三烯

After the excitation of YAG laser, 1、2、 4 were excited to their excited singlet states, then produced excited triplet states by intersystem crossing process, finally returned to their ground states.

在光敏剂1、2激发三重态与一系列链式缺电子烯烃之间的猝灭反应过程中，产生一具有电荷转移性质的激基复合物。

Dependent on the palladium role of hydrogenation and hydrogen spillover, the olefins effused from the zeolite capsule catalyst were hydrogenated effectively, mostly converted to isoparaffin.

得益于钯的催化加氢和氢溢流的功能，在基于该三分结构的费托合成反应中，烯烃产物被有效的催化加氢为烷烃，且大部分被转化成了异构烷烃。

The stable or unstable state of the montmorillonite-water dispersion is mainly effected by the properties of montmorillonite, water, and stabilizers as well as their interactions, while the type, the structure, the properties and the concentration of the stabilizer play dominate roles. Based on the molecular designing clues, this research selected three sulfonated copolymers as the stabilizers, i.e. the sodium 2-acrylamido-2-methyl-1propane sulfonate /acrylamide /disodium itaconate terpolymer, the AMPS/AM/N-vinyl pyrrolidone terpolymer and the sodium styrenesulfonate /IA copolymer. The preparation and characterization of the sulfonated copolymers were discussed, the high-temperature stability of the montmorillonitewater dispersion was characterized with the rheology, the filtration, the particle size distribution, the electrostatic properties, and the adorption of the sulfonated copolymers onto montmorillonite particles. At the same time, a systematic mechanism of the hightemperature stabilization of the dispersion was presented.

本文构筑了分子设计的思路，选取AMPS(2-丙烯酰胺基-2-甲基丙磺酸钠)/AM/IA三元共聚物、AMPS/AM/NVP三元共聚物和SSA/IA二元共聚物等三种磺化共聚物作为蒙脱土-水分散体系的高温稳定剂，进行了磺化共聚物稳定剂的制备与表征；从流变学、滤失性能、粒度分布、电性质以及磺化共聚物在蒙脱土上的吸附作用等方面，对蒙脱土-水分散体系的高温稳定性进行了研究，考察了蒙脱土-水分散体系的高温稳定性能，同时提出了高温稳定机理。

The paper discussed how docosahexaenoic acid regulated transcription expression of lipogenic and lipolytic genes, which included PPARγ(peroxisome proliferators activated receptor γ), SREBP-1c (sterol regulatory element binding protein-1c), FAS, HSL (hormone-sensitive lipase) and TGH.

探讨二十二碳六烯酸对小鼠脂肪组织和肝脏生脂相关基因过氧化物酶增殖物激活受体γ、固醇调节元件结合蛋白－1c基因(SREBP-1c)、脂肪酸合成酶基因，及脂解相关基因激素敏感脂酶基因和甘油三酯水解酶时序表达的影响。

In this study aldylencdithiomethylene Malonic acid acts as the main coordination agents and compound iron ion have been synthesized by the means of solution, As a result ,the 1D polymer is obtained.

本论文采用常规的溶液合成方法，首先设计合成了一个以含有二硫缩烯酮结构的丙二酸类配体和过渡金属铁离子的单核配合物，再以此单核配合物作为配体设计合成了三个异多核配合物和配位聚合物。

We have investigated on the chemical constituents of Nepeta partite collected from Gansu Zhuanglang, and twenty eight compounds were isolated from the methanol extraction of this species by chromatography techniques. Twenty five compounds were identified by means of chemical and spectra methods IR, FABMS, EI-MS,〓, DEPT, and 2D NMR）, among which four compounds were new as isopimar-15-en-3β, 8β, 20-triol; phenylethanal-3-O-（2'-glycerin）-5-O-β-D-glucopyranoside; 3-O-linolenoylglyceryl-6'-O-(α-D-galactopyranosyl）-β-D-galactopyranoside; ethyl rosemarinate.

我们对采自甘肃庄浪的康藏荆芥进行了化学成分的研究，利用层析手段从该植物的甲醇浸膏中分离出二十八个化合物，经化学方法和波谱技术（红外，质谱，一维和二维核磁共振谱）鉴定了二十五个化合物的结构，其中四个为新的化合物，它们分别是：异海松-15-烯-3β，8β，20-三醇；苯乙醇-3-O-（2'-甘油基）-5-O-β-D-吡喃葡萄糖甙；3-O-亚麻酰基甘油-6'-0--β-D-吡喃半乳糖甙；迷迭香酸乙酯。

The reaction of cyclic b-keto esters with CF3CO2ZnCH2I provides the corresponding ring-expanded products with the advantage of mild condition in moderate to good yields. A simple and efficient procedure has been developed for a variety of 1,3-diketones converted into the corresponding 1,4-diketones and trans-1,2-disubstituted cyclopropanols in high yields. In conclusion, this new type of organozinc reagents has been developed for many useful reaction in organic synthesis.

利用有机锌试剂所具有的双重特性，在新型的Baylis-Hillman反应中，可以直接与炔基酮和醛反应一锅制得多官能团的三取代的顺式烯；在b-酮酯化合物的扩环反应中，取得了重要进展，得到了增加一个碳的扩环产物，&一步法&合成，反应条件温和、环境友好；在1，3-二酮分子中成功地插入1个碳，合成出1，4-二酮和环丙醇，为现代有机合成提供了新的合成方法，具有良好的应用前景。

There are three isomeric pentene(C5H10)that yield 2-methylbutane on catalytic hydrogenation. Write structural formulas for these three isomers and indicate their relative stabilities based on the ΔH values

答：戊烯的三种同分异构体在催化加氢后可生成2-甲基丁烷，写出3个同分异构体的结构式，并依据他们的ΔH值判断出它们的相对稳定性

Compounds were identified by means of physic-chemical property and spectral data including three new compounds: platyphyllin A (1), neochlorgeniclatone (2),(2E,6Z)-2,6-dimethyl-8-O-β-D-glucosyl-2,6-octadienoic acid (3). The known compounds included cyclic diarylheptanoids, phenylic acid, ect.

从白桦叶的水提取物中，利用各种色谱分离手段(硅胶柱色谱、聚酰胺柱色谱、凝胶柱色谱及制备薄层色谱等)，分离得到28个化合物，通过理化性质及各种波谱数据(NMR，MS，IR，etc)鉴定了23个化合物的结构，其中新化合物三个：platyphyllin A(1)，新绿原酸内酯(neochlorgeniclatone，2)，(2E，6Z)-2，6-二甲基-8-O--2，6-辛二烯酸(2E，6Z-2，6-dimethyl-8-O-β-D-glucosyl-2，6-octadienoic acid，3。

Herein, a series of compounds, BP-C〓-NBD (n=2, 3, 4, 5, 6, 8, 10), was synthesized. Nanosecond flash photolysis, phosphorescence emission and lifetime, as well as photoisomerization reaction of norbornadiene were used to understand the intramolecular triplet energy transfer in detail.

我们设计、合成了以多亚甲基连接的二苯酮与降冰片二烯（BP-C〓-NBD，n=2，3，4，5，6，8，10）系列化合物，利用纳秒时间分辨技术、低温磷光发射、磷光寿命以及光敏异构化的方法，对其分子内三重态能量传递过程进行了详细地研究。

It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发，分析对称连杆曲线上鲍尔点的产生条件，提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品，年生产总值3000万美元，产品价廉物美、选料上乘、质量保证，深受国内外客户的青睐