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In addition, the stability of ternary Cu 〓complexes polypyridyl=1, 10-phenanthroline (Phen , pyrido [3, 2-f] [1, 7] phenanthroline , 1, 4, 8, 9-tetraazatriphenylene , dipyrido [3, 2-a: 2'3'-c] phenazine , imidazo phenanthroline and 2-phenylimidazo phenanthroline , NTP=ATP and UTP was studied by potentiometric pH titration in water at temperature 15℃, 25℃ and 35℃, and in 30% and 50% aqueous dioxane solution at 25℃.

另外,用pH电位滴定法研究了多吡啶芳香配体polypyridyl配合物Cu〓(PL=1,10-邻菲咯啉、吡啶并[3,2-f][1,7]邻菲咯啉、1,4,8,9-四氮三联苯、二吡啶并[3,2-a∶2'3'-c]吩嗪和2-苯基咪唑并邻菲咯啉或咪唑并邻菲咯啉)在不同温度(15℃、25℃和35℃)水溶液及30%和50%二氧六环-水混和溶剂(25℃)中的稳定性。

The results show that there is intensive synergistic effect among cetyltrimethylammonium bromide, benzalacetone and polyethylene glycol. A bright and compact nanocrystalline zinc was produced due to the coexistence of such three additives.

结果表明,十六烷基三甲基溴化铵、4-苯基-3-丁烯-2-酮和聚乙二醇三种添加剂之间具有较强的协同作用,采用三者组成的混合添加剂可制备出光亮致密的纳米晶锌镀层。

Three potential initiation processes were identified during the cumyl phenyl dithioacetate mediated acrylate polymerizations.

三个可能的启动过程期间,没有发现基苯基dithioacetate介丙烯酸聚合。

The novel title compound was synthesized with benzaldehyde, isobutyraldehyde, phosphorus trichloride as raw materials. The total yield was 40.8%. The structure was confirmed by 1H NMR, 31P NMR and elemental analysis.

摘要以苯甲醛、异丁醛、三氯化磷为原料合成了新型的1,3,2-氧磷杂环类化合物2-苯羟甲基-5,5-二甲基-4-苯基-2-氧代-1,3,2-二氧磷杂环己烷,总收率为40.8%,并对其进行了NMR研究和结构表征。

In order to check the corresponding compound at 31P NMR –45.4 ppm, stable pentacoordinate spirobicyclic 2-phenoxy-1,3-phenylene-dioxo-1,3,2-iminoacetoxyphosphoranes were synthesized through a new and efficient method whereby phosphorus pentachloride was displaced stepwise by catechol, N,O-bisamino acid and phenol, or catechol, phenol and N,O-bisamino acid, their 31P NMR chemical shifts are at about 31P NMR –45.0 ppm, the results showed that the compound 4 at 31P NMR –45.4 ppm was pentacoordinate phosphorane containing amino acid residue.

采用磷谱跟踪来研究上述成肽反应机理。例如在氮气保护下,0.1mmol O,O-亚苯基磷酰氯(1)和0.15mmol N,O-二苯丙氨酸(2)苯溶液加入0.6ml核磁管中,混合均匀,反应过程用磷谱检测。反应1分钟后,起始原料1(δp=19ppm)很快转变成N-磷酰苯丙氨酸的三甲基硅基酯(3)(δp=19.8ppm),在8分钟内,3完全转变成苯丙氨酸磷烷4(δp =-45.4ppm),同时出现环磷三酯(6)(δp=3.5ppm)。随着反应的进行,对应于化合物4的峰逐渐变小,而6逐渐变大。

Mainly engaged in sodium azide, barium azide, three phosphorus nitride Friday, phenyl isothiocyanate, 1 - phenyl -5 - mercapto-tetrazole, 4 - dimethylamino-pyridine, 2 - mercapto--5 -- methyl-1,3,4 thiadiazole, N-hydroxy phthalimide, anhydrous betaine and betaine hydrochloride, such as fine chemical raw materials and medicine, pesticide intermediates of the development, production and sales.

主要从事叠氮化钠,叠氮化钡,五氮化三磷,异硫氰酸苯酯,1-苯基-5-巯基四氮唑,4-二甲氨基吡啶,2-巯基-5-甲基-1,3,4噻二唑,N-羟基邻苯二甲酰亚胺,无水甜菜碱及甜菜碱盐酸盐等精细化工原料及医药、农药中间体的开发、生产和销售。

A triarylamine-based picolinic acid was synthesized through the Ullmann reaction and Negishi coupling reaction. Using this class of picolinic acid derivative as an auxiliary ligand and 1-phenylisoquinoline as a cyclometalated ligand, a cyclometalated iridium complex was also prepared.

通过Ullmann反应和Negishi偶联反应,合成了一种含三芳胺功能基的吡啶-2-甲酸衍生物;并以此为辅助配体、1-苯基异喹啉为环金属配体,设计合成了一种新型环金属铱配合物。

A triarylamine-based picolinic acid was synthesized through the Ullmann reaction and Negishi coupling reaction. Using this class of picolinic acid derivative as an auxiliary ligand and 1-phenylisoquino-line as a cyclometalated ligand, a cyclometalated iridium complex was also prepared.

通过Ullmann反应和Negishi偶联反应,合成了一种含三芳胺功能基的吡啶-2-甲酸衍生物;并以此为辅助配体、1-苯基异喹啉为环金属配体,设计合成了一种新型环金属铱配合物。

A novel fluorescent acrylamide monomer, N-(4-Benzooxazol-2-yl-phenyl)- acrylamide, was prepared from o-aminophenol, p-aminobenzoic acid and acryloyl chloride, with polyphosphoric acid as dehydrating agent and triethylamine as deacidification agent.

以邻氨基苯酚、对氨基苯甲酸和丙烯酰氯为原料,以多聚磷酸为脱水剂、三乙胺为脱酸剂,研制了一种新的荧光丙烯酰胺单体N-[4-(苯并噁唑-2-)苯基]丙烯酰胺。

In the third step, when the ratio of racemic ester to benzenesulfonyl chloride to triethylamine to catalyst 4-DMAP is 1:1:1:0.1 in 10℃, the yield is 82.9% and high purity is obtained by crystallisation.

在第三步磺酰化反应中,得到合成消旋2-苯磺酸基-2(2-氯苯基)乙酸甲酯的较佳反应条件为邻氯扁桃酸甲酯:苯磺酰氯:三乙胺=1:1:1,催化剂4-DMAP用量为摩尔反应物的10%,反应温度为10℃,收率为82.9%,同时用结晶方法获得高纯度的产物。

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What would he tell Judith and the children?

他将怎样告诉朱迪丝和孩子们呢?

I this is at that time, the opinion with peacockish true girl is full of in a heart.

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