三碘甲烷

A new chiral quaternary ammonium salt 1a was synthesized by the reaction of cinchonine and(2,4,6-)trimethyl benzyl chloride.Etherification between 1a and benzyl bromide,allyl chloride,or methyl give corresponding etherified quaternary ammonium salts 1b,1c,and 1d.

由辛可宁和2，4，6-三甲基苄氯，合成了一种新的手性季铵盐(1a)，并进一步用苄基溴、碘甲烷和烯丙基氯对分子中的羟基进行醚化，得到相转移催化剂1b、1c和1d。

Experimental process: jing and 3- methyl -2- methyl ethyl ketonesynthesizes by the benzene zong; Again the glacial acetic acidcatalysis produces 2, 3, 3 - trimethyl - 3H - yinduo; Again has thealkylate response production yinduo iodide after the methyl iodide;The iodide takes off molecular HI under NaOH to become freejier thealkali; Adds 5 - nitryls salicylic aldehydes in the ethyl alcohol forthe solvent under if to respond finally produces 6 '- the nitryl yinduolin spiral benzene and pinan; Through the infrared spectrum andthe ultimate analysis irrevocably proved its structure, and studiedthe annulus with to open the annulus the light to send changes colorthe performance, explained in different solvent medium ultravioletabsorption spectrometry solvent effect, and the comparisondiscoloration the response speed number difference, finally mixed itadds to the methyl methacrylate, the peroxidation benzoin formyl in the plexiglass, tested 6 '- the nitryl yinduolin spiralbenzene and pinan in the glass fatigue resistance, thethermostability.

实验过程：由苯肼和3-甲基-2-丁酮合成腙；再冰醋酸催化生成2 ，3 ，3—三甲基—3H—吲哚；再经过碘甲烷发生烷基化反应生成吲哚碘化物；碘化物在NaOH下脱去一分子HI成为费歇尔碱；在乙醇为溶剂下加5－硝基水杨醛与其反应最后生成6'—硝基吲哚啉螺苯并吡喃；通过红外光谱和元素分析确证其结构，并研究了环体与开环体的光致变色性能，解释了在不同溶剂介质中紫外吸收光谱的溶剂效应，并比较褪色反应速率数的差异，最后将其掺加到甲基丙烯酸甲酯，过氧化二苯甲酰有机玻璃中，测试6'—硝基吲哚啉螺苯并吡喃在玻璃中的抗疲劳性、热稳定性。

Rare precious metals company mainly engaged in electroplating and metal surface treatment, environmental treatment, washed clean of raw materials: silver nitrate, nitric acid and rhodium, palladium nitrate; Asia selenium acid, selenium dioxide, tellurium dioxide, mineral selenium powder Japan, Mitsubishi Se powder, Mitsui, Sumitomo, emerging, Germany selenium powder; molybdenum trioxide, DMF; TX-10, NP-9 series, EDTA series; sodium hypophosphite, nickel nitrate, metal thallium, rhodium, palladium, platinum , Beryllium, Ritek, zirconium products; sponge palladium; electrolytic nickel, nickel corner, hydrazine hydrate, Ultra-fine silver, nano-silver; Thallium sulfate, iodized Thallium sulfate, nickel, copper sulfate, copper chloride, copper oxide, nickel oxide , Lanthanum oxide, oxidation Er, bismuth oxide, bismuth ingots, tin ingots, indium ingot, indium foil, Xinding, zinc powder; SnCl2, sulfate-tin; hydrofluoric acid, white Vaseline, propylene glycol, dichloro Methane, the propylene glycol, triethanolamine, triethanolamine oleic acid soap, chloroform, pyrophosphate copper, Gioia sodium, polyacrylamide, PAC, oleic acid, Glycerol, phosphate and other domestic and imported chemical series.

公司主要经营稀贵金属及电镀金属表面处理、环保污水处理、洗涤清洗原料：硝酸银、硝酸铑、硝酸钯；亚硒酸、二氧化硒、二氧化碲、日本矿业硒粉、三菱硒粉、三井、住友、新兴、德国硒粉；三氧化钼、二甲基甲酰胺；TX－10、NP-9系列、EDTA系列；次亚磷酸钠、硝酸镍、金属铊、铑、钯、铂、铍、铼、锆系列产品；海绵钯；电解镍、镍角、水合肼、特细银粉、纳米银粉；硫酸铊、碘化铊、硫酸镍、硫酸铜、氯化铜、氧化铜、氧化镍、氧化镧、氧化铒、氧化铋、铋锭、锡锭，铟锭、铟箔、锌锭，锌粉；氯化亚锡、硫酸亚锡；氢氟酸、白凡士林、丙二醇，二氯甲烷，二丙二醇，三乙醇胺、三乙醇胺油酸皂、三氯甲烷、焦磷酸铜、焦亚硫酸钠、聚丙烯酰胺、聚合氯化铝、油酸、甘油、磷酸等国产、进口化工系列。

Major procurement of goods: a three-chlorosilanes, dichloromethane, AE activity ester, 3-iodine Silane, special acid, pentyl chloride, triethylamine, thiadiazole, tetrazolylazo acid, 2 - Acetamide, tetrahydrofuran, the four-guanidine, isopropanol, five phosphorus trichloride, sodium vary bitter, acid, sodium phenylacetate, 6-2 silicon n-amine, Ethylacetoacetate , Methyl isobutyl ketone, potassium dihydrogen phosphate, aluminium oxide, DL methionine, N, N-dimethylaniline, NN-diethyl aniline, 4 sodium EDTA, Anhydrous sodium sulfate, ammonium sulfate, potassium sulfate, sodium acetate, sodium carbonate, DMC, formic acid, sodium chloride medicinal, oxalate, protopine, acetone, alcohol, acetic acid, vinegar Ethyl, butyl acetate, methanol, ethanol (anhydrous, industrial, medicinal), formaldehyde, Ye Jian (30%), hydrochloride (industrial-grade, refined grade, reagent level), sulfate (98%), Ammonia, calcium carbonate, chlorine dioxide, 6 - APA ,7-ACA ,7-ADCA ,7-ANCA, sulbactam, ceftazidime activity ester, Deng salt (hydroxymethyl-K, acid precursors Potassium, sodium dihydrogen methyl), resin, the enzyme, water treatment agent, Xiao Mo agent, demulsifier, flocculants, activated carbon, all kinds of medicinal materials, All kinds of additives

三甲基一氯硅烷、二氯甲烷、AE活性酯、三甲基碘硅烷、特戊酸、特戊酰氯、三乙胺、噻二唑、四氮唑乙酸、二甲基乙酰胺、四氢呋喃、四甲基胍、异丙醇、五氯化磷、异辛酸钠、苯乙酸、苯乙酸钠、六甲基二硅胺烷、乙酰乙酸乙酯、甲基异丁酮、磷酸二氢钾、三氧化二铝、DL蛋氨酸、N，N-二甲基苯胺、NN-二乙基苯胺、乙二胺四乙酸四钠、无水硫酸钠、硫酸铵、硫酸钾、醋酸钠、碳酸钠、碳酸二甲酯、甲酸、药用氯化钠、草酸、片碱、丙酮、正丁醇、冰醋酸、醋酸乙酯、醋酸丁酯、甲醇、乙醇、甲醛、液碱（30％）、盐酸（工业级、精制级、试剂级）、硫酸（98％）、氨水、碳酸钙、二氧化氯、6－APA、7－ACA、7－ADCA 、7－ANCA、舒巴坦、头孢他啶活性酯、邓盐(羟甲基钾、前体酸钾、二氢甲基钠)、树脂、生物酶、水处理剂、消沫剂、破乳剂、絮凝剂、活性碳、各种药用辅料、各种添加剂

After the solution was kept in the dark for five minutes,chloroform was added into it to adsorb selenium formed by previous reaction,then iodine separated out was determined by sodium hyposulfite titration using starch as the indicator,at last the content of selenium dioxide in the sample was foun.

在溶有二氧化硒的0.4～0.5mol/L盐酸介质中，加入过量的碘化钾，于暗处放置5min后，加入三氧甲烷吸附反应生成的硒，以淀粉为指示剂，用硫代硫酸钠标准溶液滴定析出的碘，测得二氧化硒的含量。

In pH 5.3-6.8 Britton-Robinson buffer medium, Cefotaxime sodium can react with HgCl2 to form 1:1 anionic chelate, which can further react with basic triphenylmethane dye such as crystal violet, methyl violet, ethyl violet, brilliant green, iodine green, methyl green and malachite green to form ternary ion-association complexes. As a result, the resonance Rayleigh scattering spectrum was enhanced greatly.

在pH为5.3~6.8的Britton-Robinson缓冲溶液中，头孢噻肟钠与HgCl2形成摩尔比为1：1的螯合阴离子，它能进一步与结晶紫、甲基紫、乙基紫、亮绿、碘绿、甲基绿和孔雀石绿等碱性三苯甲烷类染料反应形成三元离子缔合物，导致共振瑞利散射的显著增强。

The remaining chapters of this thesis can be divided into two parts: thefirst part includes chapter 2 and 3, where studies about non-adiabaticphotodissociation of 〓 are discussed. Also presented is our theoreticalinvestigation on control of this process with pulsed laser fields; The secondpart of this thesis consists in chapter 4 and 5, where our application of quantumsymplectic methods to the full-dimensional unimolecular dissociation offormyl radical, HCO, is presented, results of ab initio calculation of the dipolemoment surface of HCO are also given.

论文余下的章节可以分成两个部分：第一部分包括第二和第三章，主要讨论对碘甲烷非绝热光解过程的研究，以及利用脉冲激光对这一过程进行控制的理论探讨；第二部分包括第四和第五章，借助量子辛算法研究了HCO三维解离过程中的一些动力学行为，并用从头算方法计算了HCO的偶极矩面。

Experimental data of critical parameters, and the correlations of saturated liquid and vapor density, enthalpy of vaporization, vapor pressure, pVT properties, second virial coefficient, ideal-gas heat capacity, surface tension, viscosity and thermal conductivity are obtained in this paper.

介绍了三氟碘甲烷(CF3I)热物理性质的研究成果，包括临界参数的实验数据以及饱和气液密度、饱和蒸气压、汽化潜热、 pVT性质、第二virial系数、理想气体比热容、表面张力、粘度、导热系数等的关联式，并与文献数据进行了比较，分析了实验数据对关联式的偏差。

The invention relates to a kind of middle/high temperature heat pump refrigerant mixture containing trifluoroiodomethane (R13I1) and tetrafluoroethylene (HFC134a), which is suitable for using as the refrigerants for middle/high temperature heat pump system with a temperature of 60~120deg.C.

一种含有三氟碘甲烷(R13I1)和四氟乙烷(HFC134a)的中高温热泵混合工质，适合作为冷凝温度为60-120℃的中高温热泵系统的制冷剂。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。