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The common chemical constituents were juniper camphor,1,3,3-trimethylcyclohex-1-ene-4-carboxaldehyde,borneol,α-curcumene,α-bisabolol,cis-caryophyllene,benzyl benzoate,methyl β,β-dimethylbenzenepropanoic acid ester,2,4-decadienal and heneicosane in the essential oil of the five cultivars' Hangjuhua.Among them,juniper camphor is most which were composed of 11.96%,10.51%,10.95%,13.28% and 10.77% of the total essential oil,and methyl β,β-dimethylbenzenepropanoic acid ester is second,which were composed of 1.51%,1.86%,2.52%,4.89% and 2.51% of the total essential oil,respectively.

5种栽培类型杭菊花挥发油中共有成分为1,3,3-三甲基环己-1-烯-4-甲醛、冰片、α-姜黄烯、α-甜没药萜醇、顺式石竹烯、桧脑、安息香酸苄酯、β,β-二甲基苯丙酸甲酯、2,4-癸二烯醛和二十一烷;其中桧脑含量最高,分别占挥发油总量的11.96%,10.51%,10.95%,13.28%和10.77%,为5种栽培类型杭菊花挥发油中最具特征的成分;其次是β,β-二甲基苯丙酸甲酯,分别占挥发油总量的1.51%,1.86%,2.52%,4.89%和2.51%。

When the tree changes from health to weak, the main terpene compounds changed, such as the amount of 3-carene, isolimonene,β-pinene, 4-carene were significantly enhanced, and santolina triene,α-fenchene,β-myrcene,β-phellandrene were declined. It will provide a basis for Monochamus urussovi Fischer to select suitable parasitic Picea jezoensis.

鱼鳞云杉树势由健康向衰弱转变时,主要烯萜类化合物含量发生变化,3-蒈烯、异柠檬烯、β-蒎烯、4-蒈烯、α-蒎烯等含量显著上升,而神圣亚麻三烯、α-葑烯、β-月桂烯、β-水芹烯等含量下降,这些烯萜类化合物的变化,为云杉大黑天牛定位选择适宜寄生的鱼鳞云杉提供了依据。

It was also found that combined addition of α-pinene, pine oil alcohol and camphor, the inhibitors of monoterpenoid pathway, obviously improved taxol production.

同时发现单萜途径的抑制剂α-蒎烯与松油醇及樟脑三种物质一起添加对紫杉醇合成的促进作用显著。

The synthesis of terpene hydroquinone resin with turpentine and hydroguinone was studied, with AlCl 3 as catalyst.

摘 要:研究了以无水三氯化铝为催化剂,松节油与对苯二酚聚合反应制备萜烯对苯二酚树脂的情况。

It was shown from the results that emulsifier TP-Ⅴ which was prepared by PEG 4000 reacted with TME, in the molar ratio of TME to PEG 2:1, at about 110℃ for 1 h, catalyzed by boron trifluoride diethyl etherate, has a very good emulsifying impact for TME. Particle size distribution of the emulsion was homo-geneous and viscosity of the emulsion was small.

实验结果表明,以M相对适中的PEG4000与TME按物质的量比2: 1、在催化剂三氟化硼乙醚作用下、110℃左右反应1h合成的乳化剂TP-Ⅴ,对萜烯基环氧树脂具有很好的乳化效果,制备的乳液粒子粒径均一度较高,乳液表观黏度较小。

The 26 terpenoids in the essential oil extracted from the leaves of Phoebe faberi have been identified by GC-MS technique, such as-S--3,7,11-trimethyl-1,6,10-dodecatrien-3-ol (39.34%),β-caryophyllene (29.18%),-zingiberene (5.16%) and caryophyllene oxide (4.21%).

利用GC-MS联用技术从竹叶楠叶挥发油中鉴定了26个萜类化合物,如---3,7,11-三甲基-1,6,10-十二碳三烯-3-醇(相对含量39.34%)、β-丁香烯(29.18%)、姜烯(5.16%)和氧化丁香烯(4.21%)。

The biomarkers such as the n-Alkanes, the isoprenoids, the terpane, and cholestane were detected through GC-MS analysis. Based on the study of the biomarkers, the biological evolution during Permian and Triassic can be divided as three stages, namely, the mixing source stage of low biota such as thallose and advanced plant in late Permian (below bed 63), the stage of low biota such as thallose in the boundary transitional layer (bed 63-69) and the mixing source stage of advanced plant and low biota such as thallose in early Triassic (above bed 69). What's more, the second stage near the boundary transitional layer can be subdivided into 4 stages. The stages of biota evolution is close related with sedimentary environment changing and the boundary transitional layer.

利用GC—MS分析技术,在陆相地层中检测出正构烷烃、类异戊二烯烷烃、萜烷和甾烷类生物标志化合物并根据生物标志化合物和特征值研究,将二叠系—三叠系生物演化划分为三个大的阶段,即晚二叠世的菌藻类低等生物与高等植物混源阶段(63层以下),界线异常层的菌藻类低等生物阶段(63-69层)和早三叠世高等植物与菌藻类低等生物混源阶段(69层以上),界线附近异常层的第二阶段又进一步细分为4个次一级阶段,生物演化阶段与沉积环境变化及界线异常层具有非常密切关系。

In a climatically controlled chamber (28±1℃, L16:D8), E. splendens was planted in pots containing mixed vermiculite and perlite without Cu. At about 220 d after seeding, plants (around 65 cm in height) were used to collect their volatile using SPME. Eleven chemicals were identified using GC-MS, p-pinene, D-limonene, elsholtzia ketone, dehydro elsholtzia ketone,γ-elemene, humulene, caryophyllene, a-caryophyllene, and three sesquiterpenes. The most abundant volatiles were caryophyllene and y-elemene, followed by humulene and a-caryophyllene.

室内在不含Cu的蛭石和珍珠岩混合基质中种植海州香薷,用固相微萃取法收集健康植株(株龄220余天,株高65cm左右)的挥发物,采用GC-MS法识别出11种主要组分,从中鉴定出β-蒎烯,D-柠檬烯,香薷酮,脱氢香薷酮,γ-榄香烯,蛇麻烯,石竹烯,α-石竹烯(α-caryophyllene),以及三种倍半萜类化合物,其中石竹烯和γ-榄香烯含量高,其次为蛇麻烯和α-石竹烯。

Forbesii, monoterpenes and sesquiterpenes account for 41.30% and 32.65%, respectively, in which (1R)-α-pinene (3.98%), sabinene (2.51%),(1S)-β-pinene (5.78%), m-cymene (4.05%), limonene (3.55%), 3, 7-dimethyl-1, 3, 7-octatriene (3.98%),γ-terpinene (8.70%), anisole (1.78%) and (1S)-endo-bornyl acetate (2.62%) as the monoterpenes and its derivatives, and-β-elemene (1.17%),α-bulnesene (1.40%),-β-bisabolene (1.21%),-elemol (1.42%), guaiol (1.14%), dehydroxyisocalamendiol (1.13%),-aristolene (1.99%), bulnesol (9.48%),γ-eudesmol (1.77%), guai-1(10)-en-11-ol (1.12%) and α-bisabolol (5.35 %) as the sesquiterpenes and its derivatives are the main components.

1R-α-蒎烯(3·98 %)、桧烯(2·51 %)、(1S)-β-蒎烯(5·78 %)、m-月桂烯(4·05 %)、柠檬烯(3·55 %)、3,7-二甲基-1,3,7-庚三烯(3·98 %)、γ-萜品烯(8·70 %)、茴香醚(1·78 %)和(1S)-桥环醋酸冰片酯(2·62 %)为单萜类化合物及其衍生物中的主要成分;-β-榄香烯(1·17 %)、异愈创木烯(1·40 %)、-β-没药烯(1·21 %)、-榄香醇(1·42 %)、愈创木醇(1·14 %)、去羟基异菖蒲二醇(1·13 %)、-土青木香烯(1·99 %)、异愈创木醇(9·48 %)、γ-桉醇(1·77 %)、愈创木-1(10)-烯-11-醇(1·12 %)和α-没药醇(5·35 %)为倍半萜类化合物及其衍生物中的主要成分。

Novel triterpene(12-oleanene-3β, 6α-diol) from C.hypoleucus can induce apoptosis and has inhibition effect on the proliferation in RKO cell line.

粉背南蛇藤中新的三萜齐墩果-12-烯/-3β,6α-二醇能抑制人结肠癌细胞系RKO细胞增殖和诱导凋亡。

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