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三甲氧基

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Optimization of polyester condensation process and reactor design;2. The Structure Characters of the Sulfonated Condensation Polymer Series High Performance;3. The pH value of the solution was adjusted,and the co- condensation reaction was taken place between the hydroxy groups forming transparent organic-inorganic hybrid films on polycarbonate.

以甲基丙烯酰氧基丙基三甲氧基硅烷(KH-570)水解聚合产物作为主要成膜物质,引入正硅酸乙酯水解产物硅溶胶作为无机增强物,调节两种混合溶液pH值,利用两者羟基之间的共缩聚反应在聚碳酸酯板表面制备有机/无机复合透明耐磨薄膜;采用TG/DTA、FT-IR、SEM及UV-V IS对成膜过程、薄膜性能与结构进行表征。

A steel bar is washed and dried, and then put into a glass pipe which is sealed to obtain stirring magneton; a mixed solvent of Gamma-methacrylate oxide propyl trimethoxy silane and methanol is prepared and added with an organic base to obtain a pre-bonding solvent; the stirring magneton is immerged into the pre-bounding solvent, and the outer surface of the glass pipe of the stirring magneton is bonded with a layer of silane substance with alkenyl; a reactive monomer mixture and a pore-forming agent mixed solvent are evenly mixed and then added into a container, the stirring magneton after the pre-bounding is put into the container which is sealed and then put into a water bath; after reaction, the container is removed, the stirring magneton coated with a polymer is taken out and put into a extractor and extracted by using a solvent; or the stir bar is immersed into the solvent till no impurity can be checked in the solvent, thereby obtaining the product.

将铁条清洗干燥,放入玻璃管内,密封得搅拌磁子;配制γ-甲基丙烯酸氧丙基三甲氧基硅烷与甲醇的混合溶液,加入有机碱得预键合溶液,将搅拌磁子浸入预键合溶液,在搅拌磁子的玻璃管外壁键合一层带烯基的硅烷化物质;将反应单体混合剂和致孔剂混合溶液混匀后倒入容器中,将预键合后的搅拌磁子放入容器,密封后置于水浴中,反应后除去容器,取出涂有聚合物的搅拌磁子,置于提取器中,以溶剂提取,或将搅拌棒置于溶剂中浸泡至溶剂中无杂质检出,得产物。

The crosslinked PEG-20M glass capillary column was prepared by dynamic coating method with boron trifluoride as catalyst,3-glvcidyl-oxypropyl-trimethoxysilane as crosslinking agent.

以PEG-20M为固定相,三氟化硼为催化剂,3-缩甘油氧丙基三甲氧基硅烷(简称KH-560)为交联剂,二氯甲烷为溶剂,对预先用氯化钠沉积法粗糙化的玻璃毛细管柱进行动态涂渍。

Further more, to make the hybrid microspheres with good dispersibility in aqueous media, 3-propyl triethoxysilane was added to copolymerize with St and DVB, and after hydrolization the microspheres with silanol groups on the surface were obtained, which can be well dispersed in water and used for cell imaging.

进而将3-甲基丙烯酰氧基丙基三甲氧基硅烷作为共聚单体,得到了表面硅羟基功能化的聚苯乙烯荧光微球,改善了微球在水相中的分散性,并将此类荧光功能微球成功用于细胞成像。

Two needle-shaped crystal chemicals were identificated from a plateau plant Halenia elliptica D. Don. Some analysis methods, such as EA, MS, NMR, FTIR and UV spectrometly, as well as melting point analysis, were used for the characterization of them, results showed that they were 1,3-dihydroxy-4,5,8-trimethoxyxanthone and 1-hydroxy-2,3,4,8-tetramethoxyxanthone.

提取并鉴定高原植物椭圆叶花锚的全草中2种针状结晶化合物;采用元素分析、核磁共振波谱、质谱、红外光谱、紫外光谱、熔点测定等分析方法,对其化学结构进行表征;产物分别为1,3-二羟基-4,5,8-三甲氧基酮和1-羟基-2,3,4,8-四甲氧基酮。

The silica/Polystyrene monocore-shell nanocomposite particles(95nm in diameter) were synthesized through miniemulsion polymerization by using sodium dodecyl sulfate surfactant,hexadecane costabilizer in the presence of silica particles(50nm in diameter) coated with methacryloxytrimethoxysilane.

采用细乳液聚合法,以3-甲基丙烯酰氧基丙基三甲氧基硅烷(KH570)表面改性的直径50nm的氧化硅粒子为核,在乳化剂、助乳化剂、引发剂存在的情况下制备了小粒径、单核核壳结构氧化硅/聚苯乙烯纳米复合微球。

Result: Eleven chemical constituents were isolated and elucidated as arctiin,phillyrin,forsythiaside,liquiritigenin,liquiritin,genistein,formononetin,daidzein,glycitrin,3,3′,4-tri-omethlellagic acid and chlorogenic acid.

结果 :从银翘散抗流感病毒有效部位群中分离得到 11种成分,鉴定为牛蒡子苷、连翘苷、连翘酯苷、甘草苷、甘草素、染料木素、芒柄花素、大豆素、6 甲氧基大豆素、3,3′,4 三甲氧基鞣花酸和绿原酸。

The gelatin-siloxane nano-particles are prepared from gelatin and 3-(2,3-epoxy propoxy )propyltrimethoxysilicane by performing chemical combination and hydrolytic reaction in acidic condition to obtain sol; and adjusting the pH value to slightly alkaline for performing polymerization reaction of silicane.

将明胶和3-(2,3-环氧丙氧)丙基三甲氧基硅烷在酸性条件进行化合、水解反应;将该溶胶的pH值调节至弱碱性,使硅烷发生聚合反应,即可得明胶-硅氧烷纳米颗粒。

Poly silica hybrids were prepared through polymerization, condensation and sol gel processes of the mixture of methyl methacrylate, poly and a small amount of coupling agent methacryloxylpropyl trimethoxy siliane in tetrahydrofuran.

采用溶胶-凝胶技术,以硅酸钠为原料制备聚硅酸/四氢呋喃溶胶,再与甲基丙烯酸甲酯及少许偶联剂甲基丙烯酰氧丙基三甲氧基硅烷(MPTMS 混合,经聚合、缩合和溶胶-凝胶过程制备了有机/无机两相间有— C—Si—O—键的杂化材料——聚甲基丙烯酸甲酯/二氧化硅(PMMA/Si O2 )。

The primary content of this paper is the synthesis of POSS with r-glycidyl-propyl-trimethoxysilane throught hydrolysis and condensation reaction and the modification of shape memory polyurethane with synthesized POSS.

本文主要研究了以γ-(2,3环氧丙氧)丙基三甲氧基硅烷为原料通过水解缩合反应合成含有羟基的POSS以及利用该产物改性形状记忆聚氨酯。

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