下代

All of the tripodal schiff base ligands and their complexes were characterized.

以三乙醇胺、巯基苯胺、巯基乙胺为初始原料，设计合成了六个三脚架结构的化合物，其合成路线如下：三乙醇胺与氯化亚砜反应得到三(2-氯乙基)胺(1)，然后与巯基苯胺或巯基乙胺在碱性条件下反应生成三脚架结构的三{[2-(2-氨基苯基)硫代]乙基}胺(2)或三{[2-(2-氨基乙基)硫代]乙基}胺(3)，然后再与水杨醛、2-甲酰基-8-羟基喹啉(8)、2-甲酰基-8-苄氧基喹啉(7)反应得到六种新型的含硫西佛碱化合

Based on the regional tectonic evolution, combined with the high precision isotopic ages from this paper and other geologists, we have some new acquaintances as follows: 1 There has no Caledonian granite belt distributed in north margin of North China Craton. So, the traditional evolving model of North China Carton, which formed on this idea and the acquaintance about the collision of North China plate and Siberian plate, must be incorrect; 2 The age date show that the earliest magmatic activity began since late-Palaeozoic Permian, which is inconsistent with the previous idea that there were Caledonian and Hercynian active continental margin in the north of North China Craton and in the south Xingkai Massif. 3 the crust and lithosphere were thickened by the subduction and collision of Siberia plate and North China plate during Late Paleozoic. The magma is formed when the crust is heated and melts caused by thickened lithosphere delamination and caused the Asthenosphere upwelling. But only a little basaltic magma erupted, most magma underplate under the bottom of the crust. Thermal energy derived from basaltic magma underplating made the middle and lower crust melt partially and the late Permian-early Triassic granites is formed in large scale.

根据区域构造演化分析，并结合本文及他人高精度同位素年龄，我们对延边花岗岩形成的大地构造环境有了新的认识：1在华北地台北缘并不存在所谓的加里东花岗岩带，因此，建立在此之上的传统的华北地台北缘演化模式及有关西伯利亚板块与华北板块的碰撞拼合的认识也必然是不正确的；2华北地台北缘和兴凯地块南缘不存在加里东期和海西期花岗岩带，表明两地块边缘最早的花岗质岩浆活动始于晚古生代的二叠纪，即不存在传统观点所认为的加里东期或海西期活动陆缘；3晚古生代由于西伯利亚板块与华北板块的俯冲碰撞，致使地壳和岩石圈增厚，导致加厚岩石圈发生拆沉作用，使得软流圈上涌，加热地壳使之熔融形成岩浆，但玄武质岩浆少量喷出地表，大部分底侵于地壳底部，形成下地壳高密度的玄武质底侵层，玄武质岩浆底侵的热能引起中下地壳广泛部分熔融，形成大面积分布的晚二叠世—早三叠世花岗岩。

COMPAREED WITH THE POETIC EXPERIENCES AND PHENOMENA WHASE NATURE HAS BEEN DETERMINED DURING THE LITERARY HISTORY, THE'THIRD GENERATION'POEMS, NOW STILL AFTER THE AGITATION, AND TRYING FOR CERTAIN FIRM TRANSFERENCE, ARE RATHER LIMITED IN DEALING WITH HISTORY AND THEORETICAL SIGNIFICANCE, WHETHER ON TIME SPAN OR SPIRITUAL LEVELS. THIS PAPER, THEREFORE, LAYS EMPHASIS ON DESCRIPTION AND INTERPRETATION AS WELL AS PRUDENT VALUE JUDGEMENT, INSTEND OF ARBITRARY DECISION. A MORE THOROUGH STUDY WILL HAVE YET TO BE WAITED WHEN THE'THIRD GENERATION'HAVE GONE A MORE FULL AND COMPLETE DEVELOPMENT.

与那些业已具备了历史定性的诗歌经验和现象相比，激荡之后归于沉潜，如今正在作出某些内坚实在的推移的&第三代&诗，无论在时间跨度上还是在所展示的精神层面上，对历史和理论意义的容纳程度都还显得相对有限，由此规定了论文对描述和阐释的侧重，以及对下论断式的价值判断尽可能保持谨慎的态度，后者将有待于&第三代&更为充分、完整的发展和立足于其上的更为充分的研究后，再加以弥补。

The results show that the brominated reaction is complete in 1.5 initial contact minutes,an...

结果表明，丁基橡胶的溴化过程只在最初的1.5min内，随着反应时间的延长及在碱性条件下反应，发生了分子结构的重排，即由溴代仲位烯丙基结构向更稳定溴代伯位烯丙基结构转移。

The application results from fluorination showed microwave heating could accelerate chemical reactions markedly. The reaction time could be shortened 50% at least than that of conventional heating. The relationship between fluorinating agents\' structure and their activity was studied systematically. In addition, an anhydrous KF with higher activity was prepared by using expansion effect of microwave heating. As we known, solvents were very important to reaction. The comprehensive study showed some less polar aromatic solvents could be used as dipolar solvents. In addition, they had better effect than dipolar solvents in some occasions, such as fluorination of chlorobenzaldehydes and chlorinated diphenyl ketones etc. The primary applications of ionic liquids were also studied which indicated reactions with ionic liquids as solvents were more efficient and simple.

研究表明，微波是一种节能高效的加热方式，在微波作用下的卤素交换氟化反应具有反应速度快、转化率高、选择性好的优点，其反应时间可较常规加热缩短50%以上；同时也系统地研究了氟化剂种类及制备方式对其反应活性的影响，并利用微波加热的膨化作用制备出了一种活性较高的KF，其活性与喷雾干燥KF相差不大；溶剂对反应具有重要的作用，在此系统地研究了强极性非质子溶剂和中等极性非质子溶剂的应用情况，发现一些中等极性的非质子溶剂如硝基芳烃和氯代芳烃类溶剂在氯代苯甲醛类化合物的氟化反应中具有比强极性非质子溶剂更好的使用效果。

According to the Box-Benhnken design principle,the method of response surface method with 3 factors and 3 levels was used. The factors influencing the technological parameters were determined by means of regression analysis. Response surfaces were finally graphed with the yield as the response value. The synthesis conditions were optimized as follows:reaction reagent was NBS,stoichiometric proportion between NBS and anhydrovinblastine was 1.07; the dosage of TFA was 22 mL/L; reaction temperature was －68 ℃ and duration was 90 min.

在单因素实验基础上，根据Box-Benhnken实验设计原理，采用三因素三水平的响应面分析法，研究了各个因素及其交互作用后，得到了合成7′-Br-脱水长春碱的最佳工艺条件：以二氯甲烷为溶剂，采用NBS为溴代剂，其用量与底物的物质的量比为1.07∶1，TFA的加入量22 mL/L，在－68 ℃下反应90 min，终止反应后，得到卤代产物。

From the view of initial deformation,the dual intercrossed iterative method is developed to determine the initial deformations of cables and hangers,sequential method based on initial deformations to simulate the tensioning process in batches,and converse iterative method in sequential anal.

本文从索初始变形的角度出发，针对该类结构的特点，提出了&双重交叉迭代法&确定拉索和吊杆初始变形，索初始变形&顺序分析法&模拟分批张拉施工过程以及索张拉力&顺序分析逆迭代法&解决张拉力已知时的预应力施工过程模拟问题，并将这三种方法进行不同组合，解决各种情况下的多次、分批张拉施工过程分析的问题，由此确立了一套完整的适合该类结构的预应力全过程分析方法。

Results In contrast with enzymatic dissociation, the method of mechanical dissociation, breaking up great neurospheres into small spheres with gradually reduced pipette, had advantages of raising cell viability and shortening cell doubling time (P.05). After NSCs being cultured long term in vitro, the number of neurons generated decreased with passaging, whereas the number of astrocytes increased.

体外长期培养条件下，随着培养时间的延长，NSCs分化为神经元的比例逐渐降低，星形胶质细胞的比例逐渐增高；在4~12代NSCs分化为神经元的能力表现出下降的趋势，但仍较为稳定；12代后，神经元的分化比例迅速下降，星形胶质细胞的比例迅速上升。

Among the five civil rights,those which cannot be subrogated include exclusive obligatory right for obligor,the aes strum in person,right of person,right of succession and intellectual property.Besides the aes strum due by paying,the aes strum without personality or undue in special situation,jus in rem and right of claim in rem can all be subrogated.

指出五大民事权利中，债权人不得代位行使的权利，除专属于债务人自身的债权外，还有公民的人身权，继承权，民事主体享有的知识产权；除金钱给付内容的到期债权外，只要是不具有人身属性的债权、特定情况下未到期的债权、物权及物上请求权，债权人都可代位行使。

The grand sea that is palm of Guo stage inscription to accuse is one of groups of industry of science and technology with the biggest Taiwan, health can calls the Fuji below the banner the acting plant with the biggest whole world, he also is called from this " acting labor king ".

现年58岁的郭台铭掌控的鸿海是台湾最大的科技产业集团之一，旗下富士康堪称全球最大的代工厂，他也由此被称为&代工大王&。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。