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三聚体

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It belongs to triclinic system with space group P-1, a=0.7382(1) nm, b=0.9992(2) nm, c=1.1535(2) nm,α=81.41(2)°,β=85.72(2)°,γ=72.21(2)°, D=1.404 gcm^(-3), V=0.8007(38) nm^(-3), Z=2. The crystal structure shows that the compound has trans configuration and characteristic dimers connected by intermolecular hydrogen bond.

结果表明,该晶体属三斜晶系,空间群P-1,V=0.80070(38) nm^3,Z=2,D=1.404gcm^(-3),a=0.7382 (1) nm,b=0.9992 (2) nm,c=1.1535 (2) nm,α=81.41 (2)°,β=85.72(2)°,γ=72.21(2)°,分子结构呈反式构型,通过分子间氢键组装成二聚体。

The aqueous polyurethane prepolymer was prepared through step-growth polymerization of diphenylmethane diisocyanate with polyester glycol and dimethylol propionic acid, which was then neutralized by triethylamine to form the stable transparent aqueous polyurethane dispersion.

以二苯基甲烷二异氰酸酯、聚酯二醇、二羟甲基丙酸等为原料合成了水性聚氨酯预聚体,用三乙胺中和制备了水性聚氨酯的透明乳液。

In this model, the NAC dimmer localized at the center; The first part (1-62aa) and the third part (114-162aa) surrounded this center and formed heterogenetic association; The UBA domain distributed at two ends.

这个模型的中心为NAC二聚体结构,第一部分(1-62位氨基酸)和第三部分(113-163位氨基酸)围绕这个中心异源聚合在一起,UBA结构域分布在两端。5、PeaT1结构与功能的关系。

Erve growth factor can combine with its" receptor (one of tyrosine protein kinase receptor coded by proto - oncogene tyrosine kinase, TrkA), Causing the molecule of receptors to gather on the cell surface, and the tyrosine protein in cytoplasmic domain may be activated, three tyrosine base in the kinase domain of its" receptor and two tyrosine base at other domain be phosphated, thus, phosphated tyrosine receptor kinase became the bracket which absorb all kinds of connective proteins and kinases.

GF与其酪氨酸受体激酶受体(由原癌基因trk编码的一种酪氨酸蛋白激酶受体,TrkA)相结合,引起受体分子在细胞表面发生二聚体化,然后受体细胞内结构上酪氨酸活性被激活,使受体自身结构中位于激酶结构域的三个酪氨酸残基及在此结构域外的两个酪氨酸残基发生自身磷酸化,这样,磷酸化的酪氨酸受体激酶A便成为吸收各种连接蛋白质和酶的支架。

The molecular designs and synthesis of triarylamine-based picolinic acid derivatives used as ancillary ligands, and their cyclometalated iridium complexes used as red-and green-emitters, as well as optoelectronics properites of these compounds were investigated in order to solve current problems of organic/polymeric electroluminescent materials and devices.

本论文针对目前有机/聚合物电致磷光材料和器件存在的问题,开展了新型三芳胺吡啶羧酸类辅助配体及其红光和绿光环金属铱配合物电致磷光材料的分子设计、合成和光电性能研究,主要包括:(1)设计、合成了三种新型的三芳胺吡啶羧酸类双齿阴离子型辅助配体;(2)以三芳胺吡啶羧酸衍生物作为双齿阴离子型辅助配体,合成得到了两个系列的红光和绿光环金属铱配合物;(3)研究了三芳胺吡啶羧酸类辅助配体分子结构对环金属配合物的紫外吸收和光致发光性能的影响;(4)以环金属配合物为客体,聚芴和恶二唑衍生物为主体,制作了聚合物电磷光器件,研究了含三芳胺吡啶羧酸类辅助配体、环金属配合物客体材料和聚合物主体材料等分子结构对电致发光性能的影响。

The tertiary amine of MDEA was sulfonated with γ-Propane sultone, thereby converting these polyurethanes into zwitterionomers.

并通过MDEA中的第三胺与Υ-丙磺内酯反应,转化为双离子型离聚体。

The chalice-shaped, trimeric receptor is knit together by subunit subunit contacts implicated in ion channel gating and receptor assembly.

这种三聚结构揭示了配体结合、阳离子进入和通道门控的一些分子基础。

The invention uses the fermentation liquor of one Escherichia coli generating polysialic acid as material, filters and removes thallus, adds some solvents as sodium chloride and alcohol into supernatant to deposit polysialic acid, dissolves the polysialic acid deposits via deionized water, filters to remove modified protein, uses alkali prolease to treat filtrate, complexes deposits via cetyl pyridinium chloride or cetyltrimethylammonium bromide, and dissociates, uses over alcohol to deposit polysialic acid, dissolves the deposits via ultra-pure water, grades and purifies via chromatography column, collects and dialyzes eluent, cools and dries to obtain polysialic acid.

本发明以一株产聚唾液酸大肠杆菌的发酵液为原料,经过过滤去除菌体,上清液加入适量氯化钠和乙醇等溶剂沉淀出聚唾液酸,聚唾液酸沉淀用去离子水溶解,再用过滤去除变性蛋白质,滤液经过碱性蛋白酶处理、氯代十六烷基吡啶或十六烷基三甲基溴化铵络合沉淀并解离后,再用过量乙醇沉淀出聚唾液酸,聚唾液酸沉淀用超纯水溶解,用层析柱进行分级纯化,收集洗脱液经过透析,冷冻干燥得聚唾液酸产品。

Lithologies are mostly sand and carbonate rocks, caps are mud rock, shale and magmatite. Entrap types are anticline, fault block rebuilt by breaking and the screened entrap diapered rock mass. The composition is CO_2, N_2, CH_4, C_2H_6 and He etc. It is magma air source body and its geologic fashions are intrusion and buried volcanic conduit. The relations between gas reservoirs and gas source bodies have three types: magma intrusion-breaking-communicated gas reservoir, magma intrusion-contacted CO_2 reservoir and buried volcanic conduit-contacted gas reservoir. The CO_2 migration in magma intrusion is consisted of fusing and crystallizing phases;it in volcanic conduit is consisted of near-surface effusion and crystallizing phases.The buoyancy of CO_2 in water far more than migration resistance in breaking or chink, CO_2 is easy float upward, the floating can results in differentiation of different density gases and concentration of sealed gas. The gas in sand reservoir firstly migrate into the higher porosity and coefficient of permeability sand, and along with the pressure going up it migrate into the lower. In magma intrusion-breaking-reservoir migration, CO_2 firstly migrate into watered breaking, began gravity differentiation and concentrate, the gas pressure time and again go up, CO_2 migrate into reservoir and concentrate under expansibility as the pressure reach upward a given extend. The CO_2 in reservoir experience four breaking modes: chemistry deposition, dissolution, diffusion and mechanic breaking, the pressure balance can be broken by faulting and the CO_2 will further migrate and form new reservoir.

济阳坳陷已发现的八里泊、阳25、平方王、平南、高青、花17 CO_2气藏主要储集层位有奥陶系、中生界、沙四段、沙三段、沙一段、馆陶组和明化镇组,储集层岩性以砂岩和碳酸盐岩为主,盖层以泥质岩、页岩和岩浆岩为主。;圈闭类型主要为受断裂改造的背斜、断块及刺穿岩体遮挡圈闭。;气体成分主要有CO_2、N_2、CH_4、C_2H_6、He等。;主要气源体为岩浆气源体,气源体的主要地质形式为侵入体和埋藏的火山通道。;气藏和气源体的空间关系有岩浆侵入体一断裂一气藏沟通型、岩浆侵入体-CO_2气储集层接触型和埋藏火山通道-气储集层接触型三种类型。;岩浆侵入体CO_2气运移分为熔融运移阶段和结晶运移阶段,火山通道中CO_2气运移分成近地表喷发阶段和结晶运移阶段。;断裂中,CO_2在水中的浮力远大于运移阻力,CO_2气容易上浮,CO_2在断裂中的易浮性导致不同密度气体的分异和走向上封闭的断裂气体相对富集。;气体在砂岩储集层运移聚集具有选择性,会优先进入孔隙度和渗透率较高的砂岩,随着压力增加,才会进入孔隙度和渗透率较低的砂岩;在岩浆气源体-断裂-储集层空间输导格架下,CO_2气在膨胀力的驱动下,首先进入含水的断裂并重力分异而聚集,气体压力会不断增高,当压力增至一定程度,CO_2气会向高孔隙度、渗透率的储集层运移并聚集。;在岩浆气源体-储集层接触空间输导格架下,CO_2气受膨胀力的驱动直接向储集层运移并聚集。;成藏的CO_2气会经历化学沉淀、溶解、扩散和机械破坏四种破坏方式,会受断裂切割而打破压力平衡,沿断裂进一步运移和聚集成藏。

Compound 20 has a two-dimensional hybrid structure on the basis of A-type Anderson polyoxometalates and trinuclear silver coordination complex subunits and sodium dimmers.

化合物20是将A型Anderson多酸与三核的银配合物簇及钠的二聚体形成的2D杂化结构。

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Plunder melds and run with this jewel!

掠夺melds和运行与此宝石!

My dream is to be a crazy growing tree and extend at the edge between the city and the forest.

此刻,也许正是在通往天国的路上,我体验着这白色的晕旋。

When you click Save, you save the file to the host′s hard disk or server, not to your own machine.

单击"保存"会将文件保存到主持人的硬盘或服务器上,而不是您自己的计算机上。