三烯

The result showed that there was significant botanical character difference among the three varieties of rosemary; the content of essential oil of Rosmarinus officinalis L is higher than that of Rosmarinus officinalis 'Rex' and Rosmarinus officinalis 'Wood' with 0.80, 0.46 and 0.40 mL(100g)^(-1)FW respectively;α-pinene、1,8-cineole、verbenone、geraniol and borneol were the main compositions of essential oil from Rosmarinus officinalis L, with 27.26%, 20.92%, 11.75%, 5.92% and 5.07% respectively; the major components of essential oil of Rosmarinus officinalis 'Rex' were 1,8-cineole、camphor、borneol、α-pinene and camphene, accounting for 31.07%, 21.66%, 11.98%, 5.36% and 5.34% respectively; in Rosmarinus officinalis 'Wood', camphor、1,8-cineole、bornyl acetate、borneol、α-pineneand camphene were the major compositions with 24.69%, 23.96%, 6.76%, 5.94%, 5.80% and 5.28% respectively.

结果表明：三种迷迭香的植物学性状，如外形、花色等差异显著；迷迭香的精油含有率较高，为0.80mL(100g)^(-1)FW，Rex迷迭香和Wood迷迭香的精油含有率低，分别为0.46和0.40mL(100g)^(-1)FW；迷迭香的主要成分为α-蒎烯27.26%、1，8-桉叶素20.92%、马鞭烯酮11.75%、香叶醇5.92%、龙脑5.07%等，Rex迷迭香精油中1，8-桉叶素31.07%、樟脑21.66%和龙脑11.98%、α-蒎烯5.36%、莰烯5.34%是其主要成分，Wood迷迭香精油的主要成分为樟脑24.69%、1，8-桉叶素23.96%、醋酸龙脑酯6.76%、龙脑5.94%、α-蒎烯5.80%和莰烯5.28%等。

First, a chlorinator was self-designed in this paper, and dichloride of 2-methyl-1-propene was synthesized by 2-methyl-1-propene reacted with chlorine fast in this reactor. By means of the Orthogonal Experiments design and single factor experiments, the influence of several reaction variables on the yield were examined and the optimum reaction conditions under the intervallic operation were obtained, the yield and selectivity of dichloride of 2-methyl-1-prop-ene were more than 65% and 80% respectively. Second, the preparation of 2-methylene-1, 3-propanediol, which dichloride of 2-methyl-1-propene reacted with alkali was investigated. By means of the Orthogonal Experiments design and single factor experiments, the influence of several reaction variables on the yield were examined and the optimum reaction conditions under the intervallic operation were obtained, the conversion of dichloride of 2-methyl-1-propene was 100%. Moreover the preparation of MPO, which 2-methylene-1, 3-propanediol reacted with hydrogen, in presence of Al_2O_3-Pd catalyst, was gotten, and the product was appraised.

本文在氯化反应过程中，自行设计制作出了氯化管式反应器，在该反应器中异丁烯和氯气迅速混合反应生成二氯异丁烯，根据该氯化反应特征利用正交试验和单因素试验考察了有关因素的影响并优化得到了最佳工艺条件，二氯异丁烯的总收率达65％以上，选择性达80％；接着，对二氯异丁烯进行水解反应制得了2-甲烯-1，3-丙二醇，讨论了相关因素对水解反应的影响，并通过正交试验和单因素试验得到了较佳工艺条件，二氯异丁烯的转化率达100％；同时还对制备的2-甲烯-1，3-丙二醇在常压下采用三氧化二铝负载钯催化剂催化加氢得目的产物MPO，并对产品进行了鉴定，从而打通了整个工艺路线。

13 K,α-pinene+ p -cymene (429. 05—447. 15 K),β-pinene+ p -cymene (439. 20—448. 66 K) and α-pinene+β-pinene+ p -cymene (432. 17—448. 11 K) were determined at atmospheric pressure (100. 7 kPa) with the modified Ellis still. The thermodynamic consistency of the experimental data was confirmed by means of the Herington method.

采用改进的Ellis平衡釜测定了在常压(100.7 kPa)下三个二元物系α-蒎烯＋β-蒎烯(428.82 K ~ 438.13 K)，α-蒎烯＋对伞花烃(429.05 K ~ 447.15 K)，β-蒎烯＋对伞花烃(439.20 K ~ 448.66 K)和一个三元物系α-蒎烯＋β-蒎烯＋对伞花烃(432.17 K ~ 448.11 K)的汽液相平衡数据，并利用Herington规则，以积分检验法对实验数据进行了热力学一致性检验。

On the base of molecular structure design, the mechanism and technique of the synthesis of 2-(acryloyloxy ethyl trimethyl-ammonium chloride/2-acrylamido-2methylpropane sulfonic acid/acrylamide (AETMAC/AMPS/AM) amphoteric terpolymers by radical co-polymerization in aqueous solution was studied systematically.

依据分子结构设计理论，将2—丙烯酰氧乙基—三甲基氯化铵/2—丙烯酰胺基—2—甲基丙烷磺酸/丙烯酰胺(AETMAC/AMPS/AM)三种单体进行水溶液自由基共聚，合成了AP系列两性离子聚合物。

We have studied the transition metal complexes catalyzed sequential cross coupling reactions of these new difunctional group reagents with electrophiles and nucleophiles, respectively; developed some convenient and practical new methods for the stereoselective synthesis of disubstituted alkenes, trisubstituted alkenes, conjugated dienes containing heteroatom, conjugated enyne containing heteroatom etc., enriching methodologies for organic synthesis.

继而研究了这些新型双官能试剂在过渡金属配合物催化下分别与亲电试剂、亲核试剂的顺序交叉偶联反应，为双取代烯烃、三取代烯烃、杂原子取代的共轭二烯烃、杂原子取代的共轭烯炔烃等的立体选择合成提供了方便实用的新方法，丰富了烯烃立体选择合成的方法学。

Through mechanism analyzing on the process of producing HMT , it was known that because the resistance of isobutylene was small ,the yield of outgrowth in such a reaction system was little and the yield of reaction was as high as 86%. 2,3-dimethyI-butene-2 had the biggest resistance and lowest yield of reaction of 18%. 2,3-dimethyl-butene-l had bigger resistance than isobutylene and more outgrowth than isobutyles but its yield of reaction could reach 70%.

通过对上述三种烯烃合成HMT的研究可知，由于新己烯位阻小，反应中副反应少，收率高达86％：而2，3—二甲基—丁烯—2的位阻最大，反应中副反应最多，反应收率最高仅为18％；2，3—二甲基—丁烯—1的位阻比新己烯大，反应副产物比新己烯多，但反应收率仍可达70％。

In this thesis, three different chain length hybrid monomers, containing acrylate and propenyl ether group, was synthesized by three-step reaction through 1.3-propanediol, 1.4-butanediol, 1.6-hexanediol, allyl bromide and acryloyl chloride.

本文以1.3-丙二醇、1.4-丁二醇、1.6-己二醇、烯丙基溴及丙烯酰氯为主要原料，通过三步反应合成了三种不同链长的丙烯酸酯-丙烯基醚杂化单体。

N,N-dimethyl-N'-(2-trifluorometyl-1-pentafluoroethyl) perfluoro propenyl propane diamine and N,N-dimethyl N'-(2-trifluorometyl-1-pentafluoroethyl) perfluoro propene propane diamine were prepared by the reaction of hexafluoropropene dimer and N,N-dimethyl propanediamine in the molar ratio 1:1.0 at about 35℃for 8h, and the structures of I were identified by IR and NMR spectra.

本文以六氟丙烯二聚体和N，N-二甲基丙二胺为主要原料合成了两种含氟中间体叔胺——N，N-二甲基-N'-(2-三氟甲基-1-五氟乙基)全氟丙烯基丙二胺和N，N-二甲基-N'-(2-三氟甲基-1-五氟乙基)全氟烯丙基丙二胺，用薄层色谱和柱色谱等方法对产品进行分离提纯，并运用红外光谱和核磁共振等分析手段对其结构进行了表征。

The thesis consists of two main sections. The synthesis of 1,3,4-thiadiazoles,triazolotriazines and dioxapyrrolinopyrazoles containing chiral pyrazolyl moietyfrom D-glucose is described in the first part and the section one is about theDiels-Alder reactions between dienophile enaminones and diene 1,2,4-triazines,which provides a new methodology to construct the pyridine compounds. A total of37 new compounds were synthesized.

本论文包含两部分内容，一是以D-葡萄糖为原料合成含手性吡唑基的1，3，4-噁二唑、三唑并三嗪及二氧代吡咯啉并吡唑类化合物；二是将烯胺酮作为亲双烯体，与双烯体1，2，4-三嗪类化合物发生Diels-Alder反应，发现了一令人意外的构建吡啶类化合物的新方法。

It was discovered that trimalonic acid C60、fullerol、dimalonic[60]fullerene hydrolysate、tetraethyl methano[60]fullerenediphosphonate、methano[60]fullerenediphosphonic acid and dimalonic acid C60 exhibited different inhibitory effects on Taq DNA polymerase.

实验发现，6种富勒烯衍生物三丙二酸富勒烯、富勒醇、富勒烯丙二酸水解物、亚甲基富勒烯二膦酸四乙酯、亚甲基富勒烯二膦酸四乙酯的完全水解物和二丙二酸富勒烯对Taq DNA聚合酶存在不同程度的抑制作用。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。