三键

From the ester n, the intermediate Ⅲwas produced by the Sonogashira coupling reaction with terminal alkynes under the co-catalysts of Pd2 and Cul. These final products of alkynyl benzamide derivatives IV were obtained by the cleavage of support with primary or second amines.

液相合成兼容了固相合成可快速简便地对产物进行分离纯化以及溶液相合成可在均相条件下进行反应和用常规手段对反应中间体进行分析检测的优点，用聚乙二醇4000作为可溶性聚合物支持体，通过醚键将[1，3，5]氯三嗪连接在PEG上制备成PEG支持的新型的可溶性聚合物试剂I。

Trifluoromethanesulfonic acid was found to be able to efficiently activate the benzylic sp3 C—F bond.

三氟甲磺酸被发现能够高效地活化(SP3)碳－氟键。

Next HOMO or HOMO-1 for the radical cations calculated by the ab initio 3-21+G^* method, and the atom-pair interaction energy determined by NMDO calculation, it is shown that when n is equal to or largey than 3 in the bridge chain (CH2)n for bicyclo diamine radical cations, the bridgehead nitrogen atoms form a weak N, N'-three-electron σ-bond through space.

通过比较这些阳离子几何构型，HOMO和NHOMO(即NextHOMO和HOMO-1)，和由MNDO计算确定的原子对作用能，表明当二氮双环游离基阳离子的桥链(CH2)n的n≥3时，桥头氮原子通过空间相互用用形成了一个弱的N，N'-三电子σ键。

Four kinds of aromatic ether-linked dinitriles with low melting temperatures were obtained via the nucleophilic substitution of hydroquinone, resorcinol, biphenol and bisphenol A with CBN. They were polymerized to afford a series of poly(pheny-s-triazine)s under the optimized conditions.

以对苯二酚、间苯二酚和联苯二酚为原料，分别与对氯苯腈进行亲核取代反应，合成了三种较低熔点的含醚键二腈，并分别研究了其在优化条件下的聚合反应。

In order to study strcture-bioactivity relationship concerning α,β-unsaturated-γ-lactones, we further synthesized γ-benzyloxymethy-γ-butanolide XXIII and the corresponding unsaturated buteno- lido XXV Scheme 6, p.

为了研究该类化合物的构效关系，在本论文第三部分，我们进一步设计并合成了--γ-苄氧基甲基-γ-丁内酯XXIII和--γ-苄氧基甲基-γ-丁烯内酯XXV这两个内酯化合物，目的是想考察内酯的α，β-不饱和双键是否是产生细胞毒性的关键结构。

Optically active cyclophane s, such as helical molecules and three-dimensional, cagelike cyclophanes have been the subject of extensive investigation from the standpoints of structural chemistry and material science.

本论文在大量的文献调研和本实验室过去研究结果的基础上，设计了由2，2'-二取代-1，1'-联萘和2，6-二取代吡啶，1，4-二取代苯，4，4'-二取代联苯三种不同连接桥通过炔键链接构筑的拓扑有趣的光学活性环芳化合物-四联萘笼状分子。

The foam properties of four kinds of cleavable s-triazine fatty sulfonate surfactants with different length of alkyl chains were studied by improved Ross-Miles method.

采用改进的Ross-Miles法研究了4种不同烷基链长的可断键均三嗪脂肪磺酸盐表面活性剂(OSEAT、DSEAT、TSEAT、HSEAT)的泡沫性能，考察了质量浓度、温度、Ca2+浓度对它们泡沫性能的影响。

The foam properties of four kinds of cleavable s-triazine fatty sulfonate surfactants with different length of alkyl chains were studied by improved Ross-Miles method. The effects of mass concentration, temperature and calcium ion concentration on their foam properties were discussed.

采用改进的Ross-Miles法研究了4种不同烷基链长的可断键均三嚓脂肪磺酸盐表面活性剂(OSEAT、DSEAT、TSEAT、HSEAT)的泡沫性能，考察了质量浓度、温度、Ca(上标 2+)浓度对它们泡沫性能的影响。

Both crystallographically unique Zn atoms exit as an octahedral geometry. The four equatorial positions of Zn1 atom are occupied by the carboxylate-oxygen atoms of the two tartrates, and the two oxygens of the left four carboxylate-oxygen atoms coordinate to two different Zn2 atoms, respectively, forming infinite coordination polymer chains. The left two of the trans equatorial positions of Zn2 atom are completed with two oxygen atoms of two water molecules. The axial positions of both Zn atoms are occupied by the nitrogen atoms from different 4,4'-bipyridine molecules to give a 2D rectangular-grid layers with a cavity dimension of 0.51165(3)nm×1.13896(5) nm. A three dimensional network is formed by the crystallization water chains joined by the carboxylate-oxygen atoms through hydrogen-bonding interactions.

两个晶体学独立的Zn原子均为八面体构型，其中Zn1原子赤道配位点被2个酒石酸根中的4个羧酸根氧螯合配位， 2个酒石酸根中剩下的4个羧酸根氧中的2个分别与2个Zn2原子连接形成无限一维链， Zn2原子的另外2个反式赤道配位点被2个水分子氧占据，同时这两种Zn原子的轴向配位点均被4，4'-联吡啶的氮原子占据，形成具有矩形格子[0.51165(3) nm×1.13896(5) nm]的二维层状结构，游离的2个水分子通过氢键作用形成二聚体，并与酒石酸根中未与Zn配位的羧酸氧连接，把二维层状结构连接成三维网状的超分子结构。

Carbon disulfide, dialkylamine, antimony trioxide have been used to synthesize the other organic antimony compounds-dialkyldithiocarbamate. The optimal technological conditions and purificating method have been studied in detail.

以二硫化碳、二元仲胺、三氧化二锑为原料合成了结构为Sb-〓的另一类含Sb-S键的有机锑化合物，通过大量的实验探索，详细研究了各种二烷基二硫代氨基甲酸锑的最佳合成工艺条件及产品的提纯方法，为该类化合物的制备提供了一种工艺简便，收率较高的合成工艺途径。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。