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The better condition synthesizing the assorted minerals of zirconolite and sphene doping neodymium is holding 30 min at 1230℃, and the better formula is nCa(subscript 1-x/2-y/4 Zr(subscript 1-y/4);Al(subscript x/2) Ti(subscript 2-x/2O7): nCa(subscript 1-x NdAl Ti(subscript 1-x)SiO5[4/(4-y)]:1. Nd(superscript 3+) can enter crystal lattices of ite and sphene. Sphene can immobilize Zr(subscript 4+), Al(subscript 3+) and Nd(subscript 3+); Zr(subscript 4+) and Nd(subscript 3+) replace Ca(subscript 2+), and Al(subscript 3+) replaces Ti(subscript 4+). Zirconolite can immobilize Al(subscript 3+) and Nd(subscript 3+) Nd(subscript 3+) replaces Ca(subscript 2+) and Zr(subscript 4+), and Al(subscript 3+) and replaces Ti(subscript 4+).

研究表明:钙钛锆石和榍石组合矿物固化体较佳的合成条件是在1230℃条件下保温30min,较佳配方的摩尔比为nCa(下标 1-x/2-y/4 Nd(下标 x+y/2)Zr(下标 1-y/4)Al(下标 x/2)Ti(下标 2-x/2) O7:nCa(下标 1-x Nd Ti(下标 1-x)-SiO5=[4/(4-y)]:1;Nd(上标 3+)能够进入钙钛锆石和榍石晶格,榍石能够固溶Zr(上标 4+)、Al(上标 3+)、Nd(上标 3+),Zr(上标 4+)和Nd(上标 3+)取代Ca(上标 2+)位,Al(上标 3+)占据Ti(上标 4+)位,钙钛锆石能够固溶Al(上标 3+)、Nd(上标 3+),Nd(上标 3+)进入Ca(上标 2+)位和Zr(上标 3+)位,Al(上标 3+)占据Ti(上标 4+)位。

The floatation rate of Pd (superscript 2+) reaches 100% when the concentrations of NaNO3, KBr and cetyl pyridinium bromide in solution are 0.05 g/mL, 3.0×10^(-2) mol/L, 5.0×10^(-4) mol/L(pH 4.0), respectively. Pd (superscript 2+) could be separated from Ru (superscript 3+), Al (superscript 3+), Cr (superscript 3+), Ni (superscript 2+), Ga (superscript 3+), Fe (superscript 3+) and Zn (superscript 2+) by floatation quantiatively. A method of flotation separation and enrichment of Pd (superscript 2+) was established.

当溶液中硝酸钠、溴化钾、溴化十六烷基吡啶的浓度分别为0.05 g/mL,3.0×10^(-2)mol/L,5.0×10^(-4)mol/L,在pH 4.0时,Pd(上标 2+)的浮选率达到100%,Pd(上标 2+)可与Ru(上标 3+),Al(上标 3+),Cr(上标 3+),Ni(上标 2+),Ga(上标 3+),Fe(上标 3+),Zn(上标 2+)定量分离,据此建立了浮选分离和富集Pd(上标 2+)的新方法。

PL spectra indicate that the emission bands at 515 and 542 nm correspond to the 2H(subscript 11/2)→4I(subscript 15/2) and 4S(subscript 3/2)→4I(subscript 15/2) transitions of Er(superscript 3+), respectively. In the samples, the cerium dopant exists as Ce(superscript 3+) and Ce(superscript 4+). Ce(superscript 3+) sensitizes Er(superscript 3+) and enhances the luminescence intensity of the doped nanorods remarkably and energy transfer from Ce(superscript 3+)→Er(superscript 3+) was observed.

对发光机理的初步研究表明:发光分别对应于Er(上标 3+)的2H(下标 11/2)→4I(下标 15/2),4S(下标 3/2)→4I(下标 15/2)跃迁,铈离子以Ce(上标 3+)和Ce(上标 4+)两种形式存在于体系中,Ce(上标 3+)对Er(上标 3+)起敏化作用,可以显著增强β-BBO:Er(上标 3+)/Ce(上标 3+)/Ce(上标 4+)纳米棒的发光强度,存在Ce(上标 3+)→Er(上标 3+)的能量传递过程。

When the concentrations of tetrabutyl ammonium bromide and KI in solution were 5.0×10^(-4) mol/L and 3.0×10^(-3)mol/L at pH 3.0, Bi(superscript 3+) could be quantitatively separated from Mo, Ga(superscript 3+), Co(superscript 2+), Mn(superscript 2+), Zn(superscript 2+), Rh(superscript 3+), Al(superscript 3+), Cr, V, Ni(superscript 2+), Sn, W and Fe(superscript 2+).

当溶液中溴化四丁基铵和碘化钾的浓度分别为5.0×10^(-4) mol/L和3.0×10^(-3)mol/L和在PH3时,Bi(上标 3+)可与Mo,Ga(上标 3+),Co(上标 2+),Mn(上标 2+),Zn(上标 2+),Rh(上标 3+),Al(上标 3+),Cr,V,Ni(上标 2+),Sn,W和Fe(上标 2+)定量分离。

The initial rate V0 was influenced by the ratio of molar concentration for butanol to hexanoic acid C(superscript 0 subscript ROH)/C(superscript 0 subscript HA)(at a range of 0.2-17). As C(superscript 0 subscript ROH)/C(superscript 0 subscript HA) decreases, especially when C(superscript 0 subscript ROH)/C(superscript 0 subscript HA), the V0 increases rapidly.

反应初始速率V0与正丁醇和正己酸摩尔浓度的比值C(上标 0 下标 ROH/C(上标 0 下标 HA)有关,在C(上标 0 ROH)/C(上标 0 下标 HA)=0.2-17范围内,随C(上标 0 下标 ROH)/C(上标 0 下标 HA)比值减小,初始速率V0增大,尤其是当C(上标 0 下标 ROH)/C(上标 0 下标 HA)时,V0迅速增大。

The results indicate that the synthesized sphene has a good chemical durability in the aqueous solution whose pH value is 5-9, the temperature and pH of the solution have important influences to its chemical durability in 1-21 days.

结果表明,在pH为5~9的水溶液中,合成榍石具有良好的化学稳定性,温度和pH是影响1~21 d化学稳定性的重要因素;42 d Ca(上标 2+)的浸出率比Ti(上标 4+)的浸出率高2个数量级;在90℃、pH=7下,Ca(上标 2+)和Ti(上标 4+)的42d归一化浸出率分别为3.33×10^(-3)、1.33×10^(-5)gm^(-2)d^(-1);在25℃、pH=7下,Ca(上标 2+)和Ti(上标 2+)的42d归一化浸出率分别为1.52×10^(-3)、3.05×10^(-5)m^(-2)d^(-1);在25℃、pH=3下,Ca(上标 2+)的42d归一化浸出率达到7.71×10^(-2)gm^(-2)d^(-1)。

For k≥1, an isometry φ between codes over Zsubscript P(superscript k+1 and codes over Z(subscript P^2) is introduced and used to give a generalization of the Gray map φ: Z(superscript n subscript 4)→F(superscript 2n subscript 2). Furthermore, by means of this isometry, the concept of negacyclic codes is extended to codes over the ring Zsubscript P(superscript k+1. A characterization of these codes in terms of their images under φ is given. It is also shown that the generalized Gray map image of the 1-P(superscript k-cyclic code is a distance-invariant quasi-cyclic code.

文章引入了Z下标 P(上标 k+1码和Z(下标 P^2)码之间的等距同构φ(k≥1);利用φ把Gray映射φ:Z(上标 n 下标 4)→F(上标 2n 下标 2)推广为φ:;而且利用φ,负循环码概念被推广到Z下标 P(上标 k+1码,得到了1-P(上标 k-循环码;依据等距同构φ,给出了这些码的表示;也证明了1-P(上标 k-循环码在推广的Gray映射下的像是距离不变的准循环码。

The gold nanoparticle has a maximum absorption peak at 532 nm. The chloroauric acid concentrations and the influence of Cu(superscript 2+), Zn(superscript 2+), Ca(superscript 2+), Fe(superscript 3+), Mg(superscript 2+) and Al(superscript 3+) on the determination were examined.

研究了氯金酸用量等因素对体系的影响,优化了试验条件,并对水中Cu(上标 2+),Zn(上标 2+),Ca(上标 2+),Fe(上标 3+),Mg(上标 2+),Al(上标 3+)等常见离子进行了干扰试验。

The results of physicochemical tests showed that the pigment was a kind of water dissolvable pigment with heat stability.

榛子壳棕色素为水溶性色素,具有良好的耐热性;强光长时间照射会影响色素的稳定性;在pH值4~12范围内,色素稳定性良好;Na,K,Ca(上标 2+),Al(上标 3+),Mg(上标 2+)对色素无影响,但Fe(上标 3+),Cu(上标 2+),Zn(上标 2+)对其影响较大;色素对常见的食品添加剂稳定,但柠檬酸使其发生轻微褪色。

The influence of Fe(superscript 2+) adjustment in omphacite on the p-t conditions has been discussed by comparison, and the charge balance method has been recommended as the ideal one for Fe(superscript 2+) adjustment in omphacite.

本文通过对南大别太湖地区和桐城地区榴辉岩中绿辉石的四种Fe(上标 2+)的校正比较,依据计算的峰期变质p-t条件和岩相学研究的限定,探讨了绿辉石Fe(上标 2+)的校正对温度压力计算的影响,认为电价平衡是目前较为理想的校正绿辉石Fe(上标 2+)的方法,并建议为保证分析的准确性和全面性,配合使用端元组分调Fe(上标 2+)法和Fe(上标 2+)/Fe(上标 3+)=1:1方法。

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