三聚体

It is demonstrated that the chiral quaternary ammonium salts catalysts exhibit promising catalytic properties for the substrate. Part III: The synthesis and the characterizing of the macroporous aminomethyl resin-supported cinchona alkaloid complexes and the study on its catalytic properties The part consists of two subsections. the macroporous aminomethyl resin -supported cinchona alkaloid complexes were synthesized by the stuff (cinchonine, quinine and macroporous aminomethyl resin). Their structures were characterized by means of elemental analysis, XPS, TG/DTA; the chiral polymer-supported complexes were first used as catalysts for the reduction of ketones. Their catalytic properties for the reduction processes were investigated. The comparison of the products e.e., the conversion of the substrate among different reduction processes was employed with determined by HPLC. The effects of the time, the temperature, the ratio of catalyst to substrate, reaction solvent as well as the recycle times were also discussed.

第三章聚-4-氨甲基苯乙烯负载金鸡纳碱金属络合物的合成与表征及其不对称催化性能研究本章分为两节，以辛可宁和奎宁及聚-4-氨甲基苯乙烯为原料，合成了4种聚-4-氨甲基苯乙烯负载金鸡纳碱络合物催化剂，并对它们的结构用元素分析、X-射线光电子能谱、TG/DTA等几种测试手段进行了表征；首次将所合成的手性高分子负载的金属络合物用于催化芳香酮不对称还原反应，详细研究了所得的手性高分子负载的金属络合物对不同底物的催化性能，用HPLC等分析手段定量检测了还原过程的底物转化率及其产物对映异构体选择性，并考察了反应时间、反应温度、催化剂和底物投料比、反应溶剂和循环次数对催化性能的影响。

The thermolysis of the isomerized products derived from norbornadiene-coordinated carbonyl iron complexes gave two sorts of the thermolytic products based on different substituents on the olefin ligands. One is the corresponding diiron dimer complex, and the other is the complex in which the C-C bond of the cycloolefin ligand is broken.

以降冰片二烯三羰基铁络合物衍生出来铁卡宾络合物的异构化产物的热解，随着烯烃配体上取代基的不同，而分别得到了络合物发生二聚和烯烃配体发生碳碳键断裂的两类热解产物。

Three new fulvene polymeric compounds, namely 1[Ag (L3]CH2C12 , 2[Ag2(L25(H2O)(S03CF3)2]0.5C6H6 and 3 Mn(L42(C2H5OH)2 , were synthesized, respectively. Compounds 1 and 2 reported herein represent the organometallic polymers based on both Ag-N and Ag-C coordination interactions. In the solid state, compound 3 are bound together by strong intermolecular N H-O hydrogen bonding system into a supramolecular one-dimensional H-bonded chain.B.

一、富烯有机配体的合成及与金属离子的反应化学利用富烯负离子的芳酰化反应和Heck-偶联反应合成了富烯配体L1-L18，并合成了三个基于富烯配体的金属有机配位聚合物1[Ag(L3]·CH_2Cl_2、2[Ag_2(L25(H_2O)(SO_3CF_3)_2]·0.5C_6H_6和氢键驱动的超分子聚集体3Mn(L4_2(C_2H_5OH)_2。

In this paper a series of multiblock copolymers were synthesized by polycondensation of poly , phthalic anhydride and epoxy resin in the presence of triethyl benzyl ammonium chloride as the catalyst.

以三乙基苄基氯化铵为催化剂，将聚乙二醇、邻苯二甲酸酐和环氧树脂进行共缩聚，制得聚乙二醇-环氧树脂系列多嵌段共聚体。

The forming process for the high-strength, steel-base modified polyformaldehyde composite material in five-laver structure is to melt modified polyformaldehyde by heating and roll to make the melt polyformaldehyde permeate into the gaps gaps between the large-grained spherical copper powder and screw copper nails.

四层结构的钢基铜塑复合材料的成型过程，是将改性聚甲醛加热熔化，经轧制，使熔融的聚甲醛渗透到大颗粒球形铜粉的间隙中，解决了三层材料复合过程中，熔融的聚甲醛水平流动性强过垂直方向的渗透性，造成了结合强度低的缺陷，使聚甲醛层与铜粉及基体结合更牢固，提高了其承载和抗剪切的能力。

The forming process for the high-strength, steel-base modified polyformaldehyde composite material in five-layer structure is to melt modified polyformaldehyde by heating and roll to make the melt polyformaldehyde permeate into the gaps between the large-grained spherical copper powder and screw copper nails.

五层结构的高强度钢基改性聚甲醛复合材料的成型过程，是将改性聚甲醛加热熔化，经轧制，使熔融的聚甲醛渗透到大颗粒球形铜粉的间隙中，解决了三层材料复合过程中，熔融的聚甲醛水平流动性远强过垂直方向的渗透性，造成了结合强度低的缺陷，使聚甲醛层与铜粉、螺旋铜钉及基体结合更牢固，提高了其承载和抗剪切的能力。

The forming process for the high-strength, steel-base modified polyformaldehyde composite material in five-layer structure is to melt modified polyformaldehyde by heating and roll to make the melt polyformaldehyde permeate into the gaps between the large-grained spherical copper powder and screw copper nails.

五层结构的高强度钢基改性聚甲醛复合材料的成型过程，是将改性聚甲醛加热熔化，经轧制，使熔融的聚甲醛渗透到大颗粒球形铜粉与螺旋铜钉的间隙中，解决了三层材料复合过程中，熔融的聚甲醛水平流动性远强过垂直方向的渗透性，造成了结合强度低的缺陷，使聚甲醛层与铜粉、螺旋铜钉及基体结合更牢固，提高了其承载和抗剪切的能力。

The results showed compared with the native state the shear strength of rockmass under the saturation state decreased by 11.17%, cohesion force decreased by 16.09%, internal frictional angle decreased by 10.02%.(3) 3D-σFEM numerical simulation software is used to simulate the slope stability on the native state and saturation state. Compared with the nature state the displacement of the discontinuity and stress concentration in the saturation state is largened clearly, the results showed slope stability under the rainfall is weakened.

更多含有天然结构面的岩体试件进行了不同含水量下的强度试验，试验结果证明在岩体试件处于饱水状态时的结构面抗剪强度比天然状态下平均下降了11.17%、粘聚力平均下降了16.09%、内摩擦角平均下降了10.02%；(3)采用3D-σ有限元数值软件对K86+180～K86+470段岩质边坡进行了三维有限元数值模拟，并且分天然状态分阶段开挖和饱水状态分阶段开挖两种不同状况进行了稳定性分析，从分析结果可以看出与天然状态相比，饱水状态下软弱层水平方向位移明显增大，坡脚及软弱层特别是软弱层临空面附近的剪应力值显著增大，并且其安全系数与天然状态相比也显著减小，说明在有大的降雨发生当岩体处于饱水状态时边坡整体稳定性被削弱，边坡失稳可能性增大。

In this study, Cryptomeria japonica was liquefied in phenol with H2SO4 and HCl as a catalyst. The epoxy resin was synthesized from epichlorohydrin and bisphenol A with the molar ratio of 5/1. Blending resins were prepared by mixing the liquefied Japanese cedar and epoxy resin with weight ratios of 30/100, 50/100 and 70/100, and the triethylene tetramine was added as a cross-linking hardener. The effect of mixing ratios of liquefied Japanese cedar to epoxy resin and amount of hardener added on the reactivity of blending resins and the properties of cured resins were investigated. Furthermore, polysiloxane and rice husk were added as foaming agent and filler, respectively, to the epoxy resin and blending resins. The foaming process, the bubbles shape, the mechanical properties, and the thermal stability of the epoxy foams were investigated.

中文摘要本研究将柳杉(Cryptomeria japonica； Japanese cedar)木材以酚为溶剂，H2SO4及HCl为催化剂进行液化处理，另以莫耳比5/1之环氧氯丙烷与双酚A反应合成环氧树脂，并将液化柳杉与环氧树脂以重量比30/100、50/100及70/100混合制备掺合树脂，并以三乙基四胺(Triethylene tetramine； TETA)为架桥硬化剂，探讨液化柳杉与环氧树脂混合比及硬化剂添加量对其掺合树脂之反应性，及其硬化树脂性质之影响；进一步於环氧树脂与掺合树脂中添加聚矽氧烷为发泡剂，稻壳粉为填料制备发泡体，探讨其发泡体之发泡过程、泡体形态、发泡体机械性质与热稳定性。

In this study, Japanese cedar, Ma bamboo and Makino bamboo were liquefied in polyethylene glycol/glycerol co-solvent with H2SO4 or HCl as catalyst. The liquefied woody materials were blended with PMDI (4,4'-Diphenylmethane diisocyanate;MDI) to prepare the PU foams. The effects of preparation conditions of PU resin on the properties of PU foams were investigated.

中文摘要本研究将柳杉(Cryptomeria japonica； Japanese cedar)、麻竹(Dendrocalamus latiflorus； Ma bamboo)及桂竹(Phyllostachys makinoi； Makino bamboo)等木质材料以聚乙二醇及丙三醇之混合液为溶剂，H2SO4及HCl为催化剂进行液化处理，并将其液化木质材料与4，4'-二苯甲烷二异氰酸酯反应制造聚胺基甲酸酯发泡体，探讨PU树脂调配条件对PU发泡体性质之影响。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。