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Evaluation index of industrial water pollution are defined based on industrial wastewater emission standards and the emphasis of water control, according to industrial water pollution emissions data of 31 provinces in China impact of water pollution is calculated by the improved entropy method, lead, cyanide and ammonia nitrogen are in the top three on the impact of water pollution, water pollutant index are divided into heavy metals index and composite index by variable cluster.

根据我国工业各行业的排放标准和水污染控制重点,确定了我国工业水污染状况评价指标,采用改进熵权法对我国31个省区工业水污染物的排放数据进行计算,得到工业废水中铅、氰化物、氮氨对水污染影响居于前三位,应用变量聚类将水污染物分成重金属指标和复合指标,通过熵值对全国各地区工业水污染总体状况、重金属指标、复合指标进行排序,得到东部、中部地区是我国工业水污染较严重地区,但两个地区工业水污染原因有较大区别。

According to the experiment results of degradation in field, degradation mechanism of the biodegradable mulch film can include four stages: the first, the material surface appeared deficiency while the surface area and interstice increased of material in the action of natural environment and microorganism; the second, along with the surface area and interstice of material increased and the gap strengthened, the chemical chain of the high polymer's principal chain broke as a result of the hydrolysis or the enzymatic effect in the action of hydration, causing the molecular weight and mechanics function descended; the third, the molecular of high polymer split the low polymer after its physical mechanical function descended, the material decomposed the fragments, the mass defect intensified; the fourth, the low polymer of fragments form in the natural environment, the microorganism, the biological enzyme became the smaller fragments, thus absorbed by the phagocytes, or further turn into CO2 and H2O due to hydrolysis.

根据田间降解试验结果推测,生物全降解地膜的降解机理可能包括四个阶段:第一,在自然环境、微生物作用下,材料表面出现缺陷,同时表面积增大、空隙增多;第二,随着材料表面积的增大、空隙的增多,吸水性增强,在自水合作用下,高聚物主链由于水解或酶解而使化学链断裂,导致分子量和力学性能下降;第三,在其物理机械性能下降后,高聚物分子链断裂为低聚物分子,材料裂解为碎片状,质量损失加剧;第四,碎片状低聚物在自然环境、微生物、生物酶作用下进一步水解变成尺寸更小的碎片,从而被吞噬细胞吸收,或进一步水解,生成CO2和H2O。

Water,decyloleate,propylene glycol,stearic acid,glyceryl stearate,peg-100 stearate,iris germanica(orris extract/cells),chamomilla recutita,arctium majus,prunus dulcis,ceteareth-3, Triethanolamine,phenoxyethanol,methylparaben,imidazolidinyl urea,carbomer,c12-13 alkyl lactate,disodium edta,propylparaben,glyceryl hydroxystearate,cetyl esters,ethylparaben,pentadecalactone,cera microcristallina,trihydroxystearin,butylparaben,hydroxystearic acid,isobutylparaben,chlorhexidine digluconate,tetradecyloctadecanoic acid,tetradecyleicosanoic acid,tocopherol,lecithin,ascorbyl palmitate,glyceryl oleate,citric acid

水,油酸癸酯,丙二醇,硬脂酸,甘油硬脂酸,聚乙二醇硬脂酸酯,鸢尾花提取物/活细胞,洋甘菊萃取,牛蒡提取物,甜杏仁油,鲸蜡硬脂醇醚,三乙醇胺,苯氧乙醇,羟苯甲酯,尿素醛,卡波姆,c12-13烷醇乳酸酯,乙酸乙二胺二钠,羟苯丙酯,甘油羟基硬脂酸酯,十六烷基酯,羟苯乙酯,环十五内酯,微晶蜡,三羟基硬脂精,羟苯丁酯,羟基硬脂酸,对羟基苯甲酸异丁酯,洗必泰葡萄糖酸盐,十四烷基十八烷酸,十四烷基二十烷酸,维生素E ,卵磷脂,抗坏血酸棕榈酸酯,甘油硬脂酸,柠檬酸水:几乎所有护肤品成分第一位都是水。油酸癸酯:滋润、柔肤剂,并常添加于多种化妆品中作为溶剂

A very mild and extremely efficient hydrolysis method for transformation of polystyrene-b-poly (tert-butyl acrylate) to polystyrene-b-poly was designed and carried out using more convenient and inexpensive chlorotrimethylsilane/sodium iodide as reagents.

在温和的条件下使用廉价方便的三甲基硅氯烷/碘化钠作试剂,在乙腈溶剂中,50℃下使聚苯乙烯-嵌-聚丙烯酸特丁酯高效的水解。用透射电镜和动态光散射对嵌段共聚物聚苯乙烯-b-聚丙烯酸在水介质中的胶束化进行了研究。

Structural model based on SAXS patterns and TEM images shows that the ordered mesostructure consists of 8 large and 16 small caged pores, of which 8 large cages are arranged tetrahedrally on a diamond-like lattice.

第三章采用水溶性resol型酚醛树脂预聚体与反相三嵌段共聚物PPO-PEO-PPO R1PO_(53EO_(136)PO_(53)体系,通过溶剂挥发诱导自组装过程,首次合成出金刚石面心立方(Fd3m)结构的有序介孔碳材料。

The copper atom is in a planar coordination site of [N_2O_2] and it devites from the mean plane by only 0.80 pm. Byπ-πstacking interactions, a alabastrine structure was obtained.(2)Schiff-base complex [Cu(H_2O)]·H_2O, where H3GS is the 3-carboxyl -salicylidene glycine, was synthesized and characterized by elemental analysis, IR spectra and single-crystal analysis. The crystal belongs to monoclinic system, space group P2(1)/c, a=848.46(3)pm, b=681.54(3)pm, c=1967.16(8)pm,β=95.8210(10)°, Z=4, R_1=0.0279, wR_2=0.0724. The copper atom is in a square-pyramidal field with the base

结果表明该晶系属单斜晶系,空间群P2(1)/c,晶胞参数:a=848.46(3)pm,b=681.54(3)pm,c=1967.16(8)pm,α=90°,β=95.8210(10)°,γ=90°,Z=4,R_1=0.0279,wR_2=0.0724,Cu原子位于轻微变形的四方锥场底心,底面被氮原子、酚氧原子、甘氨酸羧基的一个氧原子和一个水分子氧原子占据,而甘氨酸羧基的另一个氧原子占据相邻分子的锥顶,因而形成一维链状结构;合成了单核双聚配合物Na_2[Cu_2_2]·2H_2O ,铜三核配合物Cu_3_2·5H_2O和铜锌异三核配合物ZnCu_2_2·5H_2O,并用元素分析,IR光谱,电子光谱和磁化率测定对配合物的组

Both crystallographically unique Zn atoms exit as an octahedral geometry. The four equatorial positions of Zn1 atom are occupied by the carboxylate-oxygen atoms of the two tartrates, and the two oxygens of the left four carboxylate-oxygen atoms coordinate to two different Zn2 atoms, respectively, forming infinite coordination polymer chains. The left two of the trans equatorial positions of Zn2 atom are completed with two oxygen atoms of two water molecules. The axial positions of both Zn atoms are occupied by the nitrogen atoms from different 4,4'-bipyridine molecules to give a 2D rectangular-grid layers with a cavity dimension of 0.51165(3)nm×1.13896(5) nm. A three dimensional network is formed by the crystallization water chains joined by the carboxylate-oxygen atoms through hydrogen-bonding interactions.

两个晶体学独立的Zn原子均为八面体构型,其中Zn1原子赤道配位点被2个酒石酸根中的4个羧酸根氧螯合配位, 2个酒石酸根中剩下的4个羧酸根氧中的2个分别与2个Zn2原子连接形成无限一维链, Zn2原子的另外2个反式赤道配位点被2个水分子氧占据,同时这两种Zn原子的轴向配位点均被4,4'-联吡啶的氮原子占据,形成具有矩形格子[0.51165(3) nm×1.13896(5) nm]的二维层状结构,游离的2个水分子通过氢键作用形成二聚体,并与酒石酸根中未与Zn配位的羧酸氧连接,把二维层状结构连接成三维网状的超分子结构。

Inspected gathered in advance the body preparation method influence, the neutralizaing agent triethylamine to the disperser craft and the stability of emulsion influence, the water affinity chain extendor DMPA amount used to the river character polyurethane emulsion performance influence, the isocyanogen diethylene glycol dinitrate amount used to the river character polyurethane emulsion performance influence and the soft section low-molecular polymer dihydroxy alcohol amount used to the river character polyurethane emulsion performance influence.

考察了预聚体制备方法的影响,中和剂三乙胺对分散工艺及乳液稳定性的影响,亲水扩链剂DMPA的用量对水性聚氨酯乳液性能的影响,异氰酸酯的用量对水性聚氨酯乳液性能的影响及软段低聚物二元醇的用量对水性聚氨酯乳液性能的影响。

In the high efficiency oil removal technology aspect, the theory study and application experiment of air sparged liquid-liquid hydrocyclone was carried out, enlightened by the air sparged solid-liquid hydrocyclone. Firstly, the strength and movement of dispersed phase was analyzed in theory, it was proved that the air bubble-oil drop polymer trend to move to the axes of hydrocyclone. Secondly, using CFD method, the characteristics of oil-air-water flow field were studied, including velocity distribution, pressure distribution, turbulent motion energy and its dissipation distribution. The characteristics and separation effect under different air injection methods were simulated. Thirdly, the separation ex-periment of air sparged liquid-liquid hydrocyclone was carried out at Lab. The major structure parameters of the hydrocyclone were optimized, the reasonable air injection method and performance parameters were determined through 4 groups of air injection experiments.

首先,对气携旋流场中分散相粒子的受力及运动进行了理论分析,证明了气泡与油滴形成的聚合体,更易于向轴心运动;其次,应用CFD方法,研究了油-气-水三相流场的速度分布、压力分布、湍动能及其耗散率分布特性,对不同注气方式的流场特性及分离效果进行了数值模拟;第三,开展了气携液-液旋流分离特性室内研究,优化了旋流器的主要结构参数,对四种注气方式的分离效率进行了对比,确定了合理的注气方式和操作参数;最后,在油田现场开展了处理聚驱采出污水工艺试验,确定了工艺运行参数,评价了处理效果。

The polyurea coating was tested with Taber tribomachine and the highp ressure water jet erosion tester for studying the wear behavior of polyure coating under conditions of dry friction and highspeed water jet contained sand. The morphology of the coating was observed with SEM and Chromatic confocal 3D Profiler. The surface component of test samp les was measured by FT2IR Spectrometer and Electron Energy Disperse Spectroscopy. The p roperties of polyurea coating under two testing conditionswas analyzed.

为研究聚脲涂层在干摩擦条件下和高速含砂水流冲蚀条件下的性能变化情况,用 Taber 磨损试验机和高速含沙水射冲蚀磨损试验机测试了聚脲涂层的磨损性能,用扫描电子显微镜和白光共焦三维轮廓仪观测涂层的磨损表面形貌,用表面红外光谱和电子显微镜能谱元素分析了涂层表面试验前后的组分变化,分析了涂层在2种摩擦条件下的磨损情况。

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