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The synergistic extraction of uranyl nitrate with binary system of 1-phenyl-3-methyl-4-benzoyl-pyrazolone-5 and tributyl phosphate or diphenyl sulfoxide, and ternary system of PMBP-DPSO-TBP were studied.

本文研究了1-苯基3-甲基4-苯甲酰吡唑酮-5与磷酸三丁酯或二苯亚砜的苯溶液从硝酸介质中对U的萃取,实验发现有显著的二元协萃效应,并测定了二元协萃络合物的组成为 UO_2A_2·TBP或 UO_2A_2·DPSO,求得二元协萃平衡常数为1gβ_(12)=3.58,1gβ_(13)=3.61。

The experiments showed that polypeptides were formed by self-assembly of N, O- bis amino acids with the assistance of o-phenylene phosphoro- chloridate. Three steps were involved in the self organization reactions, i.

侧链无官能团的N,O-二-α-氨基酸在O,O-亚苯基磷酰氯辅助下能自组装得到系列2~n聚寡肽,其自组装成肽过程大致分为三步:氨基酸的活化、肽链的延长和链反应终止。

Utilizing 6 and several kinds of diazides prepared in our lab, polys containing 1,2,3-triazolyl and perfluorocyclobutane units were synthesized by "Click chemistry". Utilizing the polycondensation reaction between 6 and several commercially available aromatic diphenol or copolymerization reaction after adding another active aromatic dichloride, fluorinated polys containing phenylphosphine oxide units were synthesized. Utilizing the polycondensation reaction between 6 and several commercially available aromatic dianhydride, fluorinated polys containing PPO units were synthesized.Secondly, structure characterization of fluorinated polys.

利用化合物6同各种自制的二叠氮化合物,通过&Click chemistry&,合成了具有1,2,3-三唑环结构单元的全氟环丁基类聚芳醚;利用化合物22同各种商业化的芳香二元酚类化合物进行缩聚反应或者再加入另外一种活性芳香二氯代物进行三元共聚反应,制备了具有苯基氧膦结构单元的含氟聚芳醚;通过化合物25同各种商业化的芳香二元酸酐类化合物进行缩聚反应,得到了具有PPO结构单元的含氟聚醚酰亚胺。

A new functional electroluminescent copolymer is reported in which chromophores and hexa segments alternate along the polymer backbone.

采用Wittig反应合成了一种分子主链由烷氧基取代的1,4二苯乙烯基苯聚对亚苯基亚乙烯基(PPV的三个单元的齐聚物与柔性隔离链段五缩六乙二醇组成的交替型蓝绿色发光共聚物。

Pymetrazine is chosed as the lead compound, and 21 compounds were firstly designed and synthesized. These compounds were characterized by introducing phenyl derivatives with different functional groups to replace pyridine ring with the isosteric principle and the method of homogeneous synthesis and reasonable biologically designing in order to find new compounds with potential biological activity. These compounds were confirmed by IR, H NMR and MS spectra.

本文选取吡蚜酮为先导化合物,运用电子等排理念,综合类同合成、生物合理设计的方法,引入含有不同官能团的苯基衍生物替代吡蚜酮的结构中心吡啶环,设计合成了21个未见文献报道的化合物,寻找具有潜在生物活性的新三嗪酮类化合物,通过核磁共振氢谱、红外光谱、质谱等手段进行了结构表征,并验证正确。

There was not few report about 5-amino-3-cyan-N-(2,6-dichloro-4-trifluoromethylphenyl)pyrazole in the domestic , so that the whole synthetic course of 5-amino-3-cyan-N-(2,6-dichloro-4-trifluoromethylphenyl)pyrazole was studied and the intermediate with feasible eco...

因此,研究5-氨基-3-氰基-N-(2,6-氯-4-三氟甲基苯基)吡唑的合成,探索其中间体经济可行的合成路线,具有很好的社会效益和经济前景。

In our work, as a preliminary experiment, the N-phenacylisoquinolinium bromide was reacted with methlhydrazine in refluxed acetic acid. Unexpectedly, 2-methyl-1,2,3-triazole was obtained. The further study of this reaction led to a more simple starting material,α-bromoacetophenone to react with methylhydrazine, obtaining the same product.

我们在研究N-苯乙酰异喹啉溴化物与甲肼在冰醋酸中的反应时,意外地得到了2-甲基-4-苯基-1,2,3-三氮唑,经过进一步的研究发现α-溴代苯乙酮与甲肼也能得到同样的产物。

In this paper, the improvement of synthetic method of 2-acetylaminotropone is introduced. 3-Acetyltropolone reacted with low concen-tration methylamine solution and solvent was directly evaporated in reduce pres-sure to give 2-acetyl-7 -methylaminotropone in good yield. The compound reacted with phenyltrimethylammonium tribromide to give two new compounds.

本文介绍2-乙酰基-7-甲胺基酮合成方法的改进——用挥发性小的低浓度甲胺溶液与3-乙酰基酚酮反应;和采用直接减压蒸除溶剂法分离产品,得到较好产率的2-乙酰基-7-甲胺基酮;用化合物与三溴化苯基三甲铵反应,得到两种至今未见文献报道的新化合物。

Under catalysis of AlCl3, trans-1-chloro-3-phenyl-1-propen-3-one was first prepared using benzoyl chloride and acetylene in CH2Cl2 at 20~25℃, which the yield is 7% higher than that in CCl4 at 40~45℃.

通过对其反应条件的研究,首次用苯甲酰氯和乙炔在三氯化铝作用下合成出反-3-苯基-1-氯-1-丙烯-3-酮;并发现用二氯甲烷作介质在20~25℃下的反应产率,比用四氯化碳作介质在40~45℃下的反应产率约高7%。

In addition to cationic gold complexes bearing bulky biphenyl phosphines, a gold complex with tris(2,6-di-tert-butylphenyl)phosphite is exceptionally reactive as a catalyst for this reaction.

在与有大体积连苯基膦配体的金正配合离子加成反应中,三(2,6-二叔丁基苯)亚磷酸盐的金配合物异常活泼并充当该反应的催化剂

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