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三苯氧胺

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Three alicyclic dianhydrides, 1,2,3,4-cyclobutanetetracarboxylic dianhydride, 1,2,4,5-cyclopentanetetracarboxylic dianhydride, and 1,2, 4, 5-cydohexane tetracarboxylic dianhydride were polymerized with two aromatic diamines, 1,4-bis (4-amino-2-trifluoromethylphenoxy) benzene (6FAPB, a) and 4, 4'-bis(4-amino-2-trifluoromethyl phenoxy) biphenyl (6FBAB, b) respectively, via a two-step polycondensation procedure to afford two series of fluorinated semi-alicyclic polyimides.

分别将脂环族二酐单体1,2,3,4-环丁烷四酸二酐、1,2,4,5-环戊烷四酸二酐和1,2,4,5-环己烷四酸二酐与芳香族含氟二胺1,4-双(4-胺基-2-三氟甲基苯氧基)苯(6FAPB, a)和4,4'-双(4-胺基-2-三氟甲基苯氧基)联苯(6FBAB, b)反应制备两个系列的含氟半脂环族聚酰亚胺,研究了PI薄膜的热性能和光学性能。

2A series of alternating polyamide-imideswith fluorenyl cardo structure was synthesized by "one-pot" polycondensation of cardo diamines,trimellitic anhydride and various aromatic diamines including p-phenylene diamine,m-phenylene diamine, 4,4\'-oxydianiline,3,4\'-oxydianiline,2,2-bis[4-(4-aminophenoxy)phenyl]propane, 2,2-bis[4-(3-aminophenoxy)phenyl]propane respectively using triphenyl phosphite as condensing agents.

采用"一锅法"(One—pot Synthesis),由Cardo二胺、偏苯三酸酐和不同二胺包括对苯二胺、间苯二胺、4,4\'—二氨基二苯醚、3,4\'—二氨基二苯醚、2,2—双[4—(4—氨基苯氧基苯基]丙烷和2,2—双[4—(3—氨基苯氧基)苯基]丙烷合成了一系列含有芴基Cardo结构的交替聚酰胺酰亚胺。

PVC resin, PTFE resin, fumaric acid, anthraquinone, nitroanthraquinone, paraaminophenol, melamine, cyanuric acid, sulfanilic acid, chemical inhibitor 168, azoic coupling component As, stearate, aniline, nitroaniline, pentaerythritol, chlorcosane, sodium calcium, triethylene diamine, sodium benzene sulphinate, m-phthalic acid, thiourea, aniline black dyestuffs, acid dyestuff, etc.

聚氯乙烯树脂、聚四氟乙烯树脂、反丁烯二酸、蒽醌、硝基蒽醌、对氨基苯酚、三聚氰胺、氰尿酸、对氨基苯磺酸、抗氧剂168、色酚As、硬脂酸盐、苯胺、硝基苯胺、双季戊四醇、氯???腊、甲酸钙、三乙烯二胺、苯亚磺酸钠、间苯二甲酸、二甲酯五磺酸钠、硫脲、油溶性苯胺黑染料、酸性黑染料等有机化工原料和中间体。

Water,c12-20 acid peg-8 ester,caprylic/capric triglyceride,proplylene glycol,ppg-15 stearyl ether,chondrus crispus,iris germanica(orris extract/cells),centaurea cyanus,macadamia ternifolia,buxus chinensis,triethanolamine,potassium cetyl phosphate,butyrospermum parkii,c12-13 alkyl lactate,carbomer,phenoxyethanol,methylparaben,imidazolidinyl urea,glyceryl hydroxystearin,tocopheryl acetate.retinyl palmitate,sodium hyaluronate,biosaccharide gum-1,propylparaben,disodium edta,ethylparaben,pentadecalactone,hydroxystearic acid,tetradecyloctadecanoic acid,tetradecyleicosanoic acid,hexadecyleicosanoic acid,butylparaben,isobutylparaben,chlorhexidine digluconate,tocopherol,lecithin,ascorbyl palmitate,glyceryl stearate,glyceryl oleate,BHT,citric acid.

水,C12-20 酸 PEG-8酯,辛酸/癸酸三酸甘油酯,丙二醇,PPG-15 硬脂基醚,卡拉胶萃取,德国鸢尾花提取物/细胞,矢车菊提取物,澳洲坚果油,荷荷巴油,三乙醇胺,十六烷基磷酸钾,牛油果,c12-13烷醇乳酸酯,卡波姆,苯氧乙醇,羟苯甲酯,尿素醛,甘油羟基硬脂酸酯,醋酸盐维他命E,维他命A酯,透明质酸钠,多醣物质,羟苯丙酯,乙酸乙二胺二钠,羟苯乙酯,环十五内酯,羟基硬脂酸,十四烷基十八烷酸,十四烷基二十烷酸,十六烷基二十烷酸,羟苯丁酯,对羟基苯甲酸异丁酯,洗必泰葡萄糖酸盐,维生素E,卵磷脂,抗坏血酸棕榈酸酯,甘油硬脂酸,甘油油酸酯,BHT,柠檬酸。水:几乎所有护肤品成分第一位都是水。辛酸/癸酸三酸甘油酯:润滑剂、扩散剂,棕榈油/椰子油衍生物

Water,Hydrogenated Polyisobutene,Cyclohexasiloxane,Glycerin,Alcohol Denat,Cetearyl Alcohol,PEG-20,Petrolatum,C13-14 Isoparaffin,Zea Mays Oil,Tocopheryl Acetate,Hydroxypropyl Tetrahydropyrantriol,Hydrolyzed Soy Protein,CI 14700/Red 4,Phenoxyethanol,Adenosine,PEG-100 Stearate,Ethylparaben,Triethanolamine,Polyacrylamide,Malus Domestica Stem Cell Culture,CI 19140/Yellow 5,Dimethyl Isosorbide,Dimethicone,Dimethiconol,Limonene,Xanthan Gum,Pentaerythrityl Tetra-Di-T-Butyl Hydroxyhydrocinnamate,Linalool,2-Oleamido-1,3-Octadecanediol,Capryloyl Salicylic Acid,Acrylates/C10-30 Alkyl Acrylate Crosspolymer,Passiflora Edulis Seed Oil,Disodium EDTA,Castanea Sativa Seed Extract,Butyrospermum Parkii· Cetyl Alcohol,Butylene Glycol,Octyldodecanol,Cetearyl Glucoside,Methylparaben,Citronellol,Prunus Armeniaca Kernel Oil,Laureth-7,Coumarin,Oryza Sativa Bran Oil,Glyceryl Stearate,Fragrance

水,甘油,氢化聚异丁烯,液体石蜡/矿油,丁二醇,环己硅氧烷,鲸蜡醇,甘油硬脂酸酯,棕榈油,玉米胚芽油,PEG-100硬脂酸酯,白蜂蜡/蜂蜡,肉豆蔻醇肉豆蔻酸酯,石蜡,香精,腺苷,苧烯,山梨醇,CI 14700,CI 19140,稻糠油,杏仁油,EDTA二钠,羟丙基四氢吡喃三醇,苯氧乙醇,聚乙二醇-14M,异十六烷,氢氧化钠,辛基十二醇,季戊四醇四(双-t-丁基羟基氢化肉桂酸)酯,山梨坦三硬脂酸酯,水解大豆蛋白,卡波姆,鸡蛋果籽油,苹果果实提取物,欧洲栗籽提取物,异山梨醇酐二甲醚,聚山梨醇酯-80,辛酰水杨酸,2-油酰胺基-1,3-十八烷二醇,氯苯甘醚,麦芽糖醇,香豆素,黄原胶,微晶蜡,丙烯酰胺/丙烯酰基二甲基牛磺酸钠共聚物,丙二醇,芳樟醇,香茅醇,玉米油,羟苯丙酯,羟苯甲酯

Benzyloxy benzoyldimethylsulfoxide was prepared by the reaction of ethyl 4-benzyloxybenzoate and dimethyl sulfoxide in the presence of sodium hydride, followed by Pummerer reaction with concentrated hydrochloric acid to afford eo-hydroxy-co-thio-methyl-(4/-benzyloxy) acetophenone, which reacted with urea, thiosemicarbazide, semicarbazide hydrochloride and o-phenylenediamine to give imidazolidine-2,4-dione, l,2,4-triazine-3- one and quinoxaline derivatives, respectively.

本文用4-苄氧基苯甲酸乙酯和二甲亚砜为原料,在氢化钠存在下反应,合成了(4′-苄氧基)-苯甲酰基-二甲亚砜。研究了该亚砜在浓盐酸的存在下发生的Pummerer重排反应,用重排产物ω-羟基-ω-甲硫基-(4′-苄氧基)-苯乙酮分别与尿素、氨基脲、氨基硫脲和邻苯二胺反应合成了2,4-咪唑啉-二酮、1,2,4-三嗪-3-酮、喹喔啉等含氮杂环化合物。

2A series of alternating polyamide-imideswith fluorenyl cardo structure was synthesized by "one-pot" polycondensation of cardo diamines,trimellitic anhydride and various aromatic diamines including p-phenylene diamine,m-phenylene diamine, 4,4\'-oxydianiline,3,4\'-oxydianiline,2,2-bis[4-(4-aminophenoxy)phenyl]propane, 2,2-bis[4-(3-aminophenoxy)phenyl]propane respectively using triphenyl phosphite as condensing agents.

采用&一锅法&(One—pot Synthesis),由Cardo二胺、偏苯三酸酐和不同二胺包括对苯二胺、间苯二胺、4,4\'—二氨基二苯醚、3,4\'—二氨基二苯醚、2,2—双[4—(4—氨基苯氧基苯基]丙烷和2,2—双[4—(3—氨基苯氧基)苯基]丙烷合成了一系列含有芴基Cardo结构的交替聚酰胺酰亚胺。

2A series of alternating polyamide-imideswith fluorenyl cardo structure was synthesized by "one-pot" polycondensation of cardo diamines,trimellitic anhydride and various aromatic diamines including p-phenylene diamine,m-phenylene diamine, 4,4\'-oxydianiline,3,4\'-oxydianiline,2,2-bis[4-(4-aminophenoxy)phenyl]propane, 2,2-bis[4-(3-aminophenoxy)phenyl]propane respectively using triphenyl phosphite as condensing agents.

采用&一锅法&O(来源:88AB57C论文网www.abclunwen.comne—pot Synthesis,由Cardo二胺、偏苯三酸酐和不同二胺包括对苯二胺、间苯二胺、4,4\'—二氨基二苯醚、3,4\'—二氨基二苯醚、2,2—双[4—(4—氨基苯氧基苯基]丙烷和2,2—双[4—(3—氨基苯氧基)苯基]丙烷合成了一系列含有芴基Cardo结构的交替聚酰胺酰亚胺。

Is a research and development, production, trade and service-based economy of foreign trade entities, chemical raw materials to the professional operation of the main company's existing production of AC blowing agent, ferric chloride, hydrated Hydrazine, p-nitrophenol, m-phenylenediamine, phosphorus trichloride, phosphorus oxychloride, 2,4 - diamino benzene sulfonate, sodium dichloro isocyanurate, N-methyl-o-phenylenediamine Second hydrochloride fine chemical products such as the ability, and are obtained ISO9001 international quality system certification.

济南华尔沃进出口贸易有限公司是一家集研发、生产、贸易、服务于一体的外贸型经济实体,以专业经营化工原料为主,公司现有生产AC发泡剂、三氯化铁、水合肼、对硝基苯酚、间苯二胺、三氯化磷、三氯氧磷、2,4—二氨基苯磺酸钠、二氯异氰脲酸钠、N-甲基邻苯二胺二盐酸盐等精细化工产品的能力,并且均以取得ISO9001国际质量体系认证。

Phenylenediamines, aminophenols, methoxyanil ines, and 1,4- hydroquinone, 1-naphthylamine were polymerized via the catalysis of horseradish peroxidase in mixed solvents of l,4-dioxane and water at amibient conditions by using hydrogen peroxide as the oxidant. Several factors influencing the polymer yield, such as the concentration of the substrate, pH value and oxidant amount were examined using a- phenylenediamine as substrate.

本文选择了苯二胺、氨基苯酚、甲氧基苯胺三个系列,以及对苯二酚、1-萘胺等单体,在二氧六环-水混合介质中以辣根过氧化物酶为催化剂,以双氧水为氧化剂进行了不同底物的室温酶促聚合,并以邻苯二胺为底物考察了溶剂用量、pH值、作为氧化剂的双氧水用量等条件对聚合物收率的影响。

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