三键

All the compounds are characterized by IR and elemental analysis.we design and prepare a bipyridinium supramolecular compound and six coordination compounds, which are also characterized by IR, elemental analysis and X-ray structure analysis. According to X-ray structure analysis, hydrogen bonds and n-n stocking interactions participate in the architecture of three-dimensional framework [H2L1 (NO3)2 (H2O)2]n; one-dimensional zigzag coordination polymer [Hgl21.5CH3OH]n; binuclear metallamacrocycle (HgI2L2)2 3H2O; helical double-stranded one-dimensional coordination polymer [Co2(L2)2-2CH3OH]n; double-stranded one-dimensional coordination polymer [Co2(L3)2-CH3OH-CH3CN]n; and three-dimensional compound [Cu(C5H4NCOO)2(H2O)2]-H2O with hydrogen bonds, three-dimensional coordination polymer {[Cd(C5H6NCOO)2H2O]-DMF}n, which are indirectly obtained from the precursor ligand L3 through metal ion induced the hydrolysis of diamide and self-assembled with the hydrolyzate.

我们首次合成了一个双吡啶鎓超分子化合物和六个过渡金属配合物，并通过IR谱，元素分析和X-ray晶体衍射分析对它们进行了表征。X-ray晶体结构分析表明：超分子化合物[H_2L1·(NO_3)_2·(H_2O)_2]_n是由多种氢键和芳香环间的π-π堆积作用构建的三维无限结构；[HgI_2(L1)·1.5CH_3OH]_n是一维锯齿状配位聚合物；(HgI_2L2)_2·3H_2O是双核金属大环化合物；[Co_2(L2)_2·2CH_3OH]_n是具有一维双螺旋结构的配位聚合物；[Co_2(L3)_2·CH_3OH·CH_3CN]_n为一维双链结构的配位聚合物；以及由非直线形配体L3在金属离子Cu和Cd的诱导作用下发生水解，并且金属离子与水解产物——异烟酸根离子自组装，形成了三维氢键超分子化合物[Cu(C_5H_4NCOO)_2(H_2O)_2]·H_2O和三维配位聚合物{[Cd(C_5H_6NCOO)_2H_2O]·DMF}_n。

When all the enemies may be able to pass out more and enter the upgrade menu, a total of three can be upgraded: body volume upgrade upgrade upgrade weapons and weapons firing rate options: A button: fire up and down arrow keys: rotate the body S Key: Laser guns blank keys: keys to accelerate D: slow-motion mode

当所冇敌人都些灭后就可鉯过关，并且进入升级单选，ー共冇三种可鉯升级：升级机体血量升级武器威力升级武器射速玩法：A键：射击方向键仩下：旋转机体S键：雷射炮涳白键：加速D键：慢动作模式

It provides a route tothe compounds which contains three functional groups, two carbon-nitrogentriple bonds and one carbon-carbon double bond. In water, metallic indiumpromotes carbon-sulfur bond coupling reaction of aromatic sulfonyl chloride withsuitable organic halides to afford sulfones. In the last chapter, metallic tin mediated allylation of aldimines with allylbromide was revealed.

第三章，我们研究了在水相介质中金属铟促进的烯丙基溴对1，1-二氰基-2-芳基乙烯的Michael加成反应，生成一个含碳碳双键和二个碳氮叁键的三官能团化合物，另外，金属铟在水介质中还可以促进芳基磺酰氯与卤代烃发生碳硫键的偶联，生成砜。

The Mo center of [Mo8](superscript 4)-shows a slight distorted square antiprism coordination environment. The N atoms of cyano groups, acting as acceptors of hydrogen bonds, together with protonate N atoms from organocations and the lattice water, serving as donors of hydrogen bonds, form intricate hydrogen bond interactions, thus generating three-dimensional supramolecular network with the help of π-π interactions of some organocations.

Mo8(上标 4-)离子中，Mo中心处于扭曲的反四棱柱配位环境。8个未配位的氰基氮原子作为氢键的受体，有机阳离子上质子化的氮原子和结晶水作为氢键的给体，形成了丰富的氢键作用，这些氢键作用连同部分有机阳离子间的π-π堆积、阴阳离子间的静电力和Van Der Waals力构筑成三维超分子网络。

Reaction of 5'-O-p-methoxytrityl-thymidine with 1, 1'-carbonyl-diimidazole gave the 3'-O-carbonylimidazolide, which was condensed in high yield with 3'-O-protected thymidine to give a dithymidine carbonate. In the same way, we obtained the protected trithymidine dicarbonate. After deprotection, we obtained quantatively the trithymidine dicarbonate.By the same stratagy, we completed the synthesis of dithymidine sulfite.It was shown that allyl can be used as a good protection group for hydroxyl of ribose in the synthesis of oligonucleotides consisting in some unstable nucleotide analogues.

我们在第一部分工作的基础上，以烯丙基作为3'-OH的保护基合成了保护的三胸苷碳酸酯以及二胸苷亚硫酸酯，用我们所得的脱保护条件进行了脱保护研究，得到了三胸苷碳酸酯以及二胸苷亚硫酸酯，并研究了它们合成中的一些化学问题，结果表明：烯丙基能很好地运用于这两类寡核苷酸类似物的合成中，其脱保护条件为中性，不会影响碳酸酯键及亚硫酸酯键。

Results show that intramolecular hydrogen transfer is not favored in view of the energy trend along IHT coordinate in the region such as hypericin's peri region, where two hydrogens of hydroxyl groups bond with a common oxygen of carbonyl group and exists two IHBs in the peri region. However, intramolecular proton transfer often occur in the molecule with hexahydric cycle hydrogen bond, where only one pair of adjacent hydroxyl group and carbonyl group.

此外选择设计了一个具有三个分子内氢键的体系，兼具金丝桃蒽酮和其他苝醌类光敏剂的分子内氢键特点，研究表明两个羟基氢与共同的羰基氧形成的氢键由于存在较高的势垒，很难发生分子内氢传递，即具有金丝桃蒽酮端位结构的分子其分子内氢传递很难发生，而一般的能形成六元环状结构的分子内氢键体系容易发生分子内氢传递。

1H-imidazolyl)-1H-imidazolium chloride-4-aminobenzoic acid, 2,2-bi-1H-imidazolium bis(3,4,5-trihydroxy benzoate) tetrahydrate and bis2-(2-1H-imidazolyl-1H-imidazolium 3-carboxy-4-hydroxybenzene-sulfonate monohydrate have been synthesized and characterized by X-ray diffraction methods.

在化合物中，晶体结构中的基本单元是一个通过氢键模式R_2~2(9)和R_2~1(7)构成的氢键三聚体PABA…H_3biim~+…Cl~-，这个三聚体基本单元又通过N-H…Cl氢键相互作用形成了一维带状结构。

Theoretical calculations on a series of N-H…O=C hydrogen bond trimers were carried out using the MP2 method. We investigated the effect of substituents in hydrogen bond donor molecules on their hydrogen bond strength.

使用MP2方法研究了氢键三聚体中N-H…O=C氢键强度，探讨了氢键受体分子中不同取代基对N-H…O=C氢键强度的影响。

The results are compared to those of pulse radiolysis. A detail oxidation mechanism of sulphur containing amino acids was proposed. The structure of amino acid and peptide influence information of three electron bond was suggested.

首次在中性介质中观察到反应过程中生成了三种含硫三电子键自由基中间体，〓、〓和，测定了动力学常数，分析了反应机理，讨论了肽分子结构对三电子键形成的影响。

With the weight playing method and mechanics principles in physics, the relation between touches on keys and their tone colors is studied in a microscopic way, analyzing three aspects of the force of touch, the speech of touch and the angle of touch specifically.

结合重量弹奏法及物理力学原理，从触键力度、触键速度和触键角度三个方面进行具体的分析，从微观处入手研究触键与音色的关系。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。