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The research consists of three parts: First is to prepare the five high-purity synthetic evaporite minerals powders, including gypsum, calcite, chalcanthite, nitratine and hydromagnesite, and to verify their phases and purities by XRD. Second is to conduct a series of thermal decomposition experiments of the powders by TGA at various heating rates and isothermal condition.

实验设计上可分为三部分,首先准备符合石膏、方解石、胆矾、钠硝石与水菱镁矿等五种矿物成分之试药等级粉体,再以XRD确认其矿物相是否正确;第二部分以热重分析仪进行等升温与等温条件热分解实验;最后以三种动力学方法分析拟合热重分析所得到的反应数据。

The appropriate conditions are that the mole ratio of cyanuric chloride to ethylamine, sodium hydroxide, sodium methyl mercaptide is 1:2.1:2.1:4.0, the temperature and time of first, second, third substitution reaction is respectively 0℃, 20℃, 78℃ and 10min, 30min, 480min.

适宜反应条件为三聚氯氰:乙胺:氢氧化钠:甲硫醇钠=1:2.1:2.1:4,第一、第二、第三取代反应的反应温度和反应时间分别为0,20,78℃和10,30,480min。

In order to reduce the corrosion of acidic paint stripper to aeronautical metals and provide with better anti-corrosion additive for AIL4130, TC4, LY12, and 20(superscript #) steel, a series of inhibitors and their composite were investigated. Weight loss experiment, Tafel curves measurement and SEM observation were carried out for the above metals in the formic acid solution which was normally used in the paint stripper. The experimental results indicate that the optimizing composite inhibitor consists of sodium benzoate, 2-thiourea, hexamethylenetetramine, sodium laurylsulfonate and 1, 2, 3-benzotriazole.

为降低酸性脱漆剂对飞机金属材料的腐蚀,以脱漆剂中经常使用的甲酸水溶液为研究介质,以AIL4130、TC4、LY12、20钢等材料为研究对象,通过腐蚀失重法、塔菲尔曲线测量和SEM观察,筛选出对以上各金属材料缓蚀效果较好的复配缓蚀剂体系,即苯甲酸钠、硫脲、六次甲基四胺、十二烷基磺酸钠、苯并三氮唑等缓蚀剂的优化组合。

The study is to synthesize dual-site phase-transfer catalyst, and use it to form tri-liquid phases, and investigate the catalytic benzoylation of 4'-hydroxyacetophenone sodium salt and benzoyl chloride to produce 4-acetylphenyl benzoate in ultrasound-assisted tri-liquid-phase system.

中文摘要本研究在合成双活性基相间转移触媒,并使用该触媒合成三液相系统,并辅以超音波在三液相系统中催化4-乙醯基酚化钠与氯化苯甲醯形成苯甲酸4-乙醯基苯酯的反应。

3NE、MTT、LDH、ET-1、ICAM-1 and Tie-2experiment show: in the process of oxygen glucose deprivation/reoxygenation ,BMEC have subjected great damagement, I/R groups have significant differences compared with NC groups (p.05);polymorphonuclear leukocyte can aggregrate this injury, I/R+PMN groups have significant differences compared with I/R groups (p.05); after Sivelestat Sodium treatment, the effect of I/R injury has been decreased, I/R+PMN+Siv groups have significant differences compared with I/R+PMN groups (p.05), and NE、MTT、LDH experiment show that the three dose groups there was a significant dose-effect relationship.

3测定NE、MTT、LDH、ET-1、ICAM-1、Tie-2 mRNA均显示:氧糖剥夺/复氧复糖过程能对BMEC造成损伤,I/R组与NC组比较有明显的统计学差异(p.05);中性粒细胞能加重对BMEC的损伤,I/R组与I/R+PMN组之间比较亦有统计学差异(p.05);西维来司钠处理后,血管内皮细胞的损伤明显减轻,I/R+PMN组与I/R+PMN+SIR组比较有统计学差异(p.05),并且NE测定以及MTT、LDH实验提示在西维来司钠三个剂量组之间存在明显的量-效关系,其对BMEC的保护作用有剂量依赖性。

It has a high activated alkali degree,strong PH buffering effect,and strong resediment effect.It cooperates with suface activated agent well. Its aid-washing effect and detersive power in scour is almost the same with that of STPP,so it can replace STPP.It is an excellent new silicate non-phosphor washing assistants.It can be used to produce washing power in both front and back compound product line.It is also an imporant washing assistant for paste and liquid washing as well as basic raw material for industrial scour.It has wider foreground in market.

层状结晶硅酸钠具有较强的软化水和去污能力,很好的活性碱度,PH缓冲能力和抗再沉积能力强,与表面活性剂有较好的协同作用,用在洗涤剂中的助洗效果和去污能力与三聚磷酸钠相近,是优秀的新型硅酸盐助剂,可用于前后配料生产洗衣粉,也是膏状、液体洗涤剂的重要助洗剂及工业清洗剂的基础原料,产品市场前景广阔。

The synthesis methods of ethyl lactate catalyzed by P-toluene sulfonic acid, cationic exchange resin, ferric chloride hexahydrate, stannous chloride, Aluminium chloride, modified zirconium oxid, ferric-potassium vitriol, ammonium ferric sulfate dodecahydrate, rave earth sulfate, sodium bisulfate monohydrate, complex solid superacid, heteropoly acid, molecular sieve, ionic liquid and lipase etal.

评述了对甲苯磺酸,阳离子交换树脂,六水三氧化铁,氯化亚锡,三氯化铭,改性氧化锆,铁钾矾,十二水合硫酸铁铵,稀土硫酸盐,一水硫酸氢钠,复合固体超强酸,杂多酸,分子筛,离子液体和脂肪酶等催化剂催化合成乳酸乙酯的合成方法。

Then the contents of brain tissue water, malonyl diadehyde and the activities of Na+-K+-adenosine triphosphatase (Na+-K+-ATPase), Ca2+-Mg2+-adenosine triphosphatase (Ca2+-Mg2+-ATPase), CuZn-superoxide dismutase and mitochondrial Mn-superoxide dismutase were measured.

测定脑组织含水量、丙二醛含量、钠钾三磷酸腺苷酶(Na~+-K~+-ATPase)、钙镁三磷酸腺苷酶Ca~(++-Mg~-ATPase、铜锌超氧化物歧化酶以及线粒体锰超氧化物歧化酶的活力。

With sodium acetate as catalyst, inosine was esterified with acetic anhydride in the yield of 92% to give 2',3',5'-triacetyl inosine, which was treated with pyridine and phosphorus oxychloride to form a pyridinium solution, followed by performing an amination at 40℃ and 0.25~0.30 MPa to achieve adenosine in the yield of 67%.

肌苷在醋酸钠存在下与醋酸酐发生酯化反应以92%的收率得到2',3',5'-三乙酰肌苷,其化合物经吡啶和三氯氧磷处理形成吡啶盐溶液,未分离直接在40℃、0.25~0.30 MPa压力下进行氨解反应以67%产率制得腺苷。

Using phosphorus trichloride as the base raw material, we try out the water dosage on hydrolysts, drop quomodo of phosphorus trichloride, the ratio of phosphorus trichloride and MSIDA, other trial operate, and find out the best synthesis method.

用三氯化磷为基本原料,研究了水解用水量、三氯化磷滴加方式、三氯化磷与亚氨基二乙酸一钠盐的配比和工艺操作条件等因素的影响情况。

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