三环烯

The experimental results showed that the catalyst had better catalytic activity and selectivity. The main product of the isomerization reaction was camphene, and the byproducts were limonene, terpinolene and tricyclene etc.

该催化剂具有较好的催化活性和选择性，异构化反应的主产物是莰烯，副产物是苎烯、异松油烯、三环烯等。

By means of GC, GC-MS, GC-IR, the reaction products were investigated and the results showed that there are triylene, camphene, limonene, p-cymene, terpinolene -terpinene,-terpinene,-fenchyl formate, linalyl formate, terpinyl formate, bornyl formate and isobornyl formate containing in the products,and linalyl formate was first discovered in addition reaction of a -pinene and formic acid .The content of the main product terpinyl formate is up to 60.4%,the selectivity is 64.5%.

采用GC、GC-IR、GC-MS等对反应产物进行定量和定性分析，结果表明：微波辐射下α-蒎烯与甲酸的反应产物含有三环烯、莰烯、对-伞花烃、α-松油烯、γ-松油烯、柠檬烯、异松油烯、甲酸葑醇酯、甲酸异龙脑酯、甲酸龙脑酯、甲酸芳樟酯、甲酸松油酯。

The double bond in norbornene ring of TCPD was easily saturated at a low temperature, and an intermediate 12,13-dihydrotricyclopentadiene (12,13-DHTCPD) was formed. Higher temperature and hydrogen pressure were required for the saturation of remaining double bond in cyclopentene ring to generate a completely hydrogenated compound tetrahydrotricyclopentadiene.That is to say, the reaction occurred via the TCPD→12,13-DHTCPD→THTCPD route.

采用气质联用、红外光谱和核磁共振对加氢产物进行表征，发现在加氢反应中TCPD的降冰片烯双键首先被饱和，生成中间产物12，13-二氢三环戊二烯(12，13-DHTCPD)，残留的环戊烯双键需要在更高的温度和氢压下反应生成四氢三环戊二烯，即反应按照TCPD→12，13-DHTCPD→THTCPD的途径进行。

A new fused polycyclic indoline compound was synthesized from aniline,with the key step of Pd-catalyzed tandem cyclization using hydroquinidine as the ligand and molecular oxygen as a green oxidant.

以芳香氨为原料，通过烯丙基化、重排、酰基化及钯催化的氧化环合反应合成了一种新的氮杂三环吲哚啉化合物，其结构经1H NMR，13C NMR，IR及HR-MS表征。

This thesis sets up a new method to synthesize stereoselectively ?ra玸--2,5-disubstituted tetrahydrofurans by introducing two alkyl groups in 3-C and 5-C of lactol, flash decomposition and hydrogenation.

本文独创新的合成方法：以-乳醇，即-4，10-二氧杂三环[5.2.1.0~(2，6)]-癸-8-烯-3-醇为原料，在其3-位和5-位先反向引入两个取代基，再经过热分解和催化加氢反应，高立体选择性地合成反式-2，5-二取代四氢呋喃。

The key problem is to synthesize high stereoselectively trans- 2,5- disubstituted tetrahydrofurans. This thesis sets up a new method to synthesize stereoselectively ?ra玸--2,5-disubstituted tetrahydrofurans by introducing two alkyl groups in 3-C and 5-C of lactol, flash decomposition and hydrogenation.

本文独创新的合成方法：以-乳醇，即-4，10-二氧杂三环[5.2.1.0~(2，6)]-癸-8-烯-3-醇为原料，在其3-位和5-位先反向引入两个取代基，再经过热分解和催化加氢反应，高立体选择性地合成反式-2，5-二取代四氢呋喃。

Yet, completely differ from the cases of 〓-H, the 〓-dihydroxyl group was introduced after subsequent epoxidation and oxane ring opening of the 〓 tricyclic olefin.

在〓-β-H三环烯31基础上的环氧化和环氧开环反应引入的两个羟基，为双直立的〓，不同于〓类。

Synthesis of tricyclopentadiene Two methods of polymerization were analyzed in the synthesis of TCPD: thermal polymerization of DCPD, Diels-Alder reaction of DCPD and cyclopentadiene.

三环戊二烯的合成采用两种方式对TCPD的合成进行了研究：DCPD直接热聚法、DCPD与环戊二烯双烯加成法。

This dissertation is concerned with the approaches to a new high density liquid fuel, tetrahydrotricyclopentadiene, which can be synthesized with dicyclopentadiene as raw materials by three steps: Diels-Alder reaction, separation and hydrogenation. The main points of the paper are listed as follows.

本文以双环戊二烯为原料，通过双烯加成、分离、加氢反应得到目的产物——新型高密度液体燃料四氢三环戊二烯，主要研究内容包括： 1。

This dissertation is concerned with the approaches to a new high density liquid fuel , tetrahydrotricyclopentadiene, which can be synthesized with dicyclopentadiene as raw materials by three steps: Diels-Alder reaction, separation and hydrogenation.

本文以双环戊二烯为原料，通过双烯加成、分离、加氢反应得到目的产物——新型高密度液体燃料四氢三环戊二烯，主要研究内容包括： 1。三环戊二烯的合成采用两种方式对TCPD的合成进行了研究：DCPD直接热聚法、DCPD与环戊二烯双烯加成法。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。