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The elaboration of systems that are able to mimic those enzymes should provide very important tools for three main purposes:(1) the development of new catalysts for important reactions in industrial and fine chemistry, such as the selective oxidation of alkanes and the stereoselective epoxidation of alkenes;(2) the prediction of the oxidative metabolism of new biologically active molecules such as drugs.(3) mimetic peroxidase of high catalytical activity and selectively is very important in bio-analytical field.

建立一系列关于这些酶的模拟体系将为以下三个方面的研究工作提供非常重要的工具:(1)工业或者精细化工方面重要反应新型催化剂的开发,例如烷烃的选择性氧化以及具有立体选择性的烯烃环氧化;(2)新的生物活性物质,例如药物的氧化机理的研究和预测;(3)具有合适底物的高活性过氧化物酶模拟酶在生化分析领域的前景。

Epoxycedrane was firstly synthesized at home and abroad from α-cedrene by epoxidation of hydrogen peroxide under the catalysis of ruthenium trichloride and pyridine-2, 6-dicarboxylic acid.

以三氯化钌和2,6-二羧基吡啶为催化剂,双氧水为氧化剂,时α-柏木烯进行环氧化反应合成环氧柏木烷。本合成方法在国内外尚未见报道。

Mol/L and calcinations temperature at 500?℃. The solid superacid can be used as catalyst two times in the alkylation of naphthalene, and the total composition of MIPN,DIPN, and TIPN in product is over 98%. When the consumpt...

在催化剂用量为 10 %、反应温度为 160℃、反应时间为 2 5h的条件下连续两次使用SO2 - 4 TiO2 超酸催化萘对丙烯的烷基化反应,产品中一异丙基萘、二异丙基萘、三异丙基萘的总含量大于 98%。

Good thermal stability, High mechanical strength.Used as catalyst or catalyst carrier in the manufacturing of the important industrial products, such as cyanuramide, benzene anhydride, maleic acid anhydride, butadiene rubber, acrylic nitrite, etc.

用途:本产品在三聚氰胺、苯酐、顺丁烯二酸酐、顺丁橡胶、丙烯腈等重要工业品生产中用作催化剂及催化剂载体,也广泛用于石化产品的精制脱除芳烃,也可用于有机气体、液体的选择性吸附分离及离子交换脱除水中多价有害元素等。

Under the optimum conditions of a cyclopentene amount of 1.0 mol, a molar ratio of cyclopentene to water of 0.25, a reaction temperature of 120 ℃, a reaction time of 4.0 h, a main catalyst dosage of 4.0 g and a cocatalyst dosage of 0.8 g, the yield of cyclopentanol reached 68.6%.

确定适宜的反应条件为:环戊烯1.0 mol,n﹕n=1﹕4,反应温度120 ℃,反应时间4.0 h,硅胶负载铌酸主催化剂用量4.0 g,三(3,6-二氧杂庚基)胺助催化剂0.8 g。在此反应条件下,环戊醇收率68.6%。

Cyclopentanol was synthesized from cyclopentene and water through hydration reaction using HNb3O8·H2O/SiO2 as main catalyst and tris(dioxa-3,6-heptyl)amine (TDA-1) as cocatalyst.

在以硅胶负载铌酸为主催化剂、三(3,6-二氧杂庚基)胺为助催化剂的作用下,以环戊烯和水为原料,通过水合加成反应合成了环戊醇。

Objective To study the effects of diallyl trisulfide on apoptosis of human leukemia cells HL-60 and the probable mechanism involved.

目的 研究二烯丙基三硫对HL-60细胞凋亡的影响及其作用机制。

METHODS: diallyl trisulfide coated stent and the control stent were implanted into distal and proximal left circumflex coronary arteries of 20 dogs, respectively.

进行冠状动脉左回旋支支架置入术的犬,将二烯丙基三硫化物涂层支架和对照支架分别置入左回旋支的远端和近端。

A facile method is presented for synthesis of malonaldehyde dianil from propargyl alcohol by oxidizing using chromium trioxide and addition reaction with aniline.

以丙炔醇为原料,经三氧化铬氧化生成丙炔醛后,直接与苯胺反应简便地合成了β-苯胺基丙烯醛缩苯胺。

ABSTRACT In this paper, by employing dicarboxylic acids with special conformation, i.

利用几个结构上有特点的二元羧酸,即2,6-吡啶二甲酸、三个异构体苯二甲酸,顺丁烯二酸和4,4'-联苯甲酸作为首要桥基配体,并结合使用含氮中性配。。。

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