CSIM4 were coupled. The BOM has no treatment on transmission solar radiation, which is of great importance when the model is adapted to Arctic Ocean. So the treatment was introduced to BOM. Through numerical test on different lead albedos, it was found that sea ice thickness is not so sensitive to lead albedo, which may be contribute to the lead occupies little ratio within multiyear sea ice pack. The reason of summer over-melt of arctic sea ice is the NCEP reanalysis downward solar radiation being larger than its reality. Then the arctic sea ice climate variability was simulated. Results showed that: simulated ice thickness change is in accord with the submarine investigated mean sea-ice draft changes. Simulated annually maximum ice thickness along the Eurasian continental oceans are closely related to the observed ones. The long-term mean simulated ice motion has the same features of the SSM/I derived ice motion. Sea ice extents in differential sub-regions have same trends comparing to the satellite passive-microwave data derived ones. Simulated ice concentration is closely related to the observed in the Arctic sub-regions. Sea ice flux through the Fram Strait involves ice concentration, motion and thickness. It is a composite criterion for sea ice model evaluation. The simulated ice area and volume export through the strait accord with the satellite derived or statistically reconstructed ones.(5) The simulated ice thickness climate variability and mean sea surface current of the coupled model were analyzed, results showed: the total ice volume in the Arctic Ocean has a significant decreasing trend. The volume variability is of a 10-year timescale oscillation, with two major periods of 12-13a and 18-20a. Mean ice thickness in the arctic sub-seas has different tendencies. It has an increasing trend in the Barents-Kara Sea and Baffin Bay-Labrador Sea, and decreasing in the others. The characteristic time scale of 7-10a wherein the river discharges leads the Fram Strait ice volume export is about the period that river water takes to be conveyed across the Arctic Ocean.(6) Using the simulated ice distribution in the Arctic Ocean and China precipitation, air temperature and SST in tropical key regions, the climate teleconnection were studied. Result showed: When the mean sea ice thickness is large in the central Arctic Ocean and Chukchi-Beaufort Sea , and small in the Barents-Kara Sea and Baffin Bay-Labrador Sea , the precipitation in South China, Tibetan Plateau, and the north part of Northeastern China are always smaller than normal, and v. v. When the mean ice thickness is small in CA, BC, East Siberian Sea and Greenland-Iceland-Norwegian Sea , and large in BL, The air temperature in north-eastern China, the southern of Tibetan Plateau, and Hainan Island, are always lower than normal, and v. v. In addition, when the sea ice is thick in BC and BL, the SST is larger in the middle and eastern Pacific Ocean, and is smaller in the tropical Southeastern Indian Ocean.

由于BOM没有考虑透射太阳辐射的物理过程，研究表明透射太阳辐射对北冰洋的能量收支起到重要作用，因此在BOM模式中引入了对透射太阳辐射的处理；通过对不同水道反照率的数值试验表明海冰厚度对水道反照率的敏感性不强，可能与海冰区水道面积占的比率很小有关；而模式模拟的北极海冰夏季&过度融化&主要源于NCEP再分析资料提供了偏大的太阳短波辐射；对北极海冰的气候变率进行了模拟研究，结果表明：模拟的海冰厚度变化与潜艇探测的海冰吃深度变化具有一致性；模拟和观测的亚欧大陆沿海的年内最大海冰厚度有很好的相关；模拟的海冰移速与长期平均的卫星反演的海冰移速具有相同的速度分布特征；模拟的各个海区海冰面积的变化趋势与卫星反演资料分析的结果基本一致；模拟与观测的主要海洋分区的海冰密集度具有很好的相关：弗瑞姆海峡的海冰体积和面积的输送涉及到海冰密集度、厚度和移动速度，是判断模式模拟能力的一个综合的指标，模式模拟的结果与卫星反演或重建的面积输送、体积输送具有很好的一致性；(5)分析了模拟的北极海冰厚度的气候变率及气候平均表层海流场，结果表明：北极海冰的总体积有显著减少的趋势，北极海冰总体积的变化具有10a际尺度振荡的特点，存在18-20a和12-13a两个主周期；北极海冰的平均厚度在各个海区的变化趋势不同，在巴伦支—喀拉海和巴芬湾—拉布拉多海地区海冰厚度有显著的增加趋势，而其它海区存在减少的趋势；通过对模拟的气候平均表层海流的分析表明，北极河流流量超前弗瑞姆海峡海冰流量7-10年的特征时间尺度与表层海流的气候分布存在着必然联系：(6)利用模拟结果以及中国降水、气温和热带关键区SST资料，讨论了北极各海区海冰平均厚度与中国降水、气温以及热带关键区SST的关系，结果表明：在北极中心海区和楚科奇—波弗特海海冰厚度偏大，在巴伦支—喀拉海以及巴芬湾—拉布拉多海海冰厚度偏小，则中国降水在华南地区、青藏高原和东北北部降水偏少，反之相反；在北极中心海区、东西伯利亚海、楚科奇—波弗特海以及格陵兰海海冰厚度偏小，在巴芬湾—拉布拉多海海冰厚度偏大，则在中国东北地区、高原南部地区和海南岛附近气温偏低，反之相反；另外，北极楚科奇—波弗特海和巴芬湾—拉布拉多海海冰厚度偏大时，在热带中东太平洋海温偏高，而在热带东南印度洋海温偏低。

Since this product can be used with the tin in order to melting the surface, however we did not acquire the technology skill to melt the tin, which was caused the existence of non-uniform thin coating on the phenomenon.Our engineering staffs have reviewed and this problem has been solved, it is no longer thin coating melts the surface coating.Eventually we led our products TKEKK with pased of current 50A, it has obtained to the minimum partial fuse time.

因为此产品所用可熔体其表面是镀锡，因当时我们公司掌握的可熔体镀锡技术不成熟，导致所生产出的可熔体表面镀层存在镀层偏薄不均匀的现象，最终导致给我们的TKEKK产品通50A电流时，熔断时间偏下限，对此，我公司的工程人员通过技术改良，现已解决了此问题，现生产出的可熔体表面镀层已不存在镀层偏薄，不均匀的现象。

Practitioners were also reminded on correct technique, for example controlling the height of a front kick so ensure maximum is delivered through an opponent and not deflected upwards.

使用正确的技术提醒教练们，例如控制前踢的高度保证最大程度的击打对手而不偏向上。

Comparing the top right and the bottom left, it is easy to see in the bottom left image where the threshold is too low, and the digitized particles are obviously too small, while in the top right case, the digitized particles detected are over-sized and a good deal of noise is detected as well.

比较右上方和左下方的图片，很容易就可以看到左下方的图片的阈值过低，数字化的颗粒明显过小，而右上方的不偏数字化的颗粒过大，有很多噪点。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。