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Novel chitosan derivative with long alky groups as the hydrophobic moieties and carboxymethyl groups as the hydrophilic moieties was synthesized. The chemical structure of N-octyl-O, N-carboxymethyl chitosan was characterized via FTIR, 1H NMR and elemental analysis. The physical properties were analyzed with wide angle X-ray diffraction and differential scanning calorimetry.

以天然可生物降解的壳聚糖为原料,通过在壳聚糖6位羟基上引入羧甲基,在2位氨基上引入疏水烷基链,制得N-辛基-O,N-羧甲基壳聚糖两亲性衍生物,分别用FTIR、1H NMR和元素分析等技术对其结构进行表征,用广角X射线衍射和差示扫描量热法对具物理性质进行分析,并考察其在各种溶剂中的溶解性能及其对难溶性药物的增溶能力。

Moreover, it was successfully linked with lactobionic acid through amine groups on the surface of particles, and used to recognize living liver cells successfully.(3) In order to simplify the proceeding of preparation of silica-coated qdots, a novel one-pot method using 3-mercaptopropyl-trimethoxysilane as a capping molecule was proposed for the first time. Furthermore, amine and phosphonate groups were also modified on the surface of silica-coated qdots simultaneously. This was the first time the synthesis and the surface modification of qdots were performed in the same system.

3在前一部分工作的基础上,进一步简化量子点的合成与包壳步骤,以MPS为稳定剂,制备了硅壳包被的CdTe量子点,并在硅壳外同步修饰氨基及磷酸基团,首次成功实现了量子点的合成与表面的功能化修饰在同一体系中进行,从而制得了水溶性的、表面带有氨基和磷酸基团的硅壳型CdTe量子点。

The Vice President of Shell Bitumen, Egbert Veldman, said:?"The acquisition of KMC represents a step change in the scale of Shell′s bitumen business, improving market coverage and allow ing us to offer quality road surface products across China."

壳牌全球沥青业务副总裁爱格博特·沃德曼表示:&收购科氏中国标志着壳牌沥青业务在规模上迈上了一个新的台阶,这将进一步提高壳牌在中国的市场覆盖率,从而使我们能够为全国的客户提供更多的优质沥青产品。&

The Vice President of Shell Bitumen, Egbert Veldman, said:?"The acquisition of KMC represents a step change in the scale of Shell′s bitumen business, improving market coverage and allowing us to offer quality road surface products across China."

壳牌全球沥青业务副总裁爱格博特·沃德曼表示:&收购科氏中国标志着壳牌沥青业务在规模上迈上了一个新的台阶,这将进一步提高壳牌在中国的市场覆盖率,从而使我们能够为全国的客户提供更多的优质沥青产品。&

The Vice President of Shell Bitumen, Egbert Veldman, said:?"The acquisition of KMC represent s a step change in the scale of Shell′s bitumen business, improving market coverage and allowing us to offer quality road surface products across China."

壳牌全球沥青业务副总裁爱格博特·沃德曼表示:&收购科氏中国标志着壳牌沥青业务在规模上迈上了一个新的台阶,这将进一步提高壳牌在中国的市场覆盖率,从而使我们能够为全国的客户提供更多的优质沥青产品。&

The Vice President of Shell Bitumen, Egbert Veldman, said:?"The acquisition of KMC represents a step change in the scale of Shell′s bitumen b us iness, improving market coverage and allowing us to offer quality road surface products across China."

壳牌全球沥青业务副总裁爱格博特·沃德曼表示:&收购科氏中国标志着壳牌沥青业务在规模上迈上了一个新的台阶,这将进一步提高壳牌在中国的市场覆盖率,从而使我们能够为全国的客户提供更多的优质沥青产品。&

We found that under acid condition, selenite radical combined with active hydroxide radical and amino-group of chitooligosaccharides to form chitooligosaccharides - Se compound molecule, the remaining group complex interacted with the negative sodium tripolyphosphate via electrostatical interactation to form nanoparticles with the size about 100nm.

通过透射电镜、粒径分析仪等方法表征,发现壳寡糖-硒纳米颗粒平均粒径为100nm左右,在酸性条件下,亚硒酸根与壳寡糖单元上活性羟基和氨基化合,形成壳寡糖-硒复合分子,剩余的基团与带负电的多聚磷酸钠复凝聚,在4℃下能够稳定保存,25℃以上壳寡糖溶胀而致纳米颗粒发生分解。

Based on the detailed study of seismic tomography image in South China, and according to the geotectonic environment and shape and heat of asthenosphere upwelling, we divided the structure of lithosphereasthenosphere at the Mesozoic upper mantle of Eastern China into three types.(1)Continental platform area (North China platform and Yangtze platform): asthenosphere upwelled along paleorift; over the plume head, the granitic rocks of crust and mantle mixed and correspondingly, Au, Cu, Mo, PbZn, etc. mineralizationconcentrated regions were formed; and at the steep contact belt of asthenosphere and the thick area of lithosphere, mediatebasic complex was formed.(2)Central area of fold zone: asthenosphere was "recumbent" at suitable depth, with adequate heat and in a great extent; by heat conduction, the interior of partial crust remelted, and the crustsource granitic rocks, and correspondingly, W, Sn and rare elements mineralizationconcentrated regions were formed.

在深入研究华南地震层析成像的基础上,按照大地构造环境和软流圈上涌形状和热度,将中国东部中生代上地幔中岩石圈软流圈构造划分为3类:(1)陆台区,软流圈沿古裂陷上涌,其柱头上方形成幔壳混熔花岗质岩及相应Au、Cu、Mo、PbZn等矿集区,并于软流圈与岩石圈厚区之陡接触带形成中基性杂岩及相应Fe矿集区;(2)褶皱带中心区,软流圈在适当深度、热量充足、较大范围内&平卧&,因热传导而致使地壳内物质部分重熔,形成壳源型花岗质岩及相应的W、Sn、稀有元素矿集区;(3)褶皱带边缘区(大兴安岭南部及华南南缘),在软流圈上涌柱上方形成幔源或幔壳混熔的花岗质岩,相应为Cu、Au、PbZn、Mo、Ag矿集区。

The results for the double-ayered show that, owing to the presence of concrete outer layer of the shell, the maximum boundary stress of steel is reduced to about 20—25%, and the pressure distribution between these two layers takes the sha...

在此基础上,作者提出了计算双层蜗壳的近似方法。在三夹层蜗壳的试验中,测量了内外层钢板的应力,发现这种结构不仅在工艺上有其特点,而且能在很大程度上消除蜗壳边界的应力高峯。

According to the present situation of Hebei province, chitin was extracted from waste crab shells of Qing Huangdao, and then chitosan was prepared. On the base of those, a series of chitin/chitosan derivatives were synthesized and characterized. Finally,~then they were applied in fruit preservative, flocculation and cosmetics. The main results ~re summerized as follows:(1) Chitosans with low, middle and high viscosity have been prepared from chitin, which was extracted from waste material of crab shells produc ed in Qing HuangDao.

并对针对河北省的资源情况,从秦皇岛蟹壳废料中提取甲壳素,制备壳聚糖,在此基础上制备了一系列甲壳素/壳聚糖的衍生物,对其结构与性能进行深入的研究,并开发其在食品保鲜、污水处理、化妆品等方面的应用,具体分述如下:(1)以所提取的甲壳素为原料,在浓碱溶液中通过正交实验法对壳聚糖的制取条件进行优化,确立制备低、中、高三种粘度壳聚糖的最佳条件。

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