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The preparation method comprises monomer synthesis and polymer synthesis. The polymer synthesis is that cyclopentadienyl sodium monomer is added into metallic cobalt complex-triphenyl phosphorus cobalt chloride under strict oxygen-free and water-free conditions, and then double inner alkyne or outer alkyne conjugate monomer is added in, and after reaction, the precipitation, filtering, abstersion and vacuum-drying are carried out, the large molecules polymer containing cyclopentadienyl cobaltocenium organometallic cobalt is obtained.

制备方法,包括单体合成和聚合物的合成,聚合物的合成是在严格无氧无水条件下,在金属钴配合物三-三苯基磷氯化钴,加入环戊二烯钠单体,随后加入双内炔或双外炔共轭单体,反应后沉淀,过滤,洗涤,真空干燥,得到含环戊二烯茂钴有机金属钴的大分子聚合物。

In this dissertation, synthesis of benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene]dichlororuthenium (41) has been improved.

本论文首先改进了钌卡宾配合物[1,3-二-(2,6-甲苯基)-4,5-二氢咪唑基]-苯亚甲基-三苯基膦-二氯合钌(41)的合成方法。

A new conjugation molecule L2, based on 2,4,5-triphenylimidazole and 6-phenyl-2,2\'-bipyridine, was synthesized in two steps.

基于2,4,5-三苯基咪唑和6-苯基-2,2\'-二联吡啶,合成了一个新型的共轭分子L2。

College of Chemistry and Molecular Sciences,Wuhan University,Wuhan 430072A novel diselenide porphyrins dimmers was synthesized using 5(4- hydroxylphenyl)-10,15,20- triphenyl porphyrin and selenium as raw materials. The structure of the novel porphyrin was confirmed by 1H NMR, IR, UV, and MS.

以5-(4-羟基苯基)-10,15,20-三苯基卟啉和硒粉为原料,合成了新型二硒双卟啉,用紫外可见光谱,红外光谱,核磁共振氢谱(1H NMR),高分辩质谱对目标产物的结构进行了确认。

Absorption spectra indicate that there is little or no interaction between chromphores in the ground state. However, the fluorescence emission of oxadiazole and triphenylamine moieties are almost quenched, which shows that in the excited ground state there exists very effective intramolecular singlet-singlet energy transfer .

研究发现,这些多发色团化合物在基态发色团之间没有作用或作用很小,而其中噁二唑和三苯基胺单元的荧光被严重的猝灭,这说明在激发态下,萘酰亚胺发色团与噁二唑、三苯胺功能团之间发生了分子内单线态—单线态能量转移。

Absorption spectra indicate that there is little or no interaction between chromphores in the ground state. However, the fluorescence emission of oxadiazole and triphenylamine moieties are almost quenched, which shows that in the excited ground state there exists very effective intermolecular singlet-singlet energy transfer.

研究发现,这些多发色团化合物在基态发色团之间没有作用或作用很小,而其中恶二唑和三苯基胺单元的荧光被严重的猝灭,这说明在激发态下,萘酰亚胺发色团与恶二唑、三苯胺功能团之间发生了分子内单线态-单线态能量转移。

In the presence of palladium catalyst and triphenylphosphine, alkynyl Grignards or alkynyllithiums could successfully couple with alkyl bromides and iodides. Aryl-substituted propargylic dithioacetals could also be obtained by this strategy.

在钯触媒和三苯基磷的存在下,我们可利用炔基格林那试剂或炔基锂和简单的卤烷进行偶合,而这样的反应条件也能应用在苯基取代炔丙基硫缩酮衍生物的合成上。

Pentanediol reacted with phosphorus tribromide to make it mono-bromination, under the catalytic action of PPTs it reacted with 2,3-dihydropyran to protect another hydroxy group, then to react with triphosphine, produced quarterphossal.

再以1,5-戊二醇为原料,三溴化磷使之单溴代,得到5-溴-1-戊醇,在对甲苯磺酸吡啶盐的催化下与2,3-二氢吡喃反应保护其另一端的羟基,与三苯基膦反应生成季磷盐。

In this study, the critical point data of ternary systems which is composed of supercritical carbon dioxide, trisodium salt of tri-(m-sulfonphenyl)phosphine and cosolvent were measured the first time. With the increase of mol% of the cosolvent, critical temperature of ternary system increased, and the experimental data show a linear dependence of critical temperature with mol% of the ternary system over the concentration ranges studied too.

北京化工大学硕士研究生论文本文还首次测试了在超临界CO:中加入三磺化三苯基麟以及共溶剂组成的三元体系的临界点数据,发现三元体系中临界温度也随共溶剂的浓度增加逐渐增加,呈一种线性关系。

Have carried on testing service for nearly 200 hazardous substances, including Asbestos, PAHs, Phthalates, NP/NPEO, AZO, CFC/HCFC/Halons, PVC, PCB, PCT, PCN, CP, Mirex, TPT/TBT/TBTO, Formaldehyde, Heavy metals, can help your products in fully compliance with 'green purchase' request of international buyers.

开展除RoHS以外的近200种有害物质检测业务,包括石棉、多环芳烃、邻苯二甲酸盐、壬基苯酚/壬基苯酚乙氧基化合物、偶氮染料、氟氯烷烃/氢氯氟烷烃/海龙、聚氯乙烯、多氯联苯、多氯三联苯、多氯化萘、短链氯化石蜡、灭蚊灵、三苯基锡类/三丁基锡类/二的氧化物、甲醛、重金属等,涉及范围完全满足各国际买家的&绿色采购&要求。

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What would he tell Judith and the children?

他将怎样告诉朱迪丝和孩子们呢?

I this is at that time, the opinion with peacockish true girl is full of in a heart.

这就是当时的我,一个心中布满虚荣的女孩子真实的想法。

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