三脚架

PSO is a population-based optimization algorithm, which mimics the social behavior of animals in a flock. It makes use of individual and group memory to update each particle position allowing global and local search optimization. The objective function considered was the total weight of the structure subjected to stresses, displacements and forces constraints. The effects of the parameters were investigated as well and such combination of tuning parameters promote a better global search behavior avoiding premature convergence while rapidly converging to the optimal solution. Results showed the effectiveness of the proposed method by comparing with ANSYS Design Optimization Tool (zero-order method). The PSO with the tuning parameters makes it an ideal method for offshore wind turbines foundations optimization tasks.(2) A reliability analysis method for pile foundation bearing axial loads based PSOThe performance function of pile foundation's axially bearing capacity sometimes is nonlinear and complex, on the basis of geometric meaning of structural reliability index, an optimum model with PSO for structural reliability analysis under arbitrary random variables was established, The PSO algorithm is very efficient to solve global optimization problemsIts use in structural reliability field presents not only the advantage of its facility of implementation, but also the possibility to obtain the design point and the failure probability with a good accuracy. In addition, PSO is a zero order algorithm, for no derivative is necessary for its implementation.

本文的研究针对桩式海上风机基础结构的特点，在国内外有关研究成果的基础上对海上风机基础结构优化设计理论和可靠度方法一些相关问题进行了较为深入的研究，具体做了以下几个方面的工作：(1)基于粒子群优化的桩式海上风机基础确定性优化设计方法桩式海上风机基础的优化设计是一个复杂的、非线性约束的优化问题，针对传统的基于梯度信息的优化方法在处理非线性问题中易陷入局部最优解的问题，本文将一种耦合惩罚函数的PSO算法引入到海上风机基础结构概念设计中，PSO算法是从群体动物聚集觅食这一活动中受到启发而发展的，该算法利用个体和群体的信息共享不断改进自身的位置从而进行局部和全局最优搜索，本文中以桩和三脚架连接段直径及壁厚为设计变量，以基础总重量作为优化的目标函数，在给定的约束条件下建立了三脚架基础优化数学模型，另外本文还研究了PSO参数变化对结果的影响，协调的参数组合可以避免陷入早熟收敛而能够快速的获得全局的最优解，通过与ANSYS优化模块的计算结果比较验证了该方法的有效性，本方法为海上风机基础的确定性设计提供了一条有效的途径。

The only other bit of kit I use is a Gorrilapod, which is a little bendy tripod you can clip to a chair for photographing interiors where there isn't enough light.

我这些小玩意儿中的另一个而且不可或缺的成员，是一个猩猩三脚架。猩猩三脚架，是一个小小的、弯曲的、有弧度的三脚架。你甚至可以把它别在椅子上。当拍摄建筑物的内部而光线不够的话，它就可以发挥作用了。

To improve the yield of an Amide-type Tripodal Ligand and investigate its coordination with rare earth ion under mild condition,a series of Amide-type Tripodal Ligands(L1—L4) have been prepared by the reactions of nitrilotriacetic acid and oxalyl chloride with four kinds of amides,respectively.

为了提高酰胺型三脚架型配体的产率，进一步研究其与稀土离子的配位形式及配合物的荧光性能，以氨三乙酸为母体，草酰氯为氯化试剂，与4种胺在较温和的条件下合成了具有三脚架型结构的配体(L1—L4)，并考察了实验条件、反应温度、反应体系溶剂、缚酸剂、反应时间及催化剂对反应产率的影响。

Kinetic spectrophotometric method for the determinationof trace nitrilotriacetic acid;2. To improve the yield of an Amide-type Tripodal Ligand and investigate its coordination with rare earth ion under mild condition,a series of Amide-type Tripodal Ligands(L1—L4) have been prepared by the reactions of nitrilotriacetic acid and oxalyl chloride with four kinds of amides,respectively.

为了提高酰胺型三脚架型配体的产率，进一步研究其与稀土离子的配位形式及配合物的荧光性能，以氨三乙酸为母体，草酰氯为氯化试剂，与4种胺在较温和的条件下合成了具有三脚架型结构的配体(L1—L4)，并考察了实验条件、反应温度、反应体系溶剂、缚酸剂、反应时间及催化剂对反应产率的影响。

The X-ray crystal structure analysis of the complexes shows that all lanthanidecomplexes exhibit a tripodal ligand coordination mode, with three imino nitrogenfrom benzimidazolyl and pyridyl group, and one amino nitrogen atoms as donors.The ligands show two kinds of configuration: the fan-like and the pincer-like. Bothintra- and intermolecular π-π interactions are found in these complexes.

晶体结果表明，在所有的稀土配合物中，三脚架配体均用三个支脚上的苯并咪唑、吡啶环氮原子及一个顶端的氮原子和稀土离子进行配位，表现出三脚架式配位方式，同时，三脚架配体有风扇形及钳子形两种空间配位构型，并形成了分子内及分子间的π-π堆积作用。

In this thesis, on the one hand, two new tripodal ligands and twenty-three of their lanthanide complexes were synthesized, and their fluorescence properties were investigated, on the other hand, nine new copper and silver complexes with six kinds of tripodal ligands were synthesized and their crystal and molecular structures were determined by X-ray diffraction analysis.

本论文一方面合成了两个新三脚架配体的23个稀土配合物，并对它们的发光性能进行了探讨；另一方面得到了涉及六种三脚架配体的9个铜、银配合物，并测定了它们的晶体结构。

All of the tripodal schiff base ligands and their complexes were characterized.

以三乙醇胺、巯基苯胺、巯基乙胺为初始原料，设计合成了六个三脚架结构的化合物，其合成路线如下：三乙醇胺与氯化亚砜反应得到三(2-氯乙基)胺(1)，然后与巯基苯胺或巯基乙胺在碱性条件下反应生成三脚架结构的三{[2-(2-氨基苯基)硫代]乙基}胺(2)或三{[2-(2-氨基乙基)硫代]乙基}胺(3)，然后再与水杨醛、2-甲酰基-8-羟基喹啉(8)、2-甲酰基-8-苄氧基喹啉(7)反应得到六种新型的含硫西佛碱化合

In order to investigate the relation between the ligands and rare earth ions, in this dissertation, two new polyaza cryptands, two new tripyrazolone ligands, a macrobicyclic rare earth cryptates, a tripyrazolone and a tripodal ligands rare earth complexes have been synthesized.

为了进一步研究和探讨穴醚、吡唑啉酮、三脚架化合物配体对稀土元素的配位作用，论文首次报道了两个新氮杂穴醚配体、两个新三脚架吡唑啉酮结构配体、一个系列大二环新型的稀土配合物、一个系列三脚架吡唑啉酮结构配合物、一个系列三脚架结构三酸配合物的合成。

The carboxyl of the tripodal ligand is a goodbridging group. The building blocks are linked together by the bridging group andother weak interactions (hydrogen bond and π-π stacking interaction, etc), thusgenerating a one, two or three-dimensional metal complexes.2. Studies on the fluorescence properties of the lanthanide complexes indicated that:(1) The excitations in the ligand-based π-π〓 transitions cause the structuredemission of lanthanide complexes while the ligand luminescence is completelyquenched showing that ligand-to-metal energy transfer occurs.

三脚架配体所带的羧基是一个很好的桥联基团，配合物的结构基元通过这种基团的桥联作用及其它一些弱的作用力(如氢键、π-π堆积作用等)联系起来，构成了一维、二维或三维的超分子空间结构。2、稀土配合物的发光研究发现：(1)用配体的π-π〓跃迁波长进行激发，配合物均显示出稀土离子的特征发射峰，同时，配体的荧光峰没有出现，这说明在三脚架配体与稀土离子间进行了有效的能量传递。

With two tripodal ligands, dtma and tmpa, dtma=diethylenetriamine-N'-acetate and tmpa=tris(2-pyridyl-methylamine and a polyamine ligand, trien (=triethylenetetramine), serving as terminal ligands, we synthesized 19 species of new imidazolate -bridged Cu-Zn, Zn-Zn and Cu-Cu, and other relating compounds, in which 〓 and 〓 complexes are model compounds of Cu, Zn-SOD.

用不等臂三脚架dtma(diethylenetriamine-N'-acetate)、直链trien和等臂三脚架tmpatris(2-pyridyl-methyl-amine为配体，合成了一系列咪唑桥联Cu-Zn、Zn-Zn和Cu-Cu等有关19个新化合物，其中两个异双核〓Cu〓和〓〓配合物为Cu，Zn-SOD活性中心的模型化合物。2。

I am accused of being overreligious," she said in her quiet, frank manner,"but that does not prevent me thinking the children very cruel who obstinately commit such suicide.""

客人们在卡罗利娜·埃凯家里，举止就文雅一些，因为卡罗利娜的母亲治家很严厉。

Designed by French fashion house Herm è s, this elegant uniform was manufactured in our home, Hong Kong, and was the first without a hat.

由著名品牌 Herm è s 设计，这件高贵的制服是香港本土制造，是我们第一套不配帽子的制服。