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The surface hydroxyl group onto magnetic polyvinyl acetate nanoparticles can be obtained by saponification reaction on their surface.

结果表明,磁性聚苯乙烯颗粒与丁二酸酐发生Freidel-Crafts酰基化反应,可以在颗粒表面引入少量羧基;磁性聚甲基丙烯酸甲酯颗粒分别与乙二醇、二缩三乙二醇、聚乙二醇等发生醇-酯交换反应,可以在颗粒表面接枝不同分子链长度的末端羟基;磁性聚醋酸乙烯酯颗粒经过醇解或皂化反应可以获得表面羟基;磁性聚丙烯酸甲酯颗粒通过乙二胺或1,6己二胺的胺解反应可以得到表面氨基,继而与一氯乙酸反应可以引入亚胺二乙酸基团。

Cellulose Triacetate: Transparent, flexible material used as a base support for photographic emulsions.

三醋酸纤维素:透明的,柔软的用作摄影乳剂的片基的材料

Acetate-Base Film: Any film with a support that contains cellulose triacetate; safety film.

醋酸纤维片基∶任何具有片基的胶片其片基由三醋酸纤维素酯组成;安全胶片。

Cellulose diacetate and cellulose triacetate, for example, are not attacked by microorganisms because most of the hydroxyl groups have been converted to acetate groups.

比方说由于大部分的羟基已经被转化成了醋酸基,双乙酸纤维素和三乙酸纤维素就不再受微生物的侵蚀。

By forming simultaneously photosensitive layers on both-sides of cellulosetriacetate film with chemical reaction, we obtained a holographic recording film withstratified sensitivity─dichromated cellulose triacetate.

通过化学反应,在三醋酸纤维素酯片基的正反两面同时生成具有感光活性的光敏层的方法,获得了一种具有叠层光敏性的全息记录软片:重铬酸盐一三醋酸纤维素酯。

In part one, the reactions of some active fluorine-containing compounds such as 2, 2-dihydropolyfluoroalkanoic acids and ethyl 2-hydropolyfluoroalkenoates were studied and various fluorine-containing heterocyclic compounds were synthesized. Using 2, 2-dihydropolyfluoroalkanoic acids as the starting material, 4-fluoroalkyl quinolin-2-ols, 2- [ -1-hydropolyfluoro-1-alkenyl] -4H-3, 1-benzoxazin-4-ones, 1-aryl -4, 9-dihydro-3-fluoro-alkyl-1H-pyrazo [3, 4-b] quinolin-4-ones, 5-fluoroalkyl-12H-quin olino [2, 1-b] quinazolin-12-ones, 4-fluoroalkyl-1, 3-dihydro-1, 5-benzodiazepin-2-ones and 4-fluoroalkyl-2H-pyrido [1, 2-a] pyrimidin-2-ones were synthesized through its condensation reaction with anilines, anthranilic acid, N'-aryl-o-aminobenzamides, o-nitro aniline, o-amino pyridine and their derivatives and the subsequent transformations. 5-Fluoroalkyl isoxazolidines, 3-fluoro-3-fluoroalkylisoxazolidino [4, 3-c] quinolin-4-ones, 3-fluoroalkylisoxazolino [4, 3-c] quinolin-4-ones and 2-aryl-3per fluoroacylindoles were synthesized by inter-and intramolecular 1, 3-dipolar cycloaddition of fluorine-containing olefins and nitrones.

第二部分,我们研究了α,α-二氟苄基卤类化合物的亚磺化脱卤反应、产物的转化及全氟烷基亚磺酸盐与芳环化合物的全氟烷基化反应,发现全氟苄基碘或溴及α,α一二氟苄基溴在保险粉等亚磺化脱卤试剂引发下可生成相应的亚磺酸盐;全氟苄基亚磺酸盐与氯气或溴反应可生成全氟苄基磺酰氯或磺酰溴;在烯烃存在下,全氟苄基碘则与烯烃发生加成反应,生成相应的1:1加成产物;在三价醋酸锰的作用下,部分芳香化合物如茴香醚,二甲氧基苯,吡啶,喹啉等可以和过量的全氟烷基亚磺酸盐发生双全氟烷基化反应,反应表现出一定的区域选择性,产率良好。

In a large test tube, dissolve 0.5 g (4.5 mmole) of semicarbazide hydrochloride and 0.5 g of anhydrous sodium acetate (or 0.8 g of sodium acetate trihydrate) in 4 mL of distilled water and 7 mL of ethanol.

在一个大试管中,用4 mL蒸馏水和7 mL乙醇溶解 0.5 g (4.5 mmole)的胺基氢氯酸盐和0.5 g无水醋酸钠(或0.8 g的三水合醋酸钠)。

β-Cyclodextrin with the 6-hydroxyls protected by dimethyl-tert- butylsilyl was selectively oxidized by lead tetraacetate. After the silyl groups were removed off by boron fluoride-etherate, mono-2,3- dialdehydro-β-cyclodextrin as a cuniform molecule could be constructed.

用四醋酸铅将七元(6-O-二甲基叔丁基硅基)-β-环糊精选择氧化、并用三氟化硼乙醚脱硅基保护基后,再经分离、纯化,可获得具有&楔筒状&空腔的单-2, 3-二醛基-β-环糊精。

A series of 3,3,6,6 tetramethyl 1,8 dioxo 9 aryl 1,2,3,4,5,6,7,8,9,10 decahydro acridines have been synthesized by the condensation of aromatic aldehydes, 5,5 dimethyl 1,3 cyclohexanedione and ammonium acetate in the presence of triethylbenzylammonium chloride as catalyst in water.

芳醛、5 ,5 二甲基 1,3 环己二酮与醋酸铵在三乙基苄基氯化铵催化下以水作为溶剂反应,生成一系列 3 ,3 ,6,6 四甲基 1,8 二氧代 9 芳基 1,2 ,3 ,4,5 ,6,7,8,9,10 十氢吖啶,与其它溶剂相比,水作为该反应的溶剂具有价格便宜,不易燃和无毒等优点,而且产率较高,产物的结构通过单晶X射线确

In the course of our study the chemistry of arenes contaning allylic acetates moiety under the catalysis of palladium, we found an efficient synthesis of benzocycles via intramolecular Friedel-Crafts reaction of halogen free 6-acetoxy-4alkenyl arens.

我们在设计钯催化的碳—氢键活化时,发现了含有烯丙基醋酸酯侧链的芳烃的三氟醋酸促进的分子内的Friedel-Crafts反应,从而为有效合成苯并六元环结构提供了一个方便的方法。

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