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By using a mixture of aromatic hydrocarbon and water as a binary solvent,reaction of pyrogallol with PhCCl 3 was carried out in the presence of a catalyst(ZnCl 2?AlCl 3 or SOCl 2).2,3,4-Trihydroxybenzophenone was obtained in yields of 80%-87% with the advantages of easy control,stable yield,high product quality and low cost.

以焦性没食子酸为起始原料,在惰性气体保护和催化剂(ZnCl2、AlCl3或SOCl2)的存在下,在芳香烃与水组成的二元混合溶剂中,与三氯甲苯反应,经过芳香烃溶剂的后处理,可以得到2,3,4-三羟基二苯酮,产率最高达87%。

A polyurethane which is obtained from ingredients comprising a high-molecular polyol, an organic polyisocyanate, and a chain extender comprising a specific trifunctional isocyanurate compound having an aromatic hydroxyl group and/or a benzylic hydroxyl group, and which has a crosslinked structure due to the isocyanurate compound.

从包含高分子量多元醇、有机聚异氰酸酯和扩链剂的成分得到的聚氨酯,所述扩链剂包括含芳羟基和/或苄羟基的特定三官能团异氰脲酸酯化合物,并且其由于异氰脲酸酯化合物而具有交联结构。

This paperindicated that it was good for condensation reaction when benzene-ring bearingelectron-attaching groups. It also showed that and the 6-hydroxyl group could bereacted with acyl halide, haloid ether and halo alkene, but not with halo alkane. It wasnot only the first time to find that the reaction product of D-mannitol and aromaticaldehyde is tri-condensation derivatives, but also the first time to obtain thep-phthaldehyde-sorbitol derivatives containing eight hydroxyl groups.

研究发现:苯环上有吸电子基团时对缩合反应有利;多元醇缩醛衍生物6-羟基除与酰氯反应外,也能和卤代酸酯、溴代烯反应,但不与卤代烷反应;首次发现D-甘露醇与醛反应主要得到三缩合物;首次合成了含有8个羟基的对苯二甲醛和山梨醇的缩合物。

Furthermore, influences of different phosphate salts at various concentrations on the ionization efficiency of phosphopeptide were investigated systematically, finding that the signal intensity for phosphopeptide 48FQEEQQQTEDELQDK63 digested from β-casein were 5 to 8 times increased in an optimized condition with 10 mmol/L ammonium monobasic phosphate or 3 to 4 times increased with 10 mmol/L ammonium dibasic phosphate as additive to matrix 2,5-dihydroxybenzoic acid, respectively.

考察了两种适合于磷酸化肽离子化的基质类型2,5-二羟基苯甲酸和2,4,6-三羟基苯乙酮。用2,5-二羟基苯甲酸作为基质时,当加入10 mM 磷酸氢二铵时,磷酸化蛋白质β-casein的磷酸肽 48FQEEQQQTEDELQDK63的离子化效率可以增强5-8倍,当加入10 mM磷酸二氢胺时,磷酸肽的离子化效率可以增强3-4倍。

As our studies showed, silylation of mesoporous molecular sieves with alkoxysilane was an usual method of linking desired organical groups. However, as a result, the a lot of silanol groups still existed on the surface of mosoporous molecular sieves after silylation, which maybe affect the interface property and its catalystic activity. Based on this consideration, a novel method was proposed that a mixture of trichlorosilanes was used to silylate mesoporous molecular sieves, introducing both the further reactive group and hyhrophobic methyl group in one pot.

正如研究表明,通过硅氧烷与介孔分子筛表面的硅羟基反应是常见的键连有机基团的方法,但表面仍会剩余较多的硅羟基,硅羟基的存在会严重影响到介孔分子筛表面性质及催化活性,为此笔者提出采用混合的三氯化硅烷一步硅烷化介孔分子筛,在孔道内同时引入可进一步功能化的氯丙基或氯苄基和疏水性的甲基。

In leaf tissue of Arabidopsis, the most abundant hydroxycinnamic acidphenolics are sinapate esters, and the most abundant flavonoids are kaempferol derivatives.

拟南芥药用成分主要有酚类化合物,即羟基苯丙烯酸酚类化合物的芥子酸酯,黄酮类化合物的4,5,7-三羟基黄酮衍生物,芥子酸酯与这种黄酮类化合物具有优良的减少紫外线危害和抗氧化作用。

Objective: To investigate the cellular signal transudation pathway of vascular smooth muscle cell proliferation and cytokins secretion stimulated by oxidized low density lipoprotein and insulin-like growth factor-1 (IGF-1) and the intervention effect of HMGcoA reductase inhibitor, atovastatin and immune supppressor, rapamycin.

目的:探讨氧化低密度脂蛋白,胰岛素样生长因子-1(IGF-1)促血管平滑肌细胞增殖及分泌功能改变的细胞内信号转导机制及三羟基三甲基戊二酰辅酶A抑制剂阿托伐他汀与免疫抑制剂雷帕霉素干预作用。

Objective: To investigate the cellular signal transudation pathway of vascular smooth muscle cell proliferation and cytokins secretion stimulated by oxidized low density lipoprotein and insulin-like growth factor-1(IGF-1) and the intervention effect of HMG-coA reductase inhibitor, atovastatin and immune supppressor .rapamycin.

目的:探讨氧化低密度脂蛋白,胰岛素样生长因子-1(IGF-1)促血管平滑肌细胞增殖及分泌功能改变的细胞内信号转导机制及三羟基三甲基戊二酰辅酶A抑制剂阿托伐他汀与免疫抑制剂雷帕霉素干预作用。

The structures were identified by NMR, IRand MS.Results Three compounds were identified from its 80% alcohol extract as: 5,7,3'-trihydroxy- 4'-methoxyflavanone, 4',5, 7- trihydroxyflavanone, stigmaasterol.

结果 从紫茉莉种子的80%乙醇提取物中分离到3 化合物,它们的结构分别被鉴定: 5,7,3'-三羟基-4'-甲氧基黄酮(1), 4',5, 7-三羟基黄酮(2),豆甾醇(3)。

The structures were identified by nmr, irand ms.results three compounds were identified from its 80% alcohol extract as: 5,7,3'-trihydroxy- 4'-methoxyflavanone, 4',5, 7- trihydroxyflavanone, stigmaasterol.

结果 从紫茉莉种子的80%乙醇提取物中分离到3个化合物,它们的结构分别被鉴定为: 5,7,3'-三羟基-4'-甲氧基黄酮(1), 4',5, 7-三羟基黄酮(2),豆甾醇(3)。

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