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They had suppressed the cathodic process of carbon steel electrode. Their inhibition performance was also related with their molecule stereo conformation and electron configuration. Four of bis-(1, 1'-benzotriazoly)-α,β-diamide compounds linked via-CO 〓CO-chain were synthesized and certified by IR and 〓H-NMR. The minimum energy conformations of these compounds were obtained by MM2 forcefield program. The two benzotriazole moiety in BBT1 was more planar than in other compounds. This was beneficial in increasing the inhibition effects of BBT1. In 0.5M H〓SO〓 solution, BBT1 suppressed anodic corrosion reaction. In 3%NaCl solution, BBT1 suppressed both cathodic and anodic corrosion reactions. 1- [ (1'-imidazolly)-methyl] benzotriazole was synthesized by Mannich reaction.

合成了四个通过-CO〓CO-连接的双(1,1'-苯并三唑)-α,ω-二酰胺化合物,采用MM2分子力学程序优化了它们的分子结构,双(1,1'-苯并三唑)-α,ω-二酰胺化合物的缓蚀作用与其分子内两个苯并三唑单元的空间取向有关系,良好的平面性有利于苯并三唑二聚体的吸附和缓蚀作用,苯并三唑二聚体BBT1分子内两个苯并三唑单元近似平行,所以显示出较好的缓蚀效果。0.5M硫酸中BBT1主要抑制铜的阳极溶解的电化学反应;3%NaCl溶液中,BBT1对铜的阳极溶解和氧的阴极还原过程均有抑制作用,相比较而言对阴极过程的抑制作用更大一些。

Type B is found in chlorophyta, high plant chloroplasts and cyanobacteria with two exceptions, Prochlorococcus marinus and Synechococcus sp.

RubisCO可分为三种类型:Ⅰ型存在于植物和一些光合细菌中,是由8个大亚基和8个小亚基形成的16聚体L_8S_8;Ⅱ型存在于甲藻和某些光合细菌中,通常由大亚基形成2聚体L_2;而Ⅲ型存在于一些古细菌中,先由2个大亚基形成2聚体L_2,再由5个2聚体形成10聚体(L_2)_5。

Functional ASICs are usually believed to be tetrameric assemblies of homomeric or heteromeric subunits.However,recent Gouaux and colleagues crystal structure shows that there are three subunits in ASIC1 homomeric channel.

功能性的ASICs通常被认为是由相同或不同的亚单位形成的四聚体,然而最近Gouaux等的晶体结构研究表明ASIC1同聚体由三个亚单位装配而成。

The result indicated that, gathers in advance the emulsion water resistance and mechanics performance which in the body preparation method the one-stage process obtains is good, but two steps obtain the emulsion stability is good; The neutralizaing agent triethylamine amount used should enable to achieve neutral between x-y, to gathers in advance the body disperser and the emulsion stability only then is advantageous; The water affinity chain extendor DMPA content to the emulsion viscosity, stable and the emulsion cellophane water resistance has the remarkable influence, its amount used general control between x-y; Hard section isocyanogen diethylene glycol dinitrate primary control paint film degree of hardness, module, anti-avulsion, wear-resisting and so on performance, the soft section low-molecular polymer polyols primary control paint film elasticity, hydrolisis performance and so on bears the low temperature and bears

结果表明,预聚体制备方法中一步法得到的乳液的耐水性和力学性能较好,而两步法得到的乳液的稳定性好;中和剂三乙胺的用量应使中和度达到x-y之间,对预聚体的分散和乳液的稳定性才有利;亲水扩链剂DMPA的含量对乳液的粘度、稳定性及乳液胶膜的耐水性有着显著的影响,其用量一般控制在x-y之间;硬段异氰酸酯主要控制涂膜的硬度、模量、抗撕裂、耐磨等性能,软段低聚物多元醇主要控制涂膜的弹性、耐低温和耐水解等性能

NodD binds to and bends target promoters through anchoring two tandem and individual specific DNA sites. NodD functions as a tetramer, which has a V-shaped main body. Tetrameric NodD is to change its own conformation rather than its oligomeric forms in response to small signal molecules. The specific interaction between each NodD DNA-binding domain and each specific DNA site does not alter itself in spite of naringenin induction, and the induced conformational change is transferred from protein to DNA. Only the DNA conformation incited by induced NodD is competent for RNA polymerase to form the transcriptional open complex. It cannot be excluded that NodD may have protein-to-protein contacts with RNA polymerase, and that the NodD conformational change may also directly contribute to the transcriptional open complex formation. However, the NodD conformational change itself cannot serve as the determinant of the transcriptional molecular switch.

通过研究,我们提出了初步的NodD操纵子激活模型:第一,四聚体是NodD蛋白的功能单位,它通过铆钉两个串联的相对独立的DNA靶位点结合被诱导的启动子;第二,小分子配基的结合是改变NodD四聚体的构象而不是引发不同形式的寡聚体,在我们的模型中,NodD四聚体缩小其V形主体的弯折角,进而缩短其DNA结合功能域的间距;第三,小分子信号的诱导并没有改变NodD的DNA结合域和其DNA靶位点的相互作用,NodD的构象改变由蛋白质经其双铆钉位点传递给DNA;第四,只有诱导状态的NodD激发的DNA构象才能有效地使RNA聚合酶形成转录开放复合物;第五,不排除NodD与RNA聚合酶可能有直接的相互接触位点,不排除NodD构象的改变可能直接有利于RNA聚合酶形成转录开放复合物,但是我们认为NodD构象改变本身不是充当转录激活开关的决定因素。

A series of modified polyurethane elastomer materials with different amino siloxane content were synthesized,which were based on polyoxypropylene glycol,aminoethyl aminopropyl poly,toluene diisocyanate and the curing agent dimethylsulfide toluylenediamine.

以聚氧化丙烯二醇或聚氧化丙烯三醇、氨乙基氨丙基聚二甲基硅氧烷、甲苯二异氰酸酯为原料在无溶剂条件下制备预聚体,利用二甲基硫甲苯二胺为固化剂合成一系列氨基硅油改性聚氨酯弹性体材料,并对材料的力学性能、耐热性、表面水接触角等性能进行了测试。

The β-CA of B.napus was located in chloroplast stroma and had the conservative motif Cys-X(subscript n-His-X2-Cys peculiar to β type carbonic anhydrases. In the secondary structure,α-helix, random coil,β-sheet, and β-turn were 39.88%, 39.27%, 16.31%, and 4.53%, respectively. The three-dimensional structure was constructed by homology modeling. The 3-D alignment of β-CA from B.napus and a monomer of β-CA octamer from pea showed that the 3-D structure of β-CA from B.napus could match well with the monomer. The alignment results Implied that β-CA from B.napus was a monomer of the β-CA octamer from B.napus.

预测结果显示,甘蓝型油菜β破酸酐酶是定位于叶绿体基质的蛋白质,具有β类碳酸酐酶所特有的保守性基序Cys-χ-His-χ2-Cys;SOPMA预测二级结构显示α螺旋(39.88%)、随机卷曲(39.27%)、β折叠(16.31%)和β转角(4.53%);用同源建模法构建了三维结构图;通过VAST矢量比对工具将甘蓝型油菜β碳酸酐酶与模板进行三维结构比对,显示甘蓝型油菜β碳酸酐酶与碗豆β碳酸酐酶同型八聚体中的一个单体很好的匹配,推测甘蓝型油菜β碳酸酐酶全酶也是同型八聚体。

The results reveal that two energy transfer paths (i. e.β-PEB→α/β-PCB and β-PEB→α/βPCB′) with time constants of 50ps and 200ps, respectively, exist in R-PC monomers, and that α/β-PCB′chromophores are the terminal emitting acceptors with fluorescence lifetimes of 1150 ps. The experimental results of time-resolved fluorescence spectroscopy in case of R-PC trimers exhibit that the corresponding energy transfer processes are faster in R-PC trimers than in R-PC monomers, with time constants being 45ps, 165 ps and 920ps.

结果显示:在R-PC单体中存在2条能量传递途径,即β-PEB→α/β-PCB和β-PEB→α/β-PCB′能量传递过程,其时间常数分别为50ps和200ps;作为终端发色团的α/β-PCB′的荧光发射时间常数为1150ps.R-PC三聚体的时间分辨荧光光谱实验结果显示对应的能量传递过程速率加快,其时间常数分别为45ps,165ps和920ps。

NiRs are divided into two different types based on their prosthetic groups, namely heme-containing nitrite reductases (cd1-NiRs) and Copper-containing nitrite reductases.

Cu-NiRs呈三聚体结构,每个单体都含有两种类型的铜原子,它们在酶催化过程中起着传递电子的重要作用。在催化过程中,Cu-NiRs中部分残基的结构变化有利于催化反应的进行。

Hexafluoropropene and its derivatives are mainly used in the field of fluorocarbon surfactantve and have a better forground.

六氟丙烯三聚体和其衍生物主要被用在氟碳表面活性剂领域,有较好的发展前景。

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On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面,更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值,分为几个相等的区间作为横轴,并将各区间内所测定值依所出现的次数累积而成的面积,用柱子排起来的图形,也叫做柱状图。

You rap, you know we are not so good at rapping, huh?

你唱吧,你也知道我们并不那么擅长说唱,对吧?